Nachrichten, Meldungen

Catalyst-free room-temperature iClick reaction of molybdenum(II) and tungsten(II) azide complexes with electron-poor alkynes: structural preferences and kinetic studies

Ligand versus Complex: C-F and C-H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino) Carbene

Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron

Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions

Deprotonation of a Hydridoborate Anion

A Cyclic Alkyl(amino)carbene as Two-Atom π-Chromophore Leading to the First Phosphorescent Linear CuI Complexes

Highly Efficient Synthesis of Alkylboronate Esters via Cu(II)-Catalyzed Borylation of Unactivated Alkyl Bromides and Chlorides in Air

Cationic Bismuth Amides: Accessibility, Structure, and Reactivity

Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates

A Silacyclopropene with a Six-Coordinate Silicon Atom and an SiN4C2 Skeleton: Synthesis and Structural Characterization

Cyclisation of biscarbenoids – a novel mode of cyclobutadiene stabilisation

Synthesis of the fluorohydridoborate anions [BHF3]− and [1-HF2B-9,12-X2-closo-1,2-C2B10H9]− (X = H, I): deboronation of 1,2- and 1,7-dicarba-closo-dodecaboranes with anhydrous [Me4N]F

Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square

Neutral six-coordinate bis(dithiocarbamato)silicon(IV) complexes with an SiCl2S4 skeleton

N-Heterocyclic Silylenes in Boron Chemistry: Facile Formation of Silylboranes and Silaborinines