English Intern
Hierlmeier Group




22) G. Hierlmeier, R. J. Kutta, P. Coburger, G. Stammler, J. Schwabedissen, N. W. Mitzel, M. Dimitrova, R. Berger, P. Nürnberger and R. Wolf, Chem. Sci., 2024, DOI: 10.1039/D4SC00936C.
  Structure and photochemistry of di-tert-butyldiphosphatetrahedrane
  Chem. Sci. 2024 
  DOI: 10.1039/D4SC00936C


21) J. B. Roque, A. M. Shimozono, T. P. Pabst, G. Hierlmeier, P. O. Peterson, P. J. Chirik
  Kinetic and thermodynamic control of C(sp2)-H activation enables site-selective borylation
  Science 2023, 382, 1165-1170. 
  DOI: 10.1126/science.adj6527
20) G. Hierlmeier, P. Tosatti, K. Puentener, P. J. Chirik
  Arene Insertion with Pincer-Supported Molybdenum-Hydrides: Determination of Site-Selectivity, Relative Rates, and Arene Complex Formation
  J. Am. Chem. Soc. 2023145, 21027–21039. 
  DOI: 10.1021/jacs.3c06961
19) S. J. Horsewill, G. Hierlmeier, Z. Farasat, J. P. Barham, D. J. Scott
  Shining Fresh Light on Complex Photoredox Mechanisms through Isolation of Intermediate Radical Anions
  ACS Catal. 2023, 13, 9392–9403.
  DOI: 10.1021/acscatal.3c02515
18) B. Lee, T. P. Pabst, G. Hierlmeier, P. J. Chirik
  Exploring the Effect of Pincer Rigidity on Oxidative Addition Reactions with Cobalt(I) Complexes
  Organometallics, 2023, 42, 708–718. 
  DOI: 10.1021/acs.organomet.3c00079
17) G. Hierlmeier, P. Tosatti, K. Puentener, P. J. Chirik
  Identification of Cyclohexadienyl Hydrides as Intermediates in Molybdenum-Catalyzed Arene Hydrogenation
  Angew. Chem. Int. Ed. 2023, 62, e202216026; Angew. Chem. 2023, 135, e202216026. 
  DOI: 10.1002/anie.202216026; DOI: 10.1002/ange.202216026


16) G. Hierlmeier,+ C. Rödl,+ R. Wolf
  A Homoleptic Tris(diphosphacyclobutadiene) Tripledecker Sandwich Complex
  Chem. Commun. 2022, 58, 12212–12215.
  DOI: 10.1039/d2cc04601f
15) C. S. MacNeil, L. N. Mendelsohn, T. P. Pabst, G. Hierlmeier, P. J. Chirik
  Alcohol Synthesis by Cobalt-Catalyzed Visible-Light-Driven Reductive Hydroformylation
  J. Am. Chem. Soc. 2022, 144, 19219–19224.
  DOI: 10.1021/jacs.2c07745
14) M. K. Uttendorfer, G. Hierlmeier, R. Wolf
  A Homoleptic Diphosphatetrahedrane Nickel(0) Complex
  Z. Anorg. Allg. Chem. 2022, e202200124.
  DOI: 10.1002/zaac.202200124
13) P. Viereck, G. Hierlmeier, P. Tosatti, K. Puentener, P. J. Chirik
  Molybdenum-Catalyzed Asymmetric Hydrogenation of Fused Arenes and Heteroarenes
  J. Am. Chem. Soc. 2022, 144, 11203–11214.
  DOI: 10.1021/jacs.2c02007
12) G. Hierlmeier, R. Wolf
  Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand
  Organometallics, 2022, 41, 776–784.
  DOI: 10.1021/acs.organomet.2c00009
11) G. Hierlmeier, R. Wolf
  Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes
  Eur. J. Inorg. Chem. 2022, e202101057.
  DOI: doi/10.1002/ejic.202101057


10) G. Hierlmeier, P. Coburger, D. J. Scott, T. M. Maier, S. Pelties, R. Wolf, D. M. Pividori, K. Meyer, N. P. van Leest, B. de Bruin
  Di-tert-butyldiphosphatetrahedrane as a Source for 1,2-Diphosphacyclobutadiene Ligands
  Chem. Eur. J. 2021, 27, 14936–14946
  DOI: 10.1002/chem.202102335
9) P. Coburger, J. Leitl, D. J. Scott, G. Hierlmeier, I. G. Shenderovic, E. Hey-Hawkins, R. Wolf
  Synthesis of a Carborane-substituted Bis(phosphanido) Cobaltate(I), Ligand Substitution, and Unusual P4 Fragmentation
  Chem. Sci. 2021, 12, 11225–11235.
  DOI: 10.1039/d1sc02948g
 8) G. Hierlmeier, R. Wolf
  Activation of Di-tert-butyldiphosphatetrahedrane: Access to (tBuCP)n (n = 2, 4) Ligand Frameworks by P‒C Bond Cleavage
  Angew. Chem. Int. Ed. 2021, 60, 6435–6440; Angew. Chem. 2021, 113, 6507–6512.
  DOI: 10.1002/anie.202015680; DOI: 10.1002/ange.202015680
 7) G. Hierlmeier, M. K. Uttendorfer, R. Wolf
  Di-tert-butyldiphosphatetrahedrane as a Building Block for Phosphaalkenes and Phosphirenes        
  Chem. Commun. 2021, 57, 2356–2359.
  DOI: 10.1039/d0cc07103j


 6) C. G. P. Ziegler, C. Taube, J. A. Kelly, G. Hierlmeier, M. Uttendorfer, J. J. Weigand, R. Wolf
  An Unusual Ni2Si2P8 Cluster Formed by Complexation and Thermolysis                                                 
  Chem. Commun. 2020, 56, 14071–14074.
  DOI: 10.1039/d0cc05365a 
 5) J. Leitl, P. Coburger, D. J. Scott, N. P. van Leest, C. G. P. Ziegler, G. Hierlmeier, B. de Bruin, C. Müller, R. Wolf
  Phosphorus-Analogues of [Ni(bpy)2]: Synthesis and Application in Carbon-Halogen Bond Activation
  Inorg. Chem. 202059, 9951–9961.
  DOI: 10.1021/acs.inorgchem.0c01115
 4) G. Hierlmeier, P. Coburger, N. P. van Leest, B. de Bruin, R. Wolf
  Aggregation and Degradation of White Phosphorus Mediated by 12 Valence Electron Nickel(0) Complexes
  Angew. Chem. Int. Ed. 202059, 14148–14153Angew. Chem. 2020132, 14252–14257.
  DOI: 10.1002/anie.202004020; DOI: 10.1002/ange.202004020


 3) G. Hierlmeier, P. Coburger, M. Bodensteiner, R. Wolf
  Di-tert-butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer            
  Angew. Chem. Int. Ed. 201958, 16918–16922; Angew. Chem. 2019, 131, 17074-17078.
  DOI: 10.1002/anie.201910505; DOI: 10.1002/ange.201910505; highlighted with a front cover


 2) G. Hierlmeier, A. Hinz, R. Wolf, J. M. Goicoechea
  Synthesis and Reactivity of Nickel-Stabilised µ2:η2,η2-P, As2 and PAs Units                                          
  Angew. Chem. Int. Ed.  2018, 57, 431–436Angew. Chem. 2018130, 439–444.
  DOI: 10.1002/anie.201710582; DOI: 10.1002/ange.201710582


 1) L. R. Collins, G. Hierlmeier, M. F. Mahon, I. M. Riddlestone, M. K. Whittesey
  Unexpected Migratory Insertion Reactions of M(alkyl)2 (M=Zn, Cd)                                                          
  Chem. Eur. J. 201521, 3215–3218.
  DOI: 10.1002/chem.201406406

authors contributed equally