Institut für Organische Chemie

    Dr. Matthias Grüne, short curriculum vitae

    1983-1988:     Diploma of Chemistry, University of Münster

    1989-1992:     Dr. rer. nat. at the University of Münster,
    Institute of Physical Chemistry (with Prof. Dr. W. Müller-Warmuth),
    Ph.D. award of the University of Münster

    1993:              Postdoc at the C.N.R.S., Bordeaux-Talence (with Prof. Dr. C. Delmas)

    1994-1997:     Research associate at the Institute of Molecular Biotechnology,
    Jena (with Prof. Dr. L. R. Brown) and University of Jena
    (with Prof. Dr. A. S. Ulrich)

    1997-1999:     Research associate at the Max Planck Institute for Neurological Research,
    Cologne (with Prof. Dr. M. Hoehn and Prof. Dr. K.-A. Hossmann)

    Since 1999:    Institute of Organic Chemistry, University of Würzburg,
    head of the NMR Department



    M. Grüne, H. Meierkord, W. Müller-Warmuth, P. zum Hebel, B. Krebs, M. Wulff
    Ber. Bunsenges. Phys. Chem. 1989, 93, 1313-1317
    7Li NMR spin-lattice relaxation and ionic diffusion in lithium thioborate glasses.

    P. zum Hebel, B. Krebs, M. Grüne, W. Müller-Warmuth
    Solid State Ionics 1990, 43, 133-142
    Preparation, crystal structure and 7Li NMR of Li6+2x[B10S18]Sx (x≈2).

    M. Grüne, W. Müller-Warmuth
    Ber. Bunsenges. Phys. Chem.
    1991, 95, 1068-1071
    Considerations and examples for a uniform behavior of spin-lattice relaxation in glasses.

    M. Grüne, W. Müller-Warmuth, P. zum Hebel, B. Krebs
    Solid State Ionics 1993, 66, 165-173
    Unusual lithium dynamics and NMR relaxation in a novel crystalline thioborate-sulfide.

    M. Grüne, W. Müller-Warmuth
    Solid State NMR
    1995, 5, 145-150
    The importance of paramagnetic impurities to the NMR relaxation of ion conducting glasses.

    M. Grüne, W. Müller-Warmuth, P. zum Hebel, B. Krebs
    Solid State Ionics
    1995, 78, 305-313
    Complex lithium dynamics in the novel thioborate Li5B7S13 revealed by NMR relaxation and lineshape studies.

    M. Grüne, J. P. Fürste, S. Klußmann, V. A. Erdmann, L. R. Brown
    Nucl. Acids Res. 1996, 24, 2592-2596
    Detection of multiple conformations of the E-domain of 5S rRNA from Escherichia coli in so­lu­tion and in crystals by NMR spectroscopy.

    M. Grüne, M. Görlach, V. Soskic, S. Klußmann, R. Bald, J. P. Fürste, V. A. Erdmann, L. R. Brown
    FEBS Lett. 1996, 385, 114-118
    Initial analysis of 750 MHz NMR spectra of selectively 15N-G, U labelled E. coli 5S rRNA.

    R. Ramachandran, C. Sich, M. Grüne, V. Soskic, L. R. Brown
    J. Biomol. NMR 1996, 7, 251-255
    Sequential assignments in uniformly 13C- and 15N-labelled RNAs: The HC(N,P) and HC(N,P)-CCH-TOCSY experiments.

    R. W. Glaser, M. Grüne, C. Wandelt, A. S. Ulrich
    1999, 38, 2560-2569
    Structure analysis of a fusogenic peptide sequence from the sea urchin fertilization protein bindin.

    M. Grüne, F. Pillekamp, W. Schwindt, M. Hoehn
    Magn. Reson. Med. 1999, 42, 118-126
    Gradient echo time dependence and quantitative parameter maps for somatosensory activation in rats at 7 T.

    M. Grüne, F. A. van Dorsten, W. Schwindt, L. Olàh, M. Hoehn
    Magn. Reson. Med
    . 1999, 42, 1027-1032
    Quantitative T2* and T2' maps during reversible focal cerebral ischemia in rats: separation of blood oxygenation from nonsusceptibility-based contributions.

    C. Delmas, M. Ménétrier, L. Croguennec, I. Saadoune, A. Rougier, C. Pouillerie, G. Prado, M. Grüne, L.Fournès
    Electrochemica Acta
    1999, 45, 243-253
    An overview of the Li(Ni,M)O2 systems: syntheses, structures and properties.

    G. Bringmann, M. Wohlfahrt, H. Rischer, M. Grüne, J. Schlauer
    Angew. Chem. Int. Ed.
    2000, 39, 1464-1466; Angew. Chem. 2000, 112, 1523-1525
    A new biosynthetic pathway to alkaloids in plants: acetogenic isoquinolines.

    F. Pillekamp, M. Grüne, G. Brinker, C. Franke, U. Uhlenküken, M. Hoehn, K.-A. Hossmann
    Magn. Reson. Imag.
    2001, 19, 143-152
    Magnetic resonance prediction of outcome after thrombolytic treatment.

    F.-G. Lehnhardt, G. Röhn, R.-I. Ernestus, M. Grüne, M. Hoehn
    NMR Biomed.
    2001, 14, 307-317
    H- and 31P-NMR spectroscopy of primary and recurrent human brain tumors in vitro: malignancy-characteristic profiles of water soluble and lipophilic spectral components.

    W. Adam, M. Grüne, M. Diedering, A. V. Trofimov
    J. Am. Chem. Soc. 2001, 123, 7109-7112
    Temperature and viscosity dependence in the stereoselective formation of the inverted housane for the photochemical nitrogen loss from the deuterium-stereolabeled parent diazabicyclo[2.2.1]hept-2-ene.

    F. A. van Dorsten, L. Olàh, W. Schwindt, M. Grüne, U. Uhlenküken, F. Pillekamp, K.-A. Hossmann, M. Hoehn
    Magn. Reson. Med
    . 2002, 47, 97-104
    Dynamic changes of ADC, perfusion, and NMR relaxation parameters in transient focal ischemia of rat brain.

    W. Adam, M. A. Arnold, M. Grüne, W. N. Nau, U. Pischel, C. R. Saha-Möller
    Org. Lett.
    2002, 4, 537-540
    Spiroiminodihydantoin is a major product in the photooxidation of 2'-deoxyguanosine by the triplet states and oxyl radicals generated from hydroxyacetophenone photolysis and dioxetane thermolysis.

    G. Bringmann, K. Messer, K. Wolf, J. Mühlbacher, M. Grüne, R. Brun, A. M. Louis
    2002, 60, 389-397
    Dioncophylline E from Dioncophyllum thollonii, the first 7,3'-coupled dioncophyllaceous naphthylisoquinoline alkaloid.

    M. Guilmard, A. Rougier, M. Grüne, L. Croguennec, C. Delmas
    J. Power Sources
    2003, 115, 305-314
    Effects of aluminium on the structural and electrochemical properties of LiNiO2.

    S. L. Grage, S. Afonin, M. Grüne M, A. S. Ulrich
    Chem. Phys. Lipids 2004, 132, 65-77
    Interaction of the fusogenic peptide B18 in its amyloid-state with lipid membranes studied by solid state NMR.

    R. Dobrawa, M. Lysetska, P. Ballester, M. Grüne, F. Würthner
    Macromolecules 2005, 38, 1315–1325
    Fluorescent supramolecular polymers: metal directed self-assembly of perylene bisimide building blocks.

    G. Bringmann, T.F. Noll, T.A.M. Gulder, M. Grüne, M. Dreyer, C. Wilde, F. Pankewitz, M. Hilker, G.D. Payne, A.L. Jones, M. Goodfellow, H.-P. Fiedler
    Nature Chem. Biol.
    2006, 2, 429-433
    Different polyketide folding modes converge to an identical molecular architecture.

    C.-C. You, C. Hippius, M. Grüne, F. Würthner
    Eur. J. 2006, 12, 7510–7519
    Light-harvesting metallosupramolecular squares composed of perylene bisimide walls and fluorescent antenna dyes.

    G. Bringmann, T. F. Noll, M. Dreyer, T. Gulder, M. Grüne, D. Moskau
    J. Org. Chem.
    2007, 72, 3247-3252
    Polyketide folding in higher plants: biosynthesis of the phenylanthraquinone knipholone.

    A. Lohr, M. Grüne, F. Würthner
    Chem. Eur. J
    . 2009, 15, 3691–3705
    Self-assembly of bis(merocyanine) tweezers into discrete bimolecular π-stacks.

    R. Schmidt, M. Stolte, M. Grüne, F. Würthner
    2011, 44, 3766–3776
    Hydrogen-bond-directed formation of supramolecular polymers incorporating head-to-tail oriented dipolar merocyanine dyes.

    M. M. Safont-Sempere, P. Osswald, M. Stolte, M. Grüne, M. Renz, M. Kaupp, K. Radacki, H. Braunschweig, F. Würthner
    J. Am. Chem. Soc.
    2011, 133, 9580–9591
    Impact of molecular flexibility on binding strength and self-sorting of chiral π-surfaces.

    C. Shao, M. Grüne, M. Stolte, F. Würthner
    Chem. Eur. J.
    2012, 18, 13665–13677
    Perylene bisimide dimer aggregates: fundamental insight into self-assembly by NMR and UV/Vis spectroscopy.

    B. Fimmel, M. Son, Y. M. Sung, M. Grüne, B. Engels, D. Kim, F. Würthner
    Chem. Eur. J
    . 2015, 21, 615–630
    Phenylene ethynylene-tethered perylene bisimide folda-dimer and folda-trimer: Investigations of folding features in ground and excited states.

    C. Cheng, E. M. Othman, A. Reimer, M. Grüne, V. Kozjak-Pavlovic, H. Stopper, U. Hentschel, U. R. Abdelmohsen
    Tetrahedron Letters
    2016, 57, 2786-2789
    Ageloline A, new antioxidant and antichlamydial quinolone from the marine sponge-derived bacterium Streptomyces sp. SBT345.

    M. Arrowsmith, D. Auerhammer, R. Bertermann, H. Braunschweig, G. Bringmann, M. A. Celik, R. D. Dewhurst, M. Finze, M. Grüne, M. Hailmann, T. Hertle, I. Krummenacher
    Angew. Chem. Int. Ed.
    2016, 55, 14464-14468; Angew. Chem. 2016, 128, 14680-14684
    Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.

    P. Maier, M. Grüne, M. Lehmann
    Chem. Eur. J.
    2017, 23, 1018-1022
    A Star-shaped Oligo(phenylenevinylene) Liquid Crystal Host with an Anthracene Guest – A Double Nanosegregating Supermesogen.

    M. Lehmann, P. Maier, M. Grüne, M. Hügel
    Chem. Eur. J.
    2017, 23, 1060-1068
    Crowded Star Mesogens: Guest-Controlled Stability of Mesophases from Unconventional Liquid-Crystal Molecules.

    C. Kerpen, J. A. P. Sprenger, L. Herkert, M. Schäfer, L. A. Bischoff, P. Zeides, M. Grüne, R. Bertermann, F. A. Brede, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze
    Chem. Int. Ed. 2017, 56, 2800-2804
    Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions.

    B. Gole, V. Stepanenko, S. Rager, M. Grüne, D. D. Medina, T. Bein, F. Würthner, F. Beuerle
    Angew. Chem. Int. Ed.
    2018, 57, 846–850
    Microtubular Self-Assembly of Covalent Organic Frameworks.

    J. Landmann, J. A. P. Sprenger, P. T. Hennig, R. Bertermann, M. Grüne, F. Würthner, N. V. Ignat'ev, M. Finze
    Chem. Eur. J.
    2018, 24, 608-623
    Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscoity Ionic Liquids.

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