Deutsch Intern
Institute of Organic Chemistry

Matthias Grüne: CV and publications

Dr. Matthias Grüne, short curriculum vitae

1983-1988:     Diploma of Chemistry, University of Münster

1989-1992:     Dr. rer. nat. at the University of Münster,
Institute of Physical Chemistry (with Prof. Dr. W. Müller-Warmuth),
Ph.D. award of the University of Münster

1993:              Postdoc at the C.N.R.S., Bordeaux-Talence (with Prof. Dr. C. Delmas)

1994-1997:     Research associate at the Institute of Molecular Biotechnology,
Jena (with Prof. Dr. L. R. Brown) and University of Jena
(with Prof. Dr. A. S. Ulrich)

1997-1999:     Research associate at the Max Planck Institute for Neurological Research,
Cologne (with Prof. Dr. M. Hoehn and Prof. Dr. K.-A. Hossmann)

Since 1999:    Institute of Organic Chemistry, University of Würzburg,
head of the NMR Department



M. Grüne, H. Meierkord, W. Müller-Warmuth, P. zum Hebel, B. Krebs, M. Wulff
Ber. Bunsenges. Phys. Chem. 1989, 93, 1313-1317
7Li NMR spin-lattice relaxation and ionic diffusion in lithium thioborate glasses.

P. zum Hebel, B. Krebs, M. Grüne, W. Müller-Warmuth
Solid State Ionics  1990, 43, 133-142
Preparation, crystal structure and 7Li NMR of Li6+2x[B10S18]Sx (x≈2).

M. Grüne, W. Müller-Warmuth
Ber. Bunsenges. Phys. Chem. 1991, 95, 1068-1071
Considerations and examples for a uniform behavior of spin-lattice relaxation in glasses.

M. Grüne, W. Müller-Warmuth, P. zum Hebel, B. Krebs
Solid State Ionics 1993, 66, 165-173
Unusual lithium dynamics and NMR relaxation in a novel crystalline thioborate-sulfide.

M. Grüne, W. Müller-Warmuth
Solid State NMR  1995, 5, 145-150
The importance of paramagnetic impurities to the NMR relaxation of ion conducting glasses.

M. Grüne, W. Müller-Warmuth, P. zum Hebel, B. Krebs
Solid State Ionics 1995, 78, 305-313
Complex lithium dynamics in the novel thioborate Li5B7S13 revealed by NMR relaxation and lineshape studies.

M. Grüne, J. P. Fürste, S. Klußmann, V. A. Erdmann, L. R. Brown
Nucl. Acids Res. 1996, 24, 2592-2596
Detection of multiple conformations of the E-domain of 5S rRNA from Escherichia coli in so­lu­tion and in crystals by NMR spectroscopy.

M. Grüne, M. Görlach, V. Soskic, S. Klußmann, R. Bald, J. P. Fürste, V. A. Erdmann, L. R. Brown
FEBS Lett.  1996, 385, 114-118
Initial analysis of 750 MHz NMR spectra of selectively 15N-G, U labelled E. coli 5S rRNA.

R. Ramachandran, C. Sich, M. Grüne, V. Soskic, L. R. Brown
J. Biomol. NMR  1996, 7, 251-255
Sequential assignments in uniformly 13C- and 15N-labelled RNAs: The HC(N,P) and HC(N,P)-CCH-TOCSY experiments.

R. W. Glaser, M. Grüne, C. Wandelt, A. S. Ulrich
Biochemistry 1999, 38, 2560-2569
Structure analysis of a fusogenic peptide sequence from the sea urchin fertilization protein bindin.

M. Grüne, F. Pillekamp, W. Schwindt, M. Hoehn
Magn. Reson. Med. 1999, 42, 118-126
Gradient echo time dependence and quantitative parameter maps for somatosensory activation in rats at 7 T.

M. Grüne, F. A. van Dorsten, W. Schwindt, L. Olàh, M. Hoehn
Magn. Reson. Med. 1999, 42, 1027-1032
Quantitative T2* and T2' maps during reversible focal cerebral ischemia in rats: separation of blood oxygenation from nonsusceptibility-based contributions.

C. Delmas, M. Ménétrier, L. Croguennec, I. Saadoune, A. Rougier, C. Pouillerie, G. Prado, M. Grüne, L.Fournès
Electrochemica Acta 1999, 45, 243-253
An overview of the Li(Ni,M)O2 systems: syntheses, structures and properties.

G. Bringmann, M. Wohlfahrt, H. Rischer, M. Grüne, J. Schlauer
Angew. Chem. Int. Ed. 2000, 39, 1464-1466; Angew. Chem. 2000, 112, 1523-1525
A new biosynthetic pathway to alkaloids in plants: acetogenic isoquinolines.

F. Pillekamp, M. Grüne, G. Brinker, C. Franke, U. Uhlenküken, M. Hoehn, K.-A. Hossmann
Magn. Reson. Imag. 2001, 19, 143-152
Magnetic resonance prediction of outcome after thrombolytic treatment.

F.-G. Lehnhardt, G. Röhn, R.-I. Ernestus, M. Grüne, M. Hoehn
NMR Biomed. 2001, 14, 307-317
1H- and 31P-NMR spectroscopy of primary and recurrent human brain tumors in vitro: malignancy-characteristic profiles of water soluble and lipophilic spectral components.

W. Adam, M. Grüne, M. Diedering, A. V. Trofimov
J. Am. Chem. Soc. 2001, 123, 7109-7112
Temperature and viscosity dependence in the stereoselective formation of the inverted housane for the photochemical nitrogen loss from the deuterium-stereolabeled parent diazabicyclo[2.2.1]hept-2-ene.

F. A. van Dorsten, L. Olàh, W. Schwindt, M. Grüne, U. Uhlenküken, F. Pillekamp, K.-A. Hossmann, M. Hoehn
Magn. Reson. Med. 2002, 47, 97-104
Dynamic changes of ADC, perfusion, and NMR relaxation parameters in transient focal ischemia of rat brain.

W. Adam, M. A. Arnold, M. Grüne, W. N. Nau, U. Pischel, C. R. Saha-Möller
Org. Lett. 2002, 4, 537-540
Spiroiminodihydantoin is a major product in the photooxidation of 2'-deoxyguanosine by the triplet states and oxyl radicals generated from hydroxyacetophenone photolysis and dioxetane thermolysis.

G. Bringmann, K. Messer, K. Wolf, J. Mühlbacher, M. Grüne, R. Brun, A. M. Louis
Phytochemistry 2002, 60, 389-397
Dioncophylline E from Dioncophyllum thollonii, the first 7,3'-coupled dioncophyllaceous naphthylisoquinoline alkaloid.

M. Guilmard, A. Rougier, M. Grüne, L. Croguennec, C. Delmas
J. Power Sources 2003, 115, 305-314
Effects of aluminium on the structural and electrochemical properties of LiNiO2.

S. L. Grage, S. Afonin, M. Grüne, A. S. Ulrich
Chem. Phys. Lipids 2004, 132, 65-77
Interaction of the fusogenic peptide B18 in its amyloid-state with lipid membranes studied by solid state NMR.

R. Dobrawa, M. Lysetska, P. Ballester, M. Grüne, F. Würthner
Macromolecules 2005, 38, 1315–1325
Fluorescent supramolecular polymers: metal directed self-assembly of perylene bisimide building blocks.

G. Bringmann, T.F. Noll, T.A.M. Gulder, M. Grüne, M. Dreyer, C. Wilde, F. Pankewitz, M. Hilker, G.D. Payne, A.L. Jones, M. Goodfellow, H.-P. Fiedler
Nature Chem. Biol. 2006, 2, 429-433
Different polyketide folding modes converge to an identical molecular architecture.

C.-C. You, C. Hippius, M. Grüne, F. Würthner
Chem. Eur. J. 2006, 12, 7510–7519
Light-harvesting metallosupramolecular squares composed of perylene bisimide walls and fluorescent antenna dyes.

G. Bringmann, T. F. Noll, M. Dreyer, T. Gulder, M. Grüne, D. Moskau
J. Org. Chem. 2007, 72, 3247-3252
Polyketide folding in higher plants: biosynthesis of the phenylanthraquinone knipholone.

A. Lohr, M. Grüne, F. Würthner
Chem. Eur. J. 2009, 15, 3691–3705
Self-assembly of bis(merocyanine) tweezers into discrete bimolecular π-stacks.

R. Schmidt, M. Stolte, M. Grüne, F. Würthner
Macromolecules 2011, 44, 3766–3776
Hydrogen-bond-directed formation of supramolecular polymers incorporating head-to-tail oriented dipolar merocyanine dyes.

M. M. Safont-Sempere, P. Osswald, M. Stolte, M. Grüne, M. Renz, M. Kaupp, K. Radacki, H. Braunschweig, F. Würthner
J. Am. Chem. Soc. 2011, 133, 9580–9591
Impact of molecular flexibility on binding strength and self-sorting of chiral π-surfaces.

C. Shao, M. Grüne, M. Stolte, F. Würthner
Chem. Eur. J. 2012, 18, 13665–13677
Perylene bisimide dimer aggregates: fundamental insight into self-assembly by NMR and UV/Vis spectroscopy.

B. Fimmel, M. Son, Y. M. Sung, M. Grüne, B. Engels, D. Kim, F. Würthner
Chem. Eur. J. 2015, 21, 615–630
Phenylene ethynylene-tethered perylene bisimide folda-dimer and folda-trimer: Investigations of folding features in ground and excited states.

C. Cheng, E. M. Othman, A. Reimer, M. Grüne, V. Kozjak-Pavlovic, H. Stopper, U. Hentschel, U. R. Abdelmohsen
Tetrahedron Letters 2016, 57, 2786-2789
Ageloline A, new antioxidant and antichlamydial quinolone from the marine sponge-derived bacterium Streptomyces sp. SBT345.

M. Arrowsmith, D. Auerhammer, R. Bertermann, H. Braunschweig, G. Bringmann, M. A. Celik, R. D. Dewhurst, M. Finze, M. Grüne, M. Hailmann, T. Hertle, I. Krummenacher
Angew. Chem. Int. Ed. 2016, 55, 14464-14468; Angew. Chem. 2016, 128, 14680-14684
Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.

P. Maier, M. Grüne, M. Lehmann
Chem. Eur. J. 2017, 23, 1018-1022
A Star-shaped Oligo(phenylenevinylene) Liquid Crystal Host with an Anthracene Guest – A Double Nanosegregating Supermesogen.

M. Lehmann, P. Maier, M. Grüne, M. Hügel
Chem. Eur. J. 2017, 23, 1060-1068
Crowded Star Mesogens: Guest-Controlled Stability of Mesophases from Unconventional Liquid-Crystal Molecules.

C. Kerpen, J. A. P. Sprenger, L. Herkert, M. Schäfer, L. A. Bischoff, P. Zeides, M. Grüne, R. Bertermann, F. A. Brede, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze
Angew. Chem. Int. Ed. 2017, 56, 2800-2804
Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions.

B. Gole, V. Stepanenko, S. Rager, M. Grüne, D. D. Medina, T. Bein, F. Würthner, F. Beuerle
Angew. Chem. Int. Ed. 2018, 57, 846–850
Microtubular Self-Assembly of Covalent Organic Frameworks.

J. Landmann, J. A. P. Sprenger, P. T. Hennig, R. Bertermann, M. Grüne, F. Würthner, N. V. Ignat'ev, M. Finze
Chem. Eur. J. 2018, 24, 608-623
Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscoity Ionic Liquids.

L. A. Bischoff, M. Drisch, C. Kerpen, P. T. Hennig, J. Landmann, J. A. P. Sprenger, R. Bertermann, M. Grüne, Q. Yuan, J. Warneke, X. Wang, N. Ignat'ev, M. Finze
Chem. Eur. J. 2019, 25, 3560-3574
Cyanohydridoborate Anions: Synthesis, Salts, and Low-viscosity Ionic Liquids.

E. Kirchner, D. Bialas, F. Fennel, M. Grüne, F. Würthner
J. Am. Chem. Soc. 2019, 141, 7428-7438
Defined Merocyanine Dye Stacks from a Dimer up to an Octamer by Spacer-Encoded Self-Assembly Approach.

X. Hu, A. Schulz, J. O. Lindner, M. Grüne, D. Bialas, F. Würthner
Chem. Sci. 2021, 12, 8342-8352
Folding and fluorescence enhancement with strong odd–even effect for a series of merocyanine dye oligomers.

M. Weh, A. A. Kroeger, K. Shoyama, M. Grüne, A. Karton, F. Würthner
Angew. Chem. Int. Ed. 2023, 62(19)
π-π Catalysis Made Asymmetric-Enantiomerization Catalysis Mediated by the Chiral π-System of a Perylene Bisimide Cyclophane.