Arbeitsgruppe Braunschweig

Latest Publications


Prof. Holger Braunschweig has published 700 manuscripts since 1990, the majority of which appeared in first ranking journals such as ScienceNatureNature ChemistryAngewandte ChemieChemistry - A European Journal,...  

Latest Publications 2023/2024 

704 M. Dietz, M. Arrowsmith, H. Braunschweig
CAAC-stabilised 9,10-diboraanthracene: an electronically and structurally flexible platform for small-molecule activation and metal complexation
Dalton Trans. 202453,  449-453.
703 M. Härterich, A. Matler, R. D. Dewhurst, A. Sachs, K. Oppel, A. Stoy, H. Braunschweig
A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl
Nature Communications 202314, Article number: 2764.
702 P. Saha, N. Chrysochos, B. J. Elvers, S. Pätsch, S. I. Uddin, I. Krummenacher, M. Nandeshwar, G. P. Sankar, H. Braunschweig, P. Ravat, C. Schulzke, A. Jana
Bis-Olefin Based Crystalline Schlenk Hydrocarbon Diradicals with a Triplet Ground State
Angew. Chem. 2023135, e202311868; Angew. Chem. Int. Ed. 202362, e202311868.
701 S. Nees, T. Wellnitz, F. Dankert, S. Dotzauer, M. Härterich, M. Feldt, H. Braunschweig, C. Hering-Junghans
On the Reactivity of Phosphaalumenes towards C−C Multiple Bonds
Angew. Chem. 2023135, e202215838; Angew. Chem. Int. Ed. 202362, e202215838.
700 T. Brückner, B. Ritschel, J. O. C. Jiménez-Halla, F. Fantuzzi, D. Duwe, R. D. Dewhurst, H. Braunschweig
Metal-Free Intermolecular C–H Borylation of N-Heterocycles at B–B Multiple Bonds
Angew. Chem. 2023135, e202213284; Angew. Chem. Int. Ed. 202362, e202213284.
699 L. C. Haufe, L. Endres, M. Arrowsmith, R. Bertermann, M. Dietz, F. Fantuzzi, M. Finze, H. Braunschweig
Boron Insertion into the N≡N bond of a Tungsten Dinitrogen Complex
J. Am. Chem. Soc. 2023145, 23986–23993.
698 M. Heinz, M. Arrowsmith, J. I. Schweizer, I. Krummenacher, M. C. Holthausen, H. Braunschweig
Experimental and Computational Study of a Confirmed Borylene-to-Diborene Dimerization
J. Am. Chem. Soc. 2023145, 22685–22696.
697 M. Dietz, M. Arrowsmith, L. Endres, V. Paprocki, B. Engels, H. Braunschweig
Synthesis and Reactivity of Highly Electron-Rich Zerovalent Group 10 Diborabenzene Pogo-Stick and Half-Sandwich Complexes
J. Am. Chem. Soc. 2023145, 22222–22231.
696 M. Dietz, M. Arrowsmith, K. Drepper, A. Gärtner, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig
Structure and Electronics of a Series of CAAC-Stabilized Diboron-Doped Acenes from 1,4-Diboranaphthalene to 6,13-Diborapentacenes
J. Am. Chem. Soc. 2023145, 15001–15015.
695 A. Gärtner, U. S. Karaca, M. Rang, M. Heinz, P. D. Engel, I. Krummenacher, M. Arrowsmith, A. Hermann, A. Matler, A. Rempel, R. Witte, H. Braunschweig, M. C. Holthausen, M.-A. Légaré
Achieving Control over the Reduction/Coupling Dichotomy of N2 by Boron Metallomimetics
J. Am. Chem. Soc. 2023145, 8231–8241.
694 J. L. Bohlen, L. Endres, R. Drescher, K. Radacki, M. Dietz, I. Krummenacher, H. Braunschweig
Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation
Chem. Sci. 202314, 9010-9015.
693 Y. K. J. Bejaoui, F. Philippi, H.-G. Stammler, K. Radacki, L. Zapf, N. Schopper, K. Goloviznina, K. A. M. Maibom, R. Graf, J. A. P. Sprenger, R. Bertermann, H. Braunschweig, T. Welton, N. V. Ignat´ev, M. Finze
Insights to structure-property relationships in ionic liquids using cyclic perfluoroalkylsulfonylimides
Chem. Sci. 202314, 2200-2214.
692 S. Jana, B. J. Elvers, S. Pätsch, P. Sarkar, I. Krummenacher, M. K. Nayak, A. Maiti, N. Chrysochos, S. K. Pati, C. Schulzke, H. Braunschweig, C. B. Yildiz, A. Jana
Air and Moisture Stable para- and ortho-Quinodimethane Derivatives Derived from bis-N-Heterocyclic Olefins
Org. Lett. 202325, 1799–1804.
691 Z. Wu, N. Hippchen, J. Han, L. Ji, A. Friedrich, I. Krummenacher, H. Braunschweig, J. Krebs, M. Moos, P. Biegger, O. Tverskoy, S. Maier, C. Lambert, A. Dreuw, T. B. Marder, J. Freudenberg, U. H. F. Bunz
The Radical Anion and Dianion of Benzo[3,4]cyclobuta[1,2-b]phenazine
J. Org. Chem. 202388, 2742–2749.
690 A. Maiti, B. J. Elvers, S. Bera, F. Lindl, I. Krummenacher, P. Ghosh, H. Braunschweig, C. B. Yildiz, C. Schulzke, H.-G. Korth, A. Jana
Comment on “Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One-Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene-Based Kekulé Diradicaloids”
Chem. Eur. J. 202329, e202302848.
689 W. Lu, N. Hensiek, K. Saha, R. D. Dewhurst, M. Härterich, C. Pranckevicius, S. Hagspiel, M. Dietz, I. Krummenacher H. Braunschweig
Electron-Precise Dicationic Tetraboranes: Syntheses, Structures and Rearrangement to an Alkylidene Borate-Borenium Zwitterion and a 1,3-Azaborinine
Chem. Eur. J. 202329, e202300644.
688 C. Czernetzki, T. Tröster, L. Endres, F. Endres, M. Arrowsmith, A. Gärtner, F. Fantuzzi, H. Braunschweig
Synthesis, Structural Characterization, and Bonding of Molecular Heavier Beryllium Chalcogenides
Chem. Eur. J. 202329, e202301418.
687 F. Schorr, T. Keim, M. Arrowsmith, A. Vargas, R. D. Dewhurst, I. Krummenacher, H. Braunschweig
Thienyl-Substituted Diboranes(4): Electronic Stabilization of Radicals Versus Increased Reactivity towards Bond Activatio
Chem. Eur. J. 202329, e202301286.
686 L. Xiang, J. Wang, I. Krummenacher, K. Radacki, H. Braunschweig, Z. Lin, Q. Ye
Persistent and Predominantly Localized Boron Radical from the Reduction of a Three-dimensional Analogue of NHC-Stabilized Borafluorenium
Chem. Eur. J. 202329, e202301270.
685 D. Dhara, A. Jayaraman, M. Härterich, M. Arrowsmith, M. Jürgensen, M. Michel, H. Braunschweig
Trapping of a Transient Base-Stabilised Alumylene and Alumylene-Type Reactivity of a Self-Stabilising Dialumene towards Organic Azides
Chem. Eur. J. 202329, e202300483.
684 T. Bischof, L. Beßler, I. Krummenacher, L. Erhard, H. Braunschweig, M. Finze
Construction of a Diverse Range of Boron Heterocycles via Ring Expansion of a Carboranyl-Substituted 9-Borafluorene
Chem. Eur. J. 202329, e202300210.
683 R. Witte, M. Arrowsmith, A. Lamprecht, I. Krummenacher, H. Braunschweig
C‒C and C‒N Bond Activation, Lewis-Base Coordination and One- and Two-Electron Oxidation at a Linear Aminoborylene
Chem. Eur. J. 202329, e202203663.
682 F. Lindl, A. Lamprecht, M. Arrowsmith, E. Khitro, A. Rempel, M. Dietz, T. Wellnitz, G. Bélanger-Chabot, A. Stoy, V. Paprocki, D. Prieschl, C. Lenczyk, J. Ramler, C. Lichtenberg H. Braunschweig
Aromatic 1,2-Azaborinin-1-yls as Electron-Withdrawing Anionic Nitrogen Ligands for Main Group Elements
Chem. Eur. J. 202329, e202203345.
681 R. Dolai, B. J. Elvers, T. Singh, N. Chrysochos, R. Kumar, B. Joseph, M. K. Nayak, A. Maiti, A. Jayaraman, I. Krummenacher, J. Mondal, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana
Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC vs. CAAC as Donor Substituents
Chem. Eur. J. 202329, e202202888.
680 V. Zeh, J. S. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten
Poly(ferrocenyleneiminoborane): an inorganic–organic hybrid polymer comprising a backbone of moderately interacting ferrocenes
Chem. Commun. 202359,  13723-13726.
679 N. Chrysochos, S. Pätsch, B. J. Elvers, I. Krummenacher, N. M. Giridhar, G. Prabusankar, H. Braunschweig, C. Schulzke, P. Ravat, A. Jana
Introducing an orthogonally polarized electron-rich alkene synthesis of a zwitterionic boron-Containing π-conjugated system
Chem. Commun. 202359,  12350-12353.
678 A. Lamprecht, F. Lindl, L. Endres, I. Krummenacher, H. Braunschweig
Coinage metal complexes of BN analogues of m-terphenyl ligands
Chem. Commun. 202359,  10149-10152.
677 T. Tröster, F. Endres, M. Arrowsmith, L. Endres, F. Fantuzzi, H. Braunschweig
Dibenzoberylloles: antiaromatic s-block fluorene analogues
Chem. Commun. 202359,  9199-9202.
676 J. S. Schneider, I. Krummenacher, H. Braunschweig, H. Helten
Linear and macrocyclic oligo(p-phenylene iminoboranes) with ferrocenyl side groups – observation of selective, non-templated macrocyclization
Chem. Commun. 202359,  8408-8411.
675 D. Čavlović, O. Blacque, I. Krummenacher, H. Braunschweig, P. Ravat, M. Juríček
Dimethylnonacethrene – en route to a magnetic switch
Chem. Commun. 202359,  7743-7746.
674 T. Bischof, N. Wieprecht, S. Fuchs, L. Endres, I. Krummenacher, M. Michel, C. Mihm, H. Braunschweig, M. Finze
Unlocking Heteroaromatic Ring Systems through Chalcogen Insertion into Boroles
Inorg. Chem. 202362,  21329–21335.
673 B. Chakraborty, F. E. Basumatary, H. Braunschweig, A. K. Phukan
Cooperative Activation of Small Molecules by Base-Stabilized Borylenes
Inorg. Chem. 202362,  9063–9076.
672 D. Čavlović, O. Blacque, I. Krummenacher, H. Braunschweig, P. Ravat, M. Juríček
Dimethylnonacethrene – En Route to a Magnetic Switch
ChemRxiv 2023,doi: 10.26434/chemrxiv-2023-3fbgs.
671 S. Huynh, M. Arrowsmith, L. Meier, M. Dietz, M. Härterich, M. Michel, A. Gärtner, H. Braunschweig
Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study
Dalton Trans. 202352,  3869-3876.
670 J. Weiser, J. Cui, R. D. Dewhurst, H. Braunschweig, B. Engels, F. Fantuzzi
Structure and bonding of proximity-enforced main-group dimers stabilized by a rigid naphthyridine diimine ligand
J. Comput. Chem. 202344,  456-467.
669 S. Nees, H. Beer, P. Just, L. M. Teichmeier, L. E. Christoffer, A. Guljam, Kushik, H. Braunschweig, C. Hering-Junghans
On the reactivity of Mes*P(PMe3) towards Al(I) compounds - Evidence for the Intermediate Formation of Phosphaalumenes
ChemPlusChem 2023 202388,  e202300078.
668 D. E. Trujillo-González, G. G. García, T. A. Hamlin, F. M. Bickelhaupt, H. Braunschweig, J. O. C. Jiménez-Halla, M. Solà
The Search for Enhanced σ-Donor Ligands to Stabilize Boron-Boron Multiple Bonds
Eur. J. Inorg. Chem. 202326,  e202200767.


For a full list of publications visit our Group homepage