Latest Publications
Prof. Holger Braunschweig has published over 660 manuscripts since 1990, the majority of which appeared in first ranking journals such as Science, Nature, Nature Chemistry, Angewandte Chemie, Chemistry - A European Journal,...
Latest Publications 2022/2023
| 670 | T. Brückner, B. Ritschel, J. O. C. Jiménez-Halla, F. Fantuzzi, D. Duwe, R. D. Dewhurst, H. Braunschweig Metal-Free Intermolecular C–H Borylation of N-Heterocycles at B–B Multiple Bonds Angew. Chem. 2023, 135, e202213284; Angew. Chem. Int. Ed. 2023, 62, e202213284. |
| 669 | R. Dolai, B. J. Elvers, T. Singh, N. Chrysochos, R. Kumar, B. Joseph, M. K. Nayak, A. Maiti, A. Jayaraman, I. Krummenacher, J. Mondal, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC vs. CAAC as Donor Substituents Chem. Eur. J. 2023, 29, e202202888. |
| 668 | J. Weiser, J. Cui, R. D. Dewhurst, H. Braunschweig, B. Engels, F. Fantuzzi Structure and bonding of proximity-enforced main-group dimers stabilized by a rigid naphthyridine diimine ligand J. Comput. Chem. 2023, 44, 456-467. |
| 667 | M. Dietz, M. Arrowsmith, S. Reichl, L. I. Lugo-Fuentes, J. O. C. Jiménez-Halla, M. Scheer, H. Braunschweig Stable Two-Legged Parent Piano-Stool and Mixed Diborabenzene-E4 (E = P, As) Sandwich Complexes of Group 8 Angew. Chem. 2022, 134, e202206840; Angew. Chem. Int. Ed. 2022, 61, e202206840. |
| 666 | W. Lu, A. Jayaraman, F. Fantuzzi, R. D. Dewhurst, M. Härterich, M. Dietz, S. Hagspiel, I. Krummenacher, K. Hammond, J. Cui, H. Braunschweig An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry Angew. Chem. 2022, 134, e202113947; Angew. Chem. Int. Ed. 2022, 61, e202113947. |
| 665 | A. Gärtner, L. Meier, M. Arrowsmith, M. Dietz, I. Krummenacher, R. Bertermann, F. Fantuzzi, H. Braunschweig A Highly Strained Arene-Fused 1,2-Diborete Biradicaloid J. Am. Chem. Soc. 2022, 144, 21363–21370. |
| 664 | A. Stoy, M. Härterich, R. D. Dewhurst, J. O. Jimenez-Halla, P. Endres, M. Eißelein, T. Kupfer, A. Deissenberger, T. Thiess, H. Braunschweig Evidence for Borylene Carbonyl (LHB=C=O) and Base-Stabilized (LHB=O) and Base-Free Oxoborane (RB≡O) Intermediates in the Reactions of Diborenes with CO2 J. Am. Chem. Soc. 2022, 144, 3376-3380. |
| 663 | J. Krebs, A. Häfner, S. Fuchs, X. Guo, F. Rauch, A. Eichhorn, I. Krummenacher, A. Friedrich, L. Ji, M. Finze, Z. Lin, H. Braunschweig, T. B. Marder Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives Chem. Sci. 2022, 13, 14165-14178. |
| 662 | M. K. Nayak, P. Sarkar, B. J. Elvers, I. Krummenacher, F. Zhang, T. Vijayakanth, R. Narayanan, R. Dolai, B. Roy, V. Malik, H. Rawat, P. Ravat, R. Boomishankar, S. K. Pati, C. Schulzke, H. Braunschweig, A. Jana A bis-NHC-CAAC dimer derived dicationic diradical Chem. Sci. 2022, 13, 12533-12539. |
| 651 | D. Dhara, F. Fantuzzi, M. Härterich, R. D. Dewhurst, I. Krummenacher, M. Arrowsmith, C. Pranckevicius, H. Braunschweig Stepwise reduction of a base-stabilised ferrocenyl aluminium(III) dihalide for the synthesis of structurally-diverse dialane species Chem. Sci. 2022, 13, 9693–9700. |
| 660 | L. Kuehn, L. Zapf, L. Werner, M. Stang, S. Würtemberger-Pietsch, I. Krummenacher, H. Braunschweig, E. Lacôte, U. Radius, T. B. Marder NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions Chem. Sci. 2022, 13, 8321-8333. |
| 659 | A. Okorn, A. Jayaraman, L. Englert, M. Arrowsmith, T. Swoboda, J. Weigelt, C. Brunecker, M. Hess, A. Lamprecht, C. Lenczyk, M. Rang, H. Braunschweig Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B‒C bond cleavage Chem. Sci. 2022, 13, 7566-7574. |
| 658 | T. Bischof, X. Guo, I. Krummenacher, L. Beßler, Z. Lin, M. Finze, H. Braunschweig Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene Chem. Sci. 2022, 13, 7492-7497. |
| 657 | D. Dhara, A. Jayaraman, M. Härterich, R. D. Dewhurst, H. Braunschweig Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules Chem. Sci. 2022, 13, 5631-5638. |
| 656 | F. Fantuzzi, Y. Jiao, R. D. Dewhurst, F. Weinhold, H. Braunschweig, B. Engels Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes? Chem. Sci. 2022, 13, 5118-5129. |
| 655 | S. Fuchs, A, Jayaraman, I. Krummenacher, L. Haley, M. Baštovanović, M. Fest, K. Radacki, H. Helten, H. Braunschweig Diboramacrocycles: reversible borole dimerisation-dissociation systems Chem. Sci. 2022, 13, 2932-2938. |
| 654 | A. K. Swain, K. Radacki, H. Braunschweig, P. Ravat Pyrene-Fused [7]Helicenes Connected via Hexagonal and Heptagonal Rings: Stereospecific Synthesis and Chiroptical Properties J. Org. Chem. 2022, 87, 993-1000. |
| 653 | T. Wiesner, Z. Wu, J. Han,L. Ji, A. Friedrich, I. Krummenacher, M. Moos, C. Lambert, H. Braunschweig, B. Rudin, H. Reiss, O. Tverskoy, F. Rominger, A. Dreuw, T. B. Marder, J. Freudenberg, U. H. F. Bunz The Radical Anion, Dianion and Electron Transport Properties of Tetraiodo-Tetraazapentacene Chem. Eur. J. 2022, 28, e202201919. |
| 652 | J. Bachmann, A. Helbig, M. Crumbach, I. Krummenacher, H. Braunschweig, H. Helten Fusion of Aza- and Oxadiborepins with Furans in a Reversible Ring-Opening Process Furnishes Versatile Building Blocks for Extended π-Conjugated Materials Chem. Eur. J. 2022, 28, e202202455. |
| 651 | F. Full, Q. Wölflick, K. Radacki, H. Braunschweig, A. Nowak-Król Enhanced Optical Properties of Azaborole Helicenes by Lateral and Helical Extention Chem. Eur. J. 2022, 28, e202202280. |
| 650 | S. Hagspiel, F. Fantuzzi, M. Arrowsmith, A. Gärtner, M. Fest, J. Weiser, B. Engels, H. Helten, H. Braunschweig Modulation of the Naked-eye and Fluorescence Colour of a Protonated Boron-doped Thiazolothiazole by Anion-dependent Hydrogen Bonding Chem. Eur. J. 2022, 28, e202201398. |
| 649 | M. Ferger, C. Roger, E. Köster, F. Rauch, S. Lorenzen, I. Krummenacher, A. Friedrich, M. Košćak, D. Nestić, H. Braunschweig, C. Lambert, I. Piantanida, T. B.Marder Electron-Rich EDOT Linkers in Tetracationic bis-Triarylborane Chromophores: Influence on Water-Stability, Bio-macromolecule Sensing, and Photoinduced Cytotoxicity Chem. Eur. J. 2022, 28, e202201130. |
| 648 | G. K. Kole, M. Košćak, A. Amar, D. Majhen, K. Božinović, Z. Brkljaca, M. Ferger, E. Michail, S. Lorenzen, A. Friedrich, I. Krummenacher, M. Moos, H. Braunschweig, A. Boucekkine, C. Lambert, J.-F. Halet, I. Piantanida, K. Müller-Buschbaum, T. B. Marder Methyl Viologens of Bis-(4'-Pyridylethynyl)Arenes - Structures, Photophysical and Electrochemical Studies, and their Potential Application in Biology Chem. Eur. J. 2022, 28, e202200753. |
| 647 | A. Maiti, B. J. Elvers, S. Bera, F. Lindl, I. Krummenacher, P. Ghosh, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One-Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene-Based Kekulé Diradicaloids Chem. Eur. J. 2022, 28, e202104567. |
| 646 | M. Huang, J. Hu, I. Krummenacher, A. Friedrich, H. Braunschweig, S. A. Westcott, U. Radius, T. B. Marder Probing the Potential of Hitherto Unexplored Base-Stabilized Borylenes in Dinitrogen Binding Chem. Eur. J. 2022, 28, e202104123. |
| 645 | F. Fantuzzi, R. Moral, R. D. Dewhurst, H. Braunschweig, A. K. Phukan Base-Mediated Radical Borylation of Alkyl Sulfones Chem. Eur. J. 2022, 28, e202103866. |
| 644 | J. Cui, J. Weiser, F. Fantuzzi, M. Dietz, Y. Yatsenko, A. Häfner, S. Nees, I. Krummenacher, M. Zhang, K. Hammond, P. Roth, W. Lu, R. D. Dewhurst, B. Engels, H. Braunschweig A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor Chem. Commun. 2022, 58, 13357-13360. |
| 643 | F. Lindl, F. Fantuzzi, L. Mailänder, C. Hörl, G. Bélanger-Chabot, H. Braunschweig Azidoborolate anions and azidoborole adducts: isolable forms of an unstable borole azide Chem. Commun. 2022, 58, 4735-4738. |
| 642 | S. Kachel, A. Jayaraman, A. Okorn, I. Krummenacher, R. Drescher, C. Brunecker, S. Fuchs, M. Heß, T. E. Stennett, H. Braunschweig Azide-alkyne cycloadditions with an electronically activated alkyne: indole formation via 1-aryl-1,2,3-triazole-derived imino carbenes Chem. Commun. 2022, 58, 2331-2334. |
| 641 | M. Dömling, T. E. Stennett, A. Belyaev, B. Hupp, C. Claes, S. Ullrich, S. Endres, E. Freytag, T. Kramer, T. Kupfer, F. Schorr, T. Thiess, M. Arrowsmith, A. Steffen, H. Braunschweig Synthesis and Fluorescence Studies of Diborene Coinage Metal Complexes Inorg. Chem. 2022, 61, 14058–14066. |
| 640 | L. C. Haufe, M. Arrowsmith, M. Dietz, A. Gärtner, R. Bertermann, H. Braunschweig Spontaneous N2-diboranylation of [W(N2)2(dppe)2] with B2Br4(SMe2)2 Dalton Trans. 2022, 51, 12786-12790. |
| 639 | G. Horrer, I. Krummenacher, S. Mann, H. Braunschweig, U. Radius N-Heterocyclic carbene and cyclic (alkyl)(amino)carbene complexes of vanadium(III) and vanadium(V) Dalton Trans. 2022, 51, 11054-11071. |
| 638 | F. Schorr, M. Arrowsmith, F. Fantuzzi, A. Rempel, H. Braunschweig 1,2-Dialkynyldiboranes(4): B–B versus C≡C bond reactivity Dalton Trans. 2022, 51, 6197–6203. |
| 637 | J. Selby, M. Holzapfel, K. Radacki, A. K. Swaina, H. Braunschweig, C. Lambert Polymeric Indolenine-Squaraine Foldamers with a Preferred Helix Twist Sense and their Chiroptical Absorption and Emission Properties Macromolecules 2022, 55, 421–436. |
| 636 | P. Mentzel, M. Holzapfel, A. Schmiedel, I. Krummenacher, H. Braunschweig, A. Wodynski, M. Kaupp, F. Würthner, C. Lambert Excited states and spin-orbit coupling in chalcogen substituted perylene diimides and their radical anions Phys. Chem. Chem. Phys. 2022, 24, 26254-26268. |
For a full list of publications visit our Group homepage www.braunschweiggroup.de.
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