Arbeitsgruppe Braunschweig

Latest Publications


Prof. Holger Braunschweig has published over 650 manuscripts since 1990, the majority of which appeared in first ranking journals such as ScienceNatureNature ChemistryAngewandte ChemieChemistry - A European Journal,...  

Latest Publications 2022 

657 M. Dietz, M. Arrowsmith, S. Reichl, L. I. Lugo-Fuentes, J. O. C. Jiménez-Halla, M. Scheer, H. Braunschweig
Stable Two-Legged Parent Piano-Stool and Mixed Diborabenzene-E4 (E = P, As) Sandwich Complexes of Group 8
Angew. Chem. 2022134, e202206840; Angew. Chem. Int. Ed. 202261, e202206840.
656 W. Lu, A. Jayaraman, F. Fantuzzi, R. D. Dewhurst, M. Härterich, M. Dietz, S. Hagspiel, I. Krummenacher, K. Hammond, J. Cui, H. Braunschweig
An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry
Angew. Chem. 2022134, e202113947; Angew. Chem. Int. Ed. 202261, e202113947.
655 A. Stoy, M. Härterich, R. D. Dewhurst, J. O. Jimenez-Halla, P. Endres, M. Eißelein, T. Kupfer, A. Deissenberger, T. Thiess, H. Braunschweig
Evidence for Borylene Carbonyl (LHB=C=O) and Base-Stabilized (LHB=O) and Base-Free Oxoborane (RB≡O) Intermediates in the Reactions of Diborenes with CO2
J. Am. Chem. Soc. 2022144, 3376-3380.
654 L. Kuehn, L. Zapf, L. Werner, M. Stang, S. Würtemberger-Pietsch, I. Krummenacher, H. Braunschweig, E. Lacôte, U. Radius, T. B. Marder
NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions
Chem. Sci. 202213,  8321-8333.
653 A. Okorn, A. Jayaraman, L. Englert, M. Arrowsmith, T. Swoboda, J. Weigelt, C. Brunecker, M. Hess, A. Lamprecht, C. Lenczyk, M. Rang, H. Braunschweig
Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B‒C bond cleavage
Chem. Sci. 202213,  7566-7574.
652 T. Bischof, X. Guo, I. Krummenacher, L. Beßler, Z. Lin, M. Finze, H. Braunschweig
Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene
Chem. Sci. 202213,  7492-7497.
651 D. Dhara, A. Jayaraman, M. Härterich, R. D. Dewhurst, H. Braunschweig
Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules
Chem. Sci. 202213,  5631-5638.
650 F. Fantuzzi, Y. Jiao, R. D. Dewhurst, F. Weinhold, H. Braunschweig, B. Engels
Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?
Chem. Sci. 202213,  5118-5129.
649 S. Fuchs, A, Jayaraman, I. Krummenacher, L. Haley, M. Baštovanović, M. Fest, K. Radacki, H. Helten, H. Braunschweig
Diboramacrocycles: reversible borole dimerisation-dissociation systems
Chem. Sci. 202213, 2932-2938.
648 A. K. Swain, K. Radacki, H. Braunschweig, P. Ravat
Pyrene-Fused [7]Helicenes Connected via Hexagonal and Heptagonal Rings: Stereospecific Synthesis and Chiroptical Properties
J. Org. Chem. 202287, 993-1000.
647 S. Hagspiel, F. Fantuzzi, M. Arrowsmith, A. Gärtner, M. Fest, J. Weiser, B. Engels, H. Helten, H. Braunschweig
Modulation of the Naked-eye and Fluorescence Colour of a Protonated Boron-doped Thiazolothiazole by Anion-dependent Hydrogen Bonding
Chem. Eur. J. 202228, e202201398.
646 M. Ferger, C. Roger, E. Köster, F. Rauch, S. Lorenzen, I. Krummenacher, A. Friedrich, M. Košćak, D. Nestić, H. Braunschweig, C. Lambert, I. Piantanida, T. B.Marder
Electron-Rich EDOT Linkers in Tetracationic bis-Triarylborane Chromophores: Influence on Water-Stability, Bio-macromolecule Sensing, and Photoinduced Cytotoxicity
Chem. Eur. J. 202228, e202201130.
645 G. K. Kole, M. Košćak, A. Amar, D. Majhen, K. Božinović, Z. Brkljaca, M. Ferger, E. Michail, S. Lorenzen, A. Friedrich, I. Krummenacher, M. Moos, H. Braunschweig, A. Boucekkine, C. Lambert, J.-F. Halet, I. Piantanida, K. Müller-Buschbaum, T. B. Marder
Methyl Viologens of Bis-(4'-Pyridylethynyl)Arenes - Structures, Photophysical and Electrochemical Studies, and their Potential Application in Biology
Chem. Eur. J. 202228, e202200753.
644 A. Maiti, B. J. Elvers, S. Bera, F. Lindl, I. Krummenacher, P. Ghosh, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana
Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One-Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene-Based Kekulé Diradicaloids
Chem. Eur. J. 202228, e202104567.
643 M. Huang, J. Hu, I. Krummenacher, A. Friedrich, H. Braunschweig, S. A. Westcott, U. Radius, T. B. Marder
Probing the Potential of Hitherto Unexplored Base-Stabilized Borylenes in Dinitrogen Binding
Chem. Eur. J. 202228, e202104123.
642 F. Fantuzzi, R. Moral, R. D. Dewhurst, H. Braunschweig, A. K. Phukan
Base-Mediated Radical Borylation of Alkyl Sulfones
Chem. Eur. J. 202228, e202103866.
641 F. Lindl, F. Fantuzzi, L. Mailänder, C. Hörl, G. Bélanger-Chabot, H. Braunschweig
Azidoborolate anions and azidoborole adducts: isolable forms of an unstable borole azide
Chem. Commun. 202258, 4735-4738.
640 S. Kachel, A. Jayaraman, A. Okorn, I. Krummenacher, R. Drescher, C. Brunecker, S. Fuchs, M. Heß, T. E. Stennett, H. Braunschweig
Azide-alkyne cycloadditions with an electronically activated alkyne: indole formation via 1-aryl-1,2,3-triazole-derived imino carbenes
Chem. Commun. 202258, 2331-2334.
639 L. C. Haufe, M. Arrowsmith, M. Dietz, A. Gärtner, R. Bertermann, H. Braunschweig
Spontaneous N2-diboranylation of [W(N2)2(dppe)2] with B2Br4(SMe2)2
Dalton Trans. 202251,  12786-12790.
638 G. Horrer, I. Krummenacher, S. Mann, H. Braunschweig, U. Radius
N-Heterocyclic carbene and cyclic (alkyl)(amino)carbene complexes of vanadium(III) and vanadium(V)
Dalton Trans. 202251,  11054-11071.
637 F. Schorr, M. Arrowsmith, F. Fantuzzi, A. Rempel, H. Braunschweig
1,2-Dialkynyldiboranes(4): B–B versus C≡C bond reactivity
Dalton Trans. 202251,  6197–6203.
636 J. Selby, M. Holzapfel, K. Radacki, A. K. Swaina, H. Braunschweig, C. Lambert
Polymeric Indolenine-Squaraine Foldamers with a Preferred Helix Twist Sense and their Chiroptical Absorption and Emission Properties
Macromolecules 202255, 421–436.


For a full list of publications visit our Group homepage www.braunschweiggroup.de.