Arbeitsgruppe Braunschweig

Latest Publications


Prof. Holger Braunschweig has published over 570 manuscripts since 1990, the majority of which appeared in first ranking journals such as ScienceNatureNature ChemistryAngewandte ChemieChemistry - A European Journal,...  

Latest Publications 2020 

576 C. Saalfrank, F. Fantuzzi, T. Kupfer, B. Ritschel, K. Hammond, I. Krummenacher, R. Bertermann, R. Wirthensohn, M. Finze, P. Schmid, V. Engel, B. Engels, H. Braunschweig
cAAC-Stabilized 9,10-diboraanthracenes – Acenes with Open-Shell Singlet Biradical Ground States
Angew. Chem. 2020132, 19502–19507; Angew. Chem. Int. Ed. 202059, 19338–19343.
575 S. Nees, T. Kupfer, A. Hofmann, H. Braunschweig
Planar Cyclopenten-4-yl Cations – Highly Delocalized π Aromatics Stabilized by Hyperconjugation
Angew. Chem. 2020132, 18971–18978; Angew. Chem. Int. Ed. 202059, 18809–18815.
574 A. Hermann, F. Fantuzzi, M. Arrowsmith, T. Zorn, I. Krummenacher, B. Ritschel, K. Radacki, B. Engels, H. Braunschweig
Oxidation, Coordination and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene
Angew. Chem. 2020132, 15847–15855; Angew. Chem. Int. Ed. 202059, 15717–15725.
573 T. Thiess, G. Bélanger-Chabot, F. Fantuzzi, M. Michel, M. Ernst, B. Engels, H. Braunschweig
Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes
Angew. Chem. 2020132, 15608–15614; Angew. Chem. Int. Ed. 202059, 15480–15486.
572 V. Paprocki, P. Hrobárik, K. L. M. Harriman, M. S. Luff, T. Kupfer, M. Kaupp, M. Murugesu, H. Braunschweig
Stable Actinide π Complexes of a Neutral 1,4-Diborabenzene
Angew. Chem. 2020132, 13209–13216; Angew. Chem. Int. Ed. 202059, 13109–13115.
571 Z. Huang, S. Wang, R. D. Dewhurst, N. V. Ignat'ev, M. Finze, H. Braunschweig
Boron: Its Role in Energy-Related Processes and Applications
Angew. Chem. 2020132, 8882–8900; Angew. Chem. Int. Ed. 202059, 8800–8816.
570 J. H. Müssig, P. Lisinetskaya, R. D. Dewhurst, R. Bertermann, M. Thaler, R. Mitrić, H. Braunschweig
Tetraiododiborane(4) (B2I4) is an Polymer based on sp3 Boron in the Solid State
Angew. Chem. 2020132, 5574–5579; Angew. Chem. Int. Ed. 202059, 5531–5535.
569 U. Schmidt, L. Werner, M. Arrowsmith, A. Deißenberger, A. Hermann, A. Hofmann, S. Ullrich, J. D. Mattock, A. Vargas, H. Braunschweig
Trans-selective Insertional Dihydroboration of a cis-Diborene: Synthesis of Linear sp3-sp2-sp3-Triboranes and Subsequent Cationization
Angew. Chem. 2020132, 333–337; Angew. Chem. Int. Ed. 202059, 325–329.
568 Y.-M. Tian, X.-N. Guo, Z. Wu, A. Friedrich, S. A. Westcott, H. Braunschweig, U. Radius, T. B. Marder
Ni-Catalyzed Traceless, Directed C3-Selective C-H Borylation of Indoles
J. Am. Chem. Soc. 2020142, 13136–13144.
567 A. Hermann, M. Arrowsmith, D. E. Trujillo-Gonzalez, J. O. C. Jiménez-Halla, A. Vargas, H. Braunschweig
Trapping of a Borirane Intermediate in the Reductive Coupling of an Arylborane to a Diborene
J. Am. Chem. Soc. 2020142, 5562–5567.
566 D. Prieschl, G. Bélanger-Chabot, X. Guo, M. Dietz, M. Müller, I. Krummenacher, Z. Lin, H. Braunschweig
Synthesis of Complex Boron-Nitrogen Heterocycles Comprising Borylated Triazenes and Tetrazenes Under Mild Conditions
J. Am. Chem. Soc. 2020142, 1065–1076.
565 M. Heß, T. E. Stennett, F. Fantuzzi, R. Bertermann, M. Schock, M. Schäfer, T. Thiess, H. Braunschweig
Diverse ring-opening reactions of rhodium η4-azaborete complexes
Chem. Sci. 202011, 9134–9140.
564 R. Drescher, S. Lin, A. Hofmann, C. Lenczyk, S. Kachel, I. Krummenacher, Z. Lin, H. Braunschweig
Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum-nitrogen heterocycles
Chem. Sci. 202011, 5559–5564.
563 T. E. Stennett, A. Jayaraman, T. Brückner, L. Schneider, H. Braunschweig
Hydrophosphination of boron-boron multiple bonds
Chem. Sci. 202011, 1335–1341.
562 S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig
Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
Chem. Sci. 202011, 551–555.
561 F. Rauch, P. Endres, A. Friedrich, D. Sieh, M. Hähnel, I. Krummenacher, H. Braunschweig, M. Finze, L. Ji, T. B. Marder
An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers
Chem. Eur. J. 202026, 12951–12963.
560 F. Rauch, S. Fuchs, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
Highly Stable, Readily Reducible, Fluorescent, Trifluoromethylated 9-Borafluorenes
Chem. Eur. J. 202026, 12794–12808.
559 J. Merz, L. Dietrich, J. Nitsch, I. Krummenacher, H. Braunschweig, M. Moos, D. Mims, C. Lambert, T. B. Marder
Synthesis, Photophysical and Electronic Properties of Mono-, Di-, Tri- and Tetra-Amino-Substituted Ortho-Perylenes, and Comparison to the Tetra-Substituted Derivative
Chem. Eur. J. 202026, 12050–12059.
558 F. Rauch, J. Krebs, J. Günther, A. Friedrich, M. Hähnel, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
Electronically-Driven Regioselective Iridium-Catalyzed C-H Borylation of Donor- π-Acceptor Chromophores Containing Triarylboron Acceptors
Chem. Eur. J. 202026, 10626-10633.
557 C. Brunecker, J. H. Müssig, M. Arrowsmith, F. Fantuzzi, A. Stoy, J. Böhnke, A. Hofmann, R. Bertermann, B. Engels, H. Braunschweig
Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes
Chem. Eur. J. 202026, 8518–8523.
556 T. Thiess, M. Ernst, T. Kupfer, H. Braunschweig
Facile Access to Substituted 1,4-Diaza-2,3-Diborinines
Chem. Eur. J. 202026, 2967–2972.
555 J. T. Goettel, H. Gao, S. Dotzauer, H. Braunschweig
MeCAAC=N: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand
Chem. Eur. J. 202026, 1136–1143.
554 J. Merz, M. Dietz, Y. Vonhausen, F. Wöber, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Moos, M. Holzapfel, C. Lambert, T. B. Marder
Synthesis, Photophysical and Electronic Properties of New Red-to-NIR Emitting Donor-Acceptor Pyrene Derivatives
Chem. Eur. J. 202026, 438–453.
553 S. Liu, M.-A. Légaré, T. Dellermann, A. Hofmann, H. Braunschweig
Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds
Chem. Commun. 202056, 7277–7280.
552 D. Prieschl, M. Arrowsmith, M. Dietz, A. Rempel, M. Müller, H. Braunschweig
Synthesis of polyheterocyclic 1,1-diboryltriazenes by γ-nitrogen insertion of azides into activated B-B single bonds
Chem. Commun. 202056, 5681–5684.
551 R. D. Dewhurst, M.-A. Légaré, H. Braunschweig
Towards the catalytic activation of inert small molecules by main-group ambiphiles
Commun. Chem. 20203, Article number: 131.
550 S. Liu, M.-A. Légaré, J. Seufert, D. Prieschl, A. Rempel, L. Englert, T. Dellermann, V. Paprocki, A. Stoy, H. Braunschweig
2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent
Inorg. Chem. 202059, 10866–10873.
549 A. Narsaria, F. Rauch, J. Krebs, P. Endres, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Finze, J. Nitsch, F. M. Bickelhaupt, T. B. Marder
Computationally Guided Molecular Design to Minimize the LE/CT Gap in D-π-A Fluorinated Triarylboranes for Efficient TADF via D and π-Bridge Tuning
Adv. Funct. Mater. 2020, 30 2002064.
548 Z.-F. Jiao, Y.-M. Tian, B. Zhang, C.-H. Hao, Y. Qiao, Y.-X. Wang, Y. Qin, U. Radius, H. Braunschweig, T. B. Marder, X.-N. Guo, X.-Y. Guo
High photocatalytic activity of a NiO nanodot-decorated Pd/SiC Catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and chlorides in air under visible light
J. Catal. 2020, 389 517–524.
547 G. Horrer, M. J. Krahfuß, K. Lubitz, I. Krummenacher, H. Braunschweig, U. Radius
N-Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbine Complexes of Titanium(IV) and Titanium(III)
Eur. J. Inorg. Chem. 2020, 281–291.
546 W. C. Ewing, T. Dellermann, Y. T. A. Wong, J. D. Mattock, A. Vargas, D. L. Bryce, R. D. Dewhurst, H. Braunschweig
π-Complexes of Diborynes and Main Group Atoms
Chem. Asian J. 202015, 1553–1557
545 M. Rang, H. Braunschweig
Die Verkettung zweier Stickstoffmoleküle
Chem. unserer Zeit 202054, 8–9


For a full list of publications visit our Group homepage www.braunschweiggroup.de.