Latest Publications
Prof. Holger Braunschweig has published 750 manuscripts since 1990, the majority of which appeared in first ranking journals such as Science, Nature, Nature Chemistry, Angewandte Chemie, Chemistry - A European Journal,...
Latest Publications 2024/2025
| 753 | E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, M. Michel, K. Hammond, H. Braunschweig Structural stability of a bent tetra(amino)tetraborane ring across four charge states Chem 2025, 11, 102338. |
| 752 | M. Buckel, J. Klopf, J. S. Schneider, A. Lik, N. A. Riensch, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten A fully conjugated meso-boron-substituted porphyrinoid combining Lewis acidity with redox-switchable aromaticity Nat. Commun. 2025,16, Article number: 1775. |
| 751 | Y. Konrad, A. Jayaraman, I. Krummenacher, H. Braunschweig Formation and Metallomimetic Reactivity of a Transient Dicoordinate Alkylborylene Angew. Chem. 2025, 137, e202423669; Angew. Chem. Int. Ed. 2025, 64, e202423669. |
| 750 | P. H. R. Oliveira, M. O. Rodrigues, C. D. G. da Silva, J. Bohlen, M. Arrowsmith, A. Jayaraman, L. Lubczyk, F. Fantuzzi, E. N. da Silva Júnior, H. Braunschweig Straightforward Formation of Borirenes from Boroles and Dialkynes Angew. Chem. 2025, 137, e202423391; Angew. Chem. Int. Ed. 2025, 64, e202423391. |
| 749 | L. Wüst, J. Chorbacher, T. Wellnitz, S. Nees, H. Helten, H. Braunschweig Synthetic access to organyl-substituted 1,2,3-benzodiazaborines with turn-on fluorescence activity Chem. Sci. 2025, 16, 7284-7293. |
| 748 | M. Michel, L. Endres, F. Fantuzzi, I. Krummenacher, H. Braunschweig Harnessing transient CAAC-stabilized mesitylborylenes for chalcogen activation Chem. Sci. 2025, 16, 5632-5639. |
| 747 | M. S. Luff, T. M. Filipovic, C. S. Corsei, K. Oppel, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig, U. Radius Azolium-2-dithiocarboxylates as redox active ligands in nickel chemistry Chem. Sci. 2025, 16, 5142-5154. |
| 746 | A. V. Hauck, P. Komforth, J. Erlenbusch, J. Stickdorn, K. Radacki, H. Braunschweig, P. Besenius, S. Van Herck, L. Nuhn Aliphatic polycarbonates with acid degradable ketal side groups as multi-pH-responsive immunodrug nanocarriers Biomater. Sci. 2025, 13, 1414-1425. |
| 745 | T. Wellnitz, L. Wüst, H. Braunschweig, C. Hering-Junghans A BNAlP-heterocycle Chem. Commun. 2025, 61, 4014–4017. |
| 744 | M. Dietz, M. Arrowsmith, A. Jayaraman, A. Lamprecht, H. Braunschweig Reactivity of a Stable and Highly Electron-Rich (η6-Diborabenzene)nickel(0) Synthon Inorg. Chem. 2025, 64, 1788–1797. |
| 743 | J. S. Schneider, V. Zeh, J. Klopf, P. M. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten Poly(Ferrocenylene Iminoborane) and the Merging of 1,1’-Ferrocenylene with p-Phenylene Iminoborane Building Blocks into Alternating Copolymers, Oligomers, and Macrocycles Chem. Eur. J. 2025, 31, e202404533. |
| 742 | Y. Zhang, A. Matler, J. Krebs, I. Krummenacher, Q. Ye, H. Braunschweig, T. B. Marder, L. Ji Emission-Tunable B←N Lewis Pair-Functionalized Naphthalenes: Synthesis, Structures, and Properties Chem. Eur. J. 2025, 31, e202403973. |
| 741 | F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-m6825. |
| 740 | S. Dotzauer, S. Kar, T. Swoboda, C. Weidemann, A. Häfner, R. D. Dewhurst, H. Braunschweig Synthesis of base-free boriranes and their conversion to borirenes using strong reductant Dalton Trans. 2025, 54, 3857–3862. |
| 739 | B. Chakraborty, R. R. Hazarika, H. Braunschweig, A. K. Phukan Binding of base-stabilized borylenes with transition metals and formation of metal only Lewis pairs Dalton Trans. 2025, 54, 842-850. |
| 738 | L. Euringer, M. Holzapfel, I. Krummenacher, H. Braunschweig, C. Lambert Switching from Transition-State Theory to Solvent-Controlled Adiabatic Charge-Transfer Regime in Bis-Triarylamine Mixed Valence Radical Cations by Modification of the Bridge Electron Density J. Phys. Chem. B 2025, 129, 4197–4206. |
| 737 | D. Dhara, L. Endres, A. Roy, R. D. Dewhurst, R. Bertermann, F. Fantuzzi, H. Braunschweig A Discrete Trialane with a Near-Linear Al3 Axis J. Am. Chem. Soc. 2024, 146, 33536–33542. |
| 736 | F. Zhang, V. Brancaccio, F. Saal, U. Deori, K. Radacki, H. Braunschweig, P. Rajamalli, P. Ravat Ultra-Narrowband Circularly Polarized Luminescence from Multiple 1,4-Azaborine-Embedded Helical Nanographenes J. Am. Chem. Soc. 2024, 146, 29782–29791. |
| 735 | V. Malhotra, B. J. Elvers, R. Dolai, N. Chrysochos, S. S. M. Bandaru, T. Gangber, N. J. Britto, I. Krummenacher, G. Rajaraman, H. Braunschweig, C. Schulzke, A. Jana Cross-Coupling of NHC/CAAC-Based Carbodicarbene: Synthesis of Electron-Deficient Diradicaloids J. Am. Chem. Soc. 2024, 146, 29481–29490. |
| 734 | L. Euringer, M. Holzapfel, I. Krummenacher, M. Franz, S. Richert, H. Braunschweig, C. Lambert Tuning Electron Transfer Coupling and Exchange Interaction in Bis-triarylamine Radical Cations and Dications by Bridge Electron Density J. Am. Chem. Soc. 2024, 146, 27679–27689. |
| 733 | C. Luz, K. Oppel, R. D. Dewhurst, H. Braunschweig, U. Radius Construction of a Boron Chain on a Single Metal by Dehydrocoupling of Borane Ligands J. Am. Chem. Soc. 2024, 146, 23741–23751. |
| 732 | L. Wu, X. Zhang, M. Moos, I. Krummenacher, M. Dietz, A. Jayaraman, R. Bertermann, Q. Ye, M. Finze, M. Wenzel, R. Mitric, C. Lambert, H. Braunschweig, L. Ji Full Electron Delocalization across the Cluster in 1,12-bisBMes2-p-carborane Radical Anion J. Am. Chem. Soc. 2024, 146, 17956–17963. |
| 731 | M. Rang, M. Heinz, A. Halkić, M. Weber, R. D. Dewhurst, A. Rempel, M. Härterich, M. C. Holthausen, H. Braunschweig Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono‑,Tri‑, and Tetrafunctionalized Hydrazines in Two Steps from N2 J. Am. Chem. Soc. 2024, 146, 11048–11053. |
| 730 | A. Das, B. J. Elvers, N. Chrysochos, S. I. Uddin, T. Gangber, I. Krummenacher, D. Borah, A. Mishra, M. Shanmugam, C. B. Yildiz, H. Braunschweig, C. Schulzke, A. Jana Dianionic and Neutral Diboron-Centered Classical Diradicaloids J. Am. Chem. Soc. 2024, 146, 9004–9011. |
| 729 | S. Dotzauer, A. Jayaraman, D. Reinhart, H. Braunschweig Intermolecular 1,2-Aminoboration of Alkynes and the Critical Role of Electron-Rich Alkynes Angew. Chem. 2024, 136, e202413370; Angew. Chem. Int. Ed. 2024, 63, e202413370. |
| 728 | A. Jayaraman, B. Ritschel, M. Arrowsmith, C. Markl, M. Jürgensen, A. Halkić, Y. Konrad, A. Stoy, K. Radacki, H. Braunschweig Experimental Observation of a Terminal Borylene-Dinitrogen Adduct via Cleavage of a 1,2,3,4,5-Diboratriazoline Angew. Chem. 2024, 136, e202412307; Angew. Chem. Int. Ed. 2024, 63, e202412307. |
| 727 | L. Walther, K. Radacki, R. D. Dewhurst, R. Bertermann, M. Finze, H. Braunschweig All-Inorganic sp-Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes Angew. Chem. 2024, 136, e202404930; Angew. Chem. Int. Ed. 2024, 63, e202404930. |
| 726 | M. Weber, T. Kupfer, M. Arrowsmith, R. D. Dewhurst, M. Rang, B. Ritschel, S. Titlbach, M. Ernst, M. Oliveira Rodrigues, E. N. da Silva Júnior, H. Braunschweig Bypassing Ammonia: From N2 to Nitrogen Heterocycles without N1 Intermediates or Transition Metals Angew. Chem. 2024, 136, e202402777; Angew. Chem. Int. Ed. 2024, 63, e202402777. |
| 725 | C. Czernetzki, T. Kunz, S. Huynh, A. Lamprecht, J. Sprenger, M. Finze, M. Arrowsmith, H. Braunschweig Synthesis and Reactivity of Tricoordinate Organoberyllium Azides Angew. Chem. 2024, 136, e202401279; Angew. Chem. Int. Ed. 2024, 63, e202401279. |
| 724 | D. Dhara, L. Endres, I. Krummenacher, M. Arrowsmith, R. D. Dewhurst, B. Engels, R. Bertermann, M. Finze, S. Demeshko, F. Meyer, F. Fantuzzi, H. Braunschweig Synthesis and Reactivity of a Dialane-Bridged Diradical Angew. Chem. 2024, 136, e202401052; Angew. Chem. Int. Ed. 2024, 63, e202401052. |
| 723 | M. Arrowsmith, H. Braunschweig Peter Paetzold (1935‒2023): a Chemist of Many Talents Angew. Chem. 2024, 136, e202319179; Angew. Chem. Int. Ed. 2024, 63, e202319179. |
| 722 | S. Koushik, H. Braunschweig Characterization of a secondary carbon-centred radical Nature Synth. 2024, 3, 677–678. |
| 721 | N. Wieprecht, I. Krummenacher, L. Wüst, M. Michel, S. Fuchs, S. Nees, M. Härterich, H. Braunschweig The forgotten borole: synthesis, properties and reactivity of a 1-boraindene Chem. Sci. 2024, 15, 12496-12501. |
| 720 | A. Swain, K. Radacki, H. Braunschweig, P. Ravat Helically twisted nanoribbons via stereospecific annulative π-extension reaction employing [7]helicene as a molecular wrench Chem. Sci. 2024, 15, 11737-11747. |
| 719 | J. Krebs, L. Brändler, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, B. F. E. Curchod, T. B. Marder Synthesis, Photophysical and Electronic Properties of a D-π-A Julolidine-Like Pyrenyl-o-Carborane Chem. Eur. J. 2024, 30, e202401704. |
| 718 | P. Mentzel, M. Holzapfel, A. Schmiedel, J. Günther, M. Michel, I. Krummenacher, A. Wodyński, M. Kaupp, H. Braunschweig, C. Lambert Structure and Photophysics of N-Tolanyl-phenochalcogenazines and their Radical Cations Chem. Eur. J. 2024, 30, e202303782. |
| 717 | Í. A. O. Bozzi, L. A. Machado, E. B. T. Diogo, F. G. Delolo, L. O. F. Barros, G. A. P. Graça, M. H. Araujo, F. T. Martins, L. F. Pedrosa, L. C. da Luz, F. S. Rodembusch, J. S. F. Guimarães, A. G. Oliveira, S. Röttger, D. B. Werz, C. P. Souza, F. Fantuzzi, T. B. Marder, H. Braunschweig, E. N. da Silva Júnior Electrochemical Diselenation of BODIPY Fluorophores for Bioimaging Applications and Sensitization of 1O2 Chem. Eur. J. 2024, 30, e202303883. |
| 716 | J. L. Bohlen, N. Wieprecht, M. Arrowsmith, A. Häfner, M. Neder H. Braunschweig One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives Chem. Commun. 2024, 60, 14782-14785. |
| 715 | M. S. Luff, K. Oppel, I. Krummenacher, H. Braunschweig, U. Radius Radical anions of 1,1-azoliumdithiocarboxylates Chem. Commun. 2024, 60, 14447-14450. |
| 714 | R. Witte, S. Kar, K. Radacki, M. Härterich, M. Rang, M. Michel, C. Mihm, C. Czernetzki, T. Brückner, E. Beck, S. Lutz, R. D. Dewhurst, H. Braunschweig Transition-metal-like coordination chemistry of dicoordinate borylenes with organic azides Chem. Commun. 2024, 60, 8629-8632. |
| 713 | T. Brückner, D. Duwe, F. Fantuzzi, M. Heß, R. D. Dewhurst, K. Radacki, H. Braunschweig Hydrosilylation of B-B Triple Bonds: Catalyst- and Reductant-Free Construction of B–Si bonds and B2Si Heterocycles Chem. Commun. 2024, 60, 3259-3262. |
| 712 | M. K. Nayak, B. J. Elvers, S. Mehta, I. Krummenacher, A. Mondal, H. Braunschweig, C. Schulzke, P. Ravat, A. Jana Bis-[cyclic(alkyl)(amino)carbene]s-derived diradicals Chem. Commun. 2024, 60, 1739-1742. |
| 711 | D. Duwe, K. Saha, L. Endres, T. Brückner, R. D. Dewhurst, M. Dietz, K. Radacki, F. Fantuzzi, H. Braunschweig Stepwise and selective synthesis of chelating, multimetallic and mixed-metal π-diborene complexes Chem. Commun. 2024, 60, 1120-1123. |
| 710 | M. Passargus, M. Arrowsmith, R. Bertermann, M. Finze, H. Braunschweig A-Frame-Templated High-Coordinate Platinum(IV) cis-Bis(boryl) Complexes Inorg. Chem. 2024, 63, 10657–10670. |
| 709 | C. Czernetzki, M. Arrowsmith, L. Endres, I. Krummenacher, H. Braunschweig Tricoordinate Beryllium Radicals and Their Reactivity Inorg. Chem. 2024, 63, 2670–2678. |
| 708 | C. Czernetzki, M. Arrowsmith, M. Jürgensen, S. Hagspiel, H. Braunschweig Synthesis and structures of molecular beryllium Grignard analogues featuring terminal and bridging pseudohalides Dalton Trans. 2024, 53, 18296-18303. |
| 707 | A. Lamprecht, M. Arrowsmith, M. Dietz, S. Fuchs, A. Rempel, M. Härterich, H. Braunschweig Synthesis, reduction and C‒H activation chemistry of azaborinines with redox-active organoboryl substituents Dalton Trans. 2024, 53, 449-453. |
| 706 | M. Dietz, M. Arrowsmith, H. Braunschweig CAAC-stabilised 9,10-diboraanthracene: an electronically and structurally flexible platform for small-molecule activation and metal complexation Dalton Trans. 2024, 53, 449-453. |
| 705 | F. Lindl, T. Thiess, J. T. Goettel, S. Dotzauer, M. J. Ernst, G. Bélanger-Chabot, H. Braunschweig Borole Ring Expansion Reactions with Boron Azides: A Versatile Pathway to Borylated Azaborinines Eur. J. Inorg. Chem. 2024, 27, e202400498. |
| 704 | J. Cui, Y. He, C. P. Souza, J. Weiser, M. Dietz, I. Krummenacher, R. D. Dewhurst, H. Braunschweig, F. Fantuzzi Single-Electron Oxidation, Chloride Abstraction, and Hydride-Induced Decomposition of a Dichloro-Bis(Germylene) Eur. J. Inorg. Chem. 2024, 27, e202400422. |
For a full list of publications visit our Group homepage www.braunschweiggroup.de.
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