Most Recent Publications

Prof. Holger Braunschweig has published 770 manuscripts since 1990, the majority of which appeared in first ranking journals such as Science, Nature, Nature Chemistry, Nature Communications, Science Advances, JACS, Angewandte Chemie, Chemical Science,...
Most Recent Publications - 2025
| 773 | E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, M. Michel, K. Hammond, H. Braunschweig Structural stability of a bent tetra(amino)tetraborane ring across four charge states Chem 2025, 11, 102338. |
| 772 | E. Beck, D. Bröllos, I. Krummenacher, T. Kupfer, M. Dietz, T. Wellnitz, C. Mihm, H. Braunschweig Boron-chalcogen heterocycles and linear tetraboranes from a cyclic tetra(amino)tetraborane Nat. Commun. 2025,16, Article number: 5304. |
| 771 | M. Buckel, J. Klopf, J. S. Schneider, A. Lik, N. A. Riensch, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten A fully conjugated meso-boron-substituted porphyrinoid combining Lewis acidity with redox-switchable aromaticity Nat. Commun. 2025,16, Article number: 1775. |
| 770 | E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, H. Braunschweig Capturing carbon monoxide – Accessing bis(boryl)ketones through direct B−B bond carbonylation Sci. Adv. 2025,11, eadz3520. |
| 769 | J. Han, H. Xu, A. Sharma, J. Asatryan, F. Rauch, A. Friedrich, J. Krebs, L. Swoboda, J. Schuster, S. Pagidi, N. K. Kalluvettukuzhy, M. Alqurashi, P. Thilagar, N. Schopper, I. Krummenacher, V. Stepanenko, M. Finze, H. Braunschweig, J. Martín, F. Würthner, D. Baran, T. B. Marder Understanding Twisted Triarylboranes from Single Crystals to Heterojunction Blends and Their Applications in Organic Photovoltaics J. Am. Chem. Soc. 2025, 147,28694–28713. |
| 768 | M. Müller, J. Klopf, A. Friedrich, S. Lutz, M. Buckel, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten BNB-Modified Perylene, Terrylene, and Quaterrylene Diimides: Introduction of the π-Accepting and Aggregation-Suppressing Diborinic Imide Group in Rylene Dyes J. Am. Chem. Soc. 2025, 147,28289–28302. |
| 767 | M. Neder, M. Arrowsmith, L. Endres, C. Mihm, S. Nees, R. Bertermann, H. Braunschweig Highly Antiaromatic Naphtho-1,2-Diboretes as Precursors for Tunable, Unsymmetrical 1,4-Diboraanthracenes J. Am. Chem. Soc. 2025, 147,23034–23048. |
| 766 | F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation Angew. Chem. 2025, 137, e202508779; Angew. Chem. Int. Ed. 2025, 64, e202508779. |
| 765 | T. Wellnitz, E. Zander, L. Wüst, J. Boardman, M. Neubauer, S. Nees, H. Braunschweig, C. Hering-Junghans Reactivity of Pnictaalumenes Towards 1,3-Dipole Molecules Angew. Chem. 2025, 137, e202506356; Angew. Chem. Int. Ed. 2025, 64, e202506356. |
| 764 | M. Riethmann, L. Eyßelein, I. Krummenacher, R. Bertermann, H. Braunschweig, M. Gerken, M. Finze, U. Radius A Joyful Journey: Tungsten(VI) and Tungsten(V) Fluorides Meet N-Heterocyclic Carbenes and Cyclic (Alkyl)(Amino)carbenes Angew. Chem. 2025, 137, e202504498; Angew. Chem. Int. Ed. 2025, 64, e202504498. |
| 763 | Y. Konrad, A. Jayaraman, I. Krummenacher, H. Braunschweig Formation and Metallomimetic Reactivity of a Transient Dicoordinate Alkylborylene Angew. Chem. 2025, 137, e202423669; Angew. Chem. Int. Ed. 2025, 64, e202423669. |
| 762 | P. H. R. Oliveira, M. O. Rodrigues, C. D. G. da Silva, J. Bohlen, M. Arrowsmith, A. Jayaraman, L. Lubczyk, F. Fantuzzi, E. N. da Silva Júnior, H. Braunschweig Straightforward Formation of Borirenes from Boroles and Dialkynes Angew. Chem. 2025, 137, e202423391; Angew. Chem. Int. Ed. 2025, 64, e202423391. |
| 761 | M. Michel, S. Kar, L. Endres, R. D. Dewhurst, B. Engels, H. Braunschweig The synthesis of a neutral boryne Nat. Synth. 2025, 4, 869–876. |
| 760 | C. Markl, S. Kar, L. Lubczyk, K. Hammond, R. D. Dewhurst, H. Braunschweig Simple, one-step syntheses of tri- and tetracyclic B,N,S-heterocycles from reactions of a diboracumulene with thiols Chem. Sci. 2025, 16, 18911–18918. |
| 759 | L. Wüst, J. Chorbacher, T. Keim, T. Wellnitz, J. Spieß, N. Wieprecht, M. Michel, H. Helten, H. Braunschweig Tuning the emission properties of luminescent 1,2,3-diazaborinates Chem. Sci. 2025, 16, 15086–15096. |
| 758 | C. Mihm, S. Kar, A. Sachs, D. Duwe, R. D. Dewhurst, H. Braunschweig Synthesis of symmetrical and unsymmetrical cyclic diborenes via NHC-directed C–H borylation Chem. Sci. 2025, 16, 11637-11643. |
| 757 | L. Wüst, L. Scheuring, T. Wellnitz, K. Radacki, H. Braunschweig Alkali metal salts of 1,2,3-benzodiazaborines: platforms for late-stage N-functionalization and metal complexation Chem. Sci. 2025, 16, 9934-9942. |
| 756 | M. Agati, S. Romi, S. Fanetti, K. Radacki, M. Hanfland, H. Braunschweig, T. B. Marder, S. J. Clark, A. Friedrich, R. Bini Insights into topochemical versus stress-induced high-pressure reactivity of azobenzene by single crystal X-ray diffraction Chem. Sci. 2025, 16, 9240-9254. |
| 755 | M. Jürgensen, T. Kunz, M. Arrowsmith, M. Dietz, S. Hagspiel, H. Braunschweig Synthesis and reactivity of a parent phosphathioethynolato-borane and a boraarsaketene Chem. Sci. 2025, 16, 8870-8877. |
| 754 | L. Wüst, J. Chorbacher, T. Wellnitz, S. Nees, H. Helten, H. Braunschweig Synthetic access to organyl-substituted 1,2,3-benzodiazaborines with turn-on fluorescence activity Chem. Sci. 2025, 16, 7284-7293. |
| 753 | M. Michel, L. Endres, F. Fantuzzi, I. Krummenacher, H. Braunschweig Harnessing transient CAAC-stabilized mesitylborylenes for chalcogen activation Chem. Sci. 2025, 16, 5632-5639. |
| 752 | M. S. Luff, T. M. Filipovic, C. S. Corsei, K. Oppel, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig, U. Radius Azolium-2-dithiocarboxylates as redox active ligands in nickel chemistry Chem. Sci. 2025, 16, 5142-5154. |
| 751 | A. V. Hauck, P. Komforth, J. Erlenbusch, J. Stickdorn, K. Radacki, H. Braunschweig, P. Besenius, S. Van Herck, L. Nuhn Aliphatic polycarbonates with acid degradable ketal side groups as multi-pH-responsive immunodrug nanocarriers Biomater. Sci. 2025, 13, 1414-1425. |
| 750 | N. Hensiek, D. Duwe, M. Arrowsmith, M. Michel, H. Braunschweig Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles Chem. Commun. 2025, 61, 14721–14724. |
| 749 | T. Wellnitz, L. Wüst, H. Braunschweig, C. Hering-Junghans A BNAlP-heterocycle Chem. Commun. 2025, 61, 4014–4017. |
| 748 | A. Häfner, L. Endres, M. Arrowsmith, C. Mimh, S. Fuchs, S. Nees, K. Radacki, I. Krummenacher, R. Bertermann, F. Fantuzzi, H. Braunschweig Synthesis and reactivity of a benzo-fused 1,2-diborete biradicaloid Inorg. Chem. Front. 2025, 12, 5493–5505. |
| 747 | M. Passargus, M. Arrowsmith, R. Bertermann, M. Finze, H. Braunschweig Reactivity of a Diplatinum-Templated BNBN Analogue of Butatriene Toward Azides Inorg. Chem. 2025, 64, 21111–21129. |
| 746 | M. Dietz, M. Arrowsmith, A. Jayaraman, A. Lamprecht, H. Braunschweig Reactivity of a Stable and Highly Electron-Rich (η6-Diborabenzene)nickel(0) Synthon Inorg. Chem. 2025, 64, 1788–1797. |
| 745 | K. A. M. Maibom, C. Breitenstein, S. Lorenzen, T. Knuplez, L. N. Schneider, Y. B. J. Bejaoui, J. Gierling, K. Radacki, H. Braunschweig, C. Deutsch, M. Shan, T. Fuchß, M. Schulte, N. V. Ignat’ev, M. Finze N,N-Bis(trifluoromethyl)aminoacetonitrile: A Versatile Building Block for the Introduction of the Bis(trifluoromethyl)amino Group Chem. Eur. J. 2025, 31, e202501550. |
| 744 | J. S. Schneider, V. Zeh, J. Klopf, P. M. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten Poly(Ferrocenylene Iminoborane) and the Merging of 1,1’-Ferrocenylene with p-Phenylene Iminoborane Building Blocks into Alternating Copolymers, Oligomers, and Macrocycles Chem. Eur. J. 2025, 31, e202404533. |
| 743 | Y. Zhang, A. Matler, J. Krebs, I. Krummenacher, Q. Ye, H. Braunschweig, T. B. Marder, L. Ji Emission-Tunable B←N Lewis Pair-Functionalized Naphthalenes: Synthesis, Structures, and Properties Chem. Eur. J. 2025, 31, e202403973. |
| 742 | Y. Konrad, M. Arrowsmith, H. Braunschweig Isolation and Cycloaddition Reactions of a Stable Boraketene ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-l9qnb. |
| 741 | F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-m6825. |
| 740 | S. Dotzauer, S. Kar, T. Swoboda, C. Weidemann, A. Häfner, R. D. Dewhurst, H. Braunschweig Synthesis of base-free boriranes and their conversion to borirenes using strong reductant Dalton Trans. 2025, 54, 3857–3862. |
| 739 | B. Chakraborty, R. R. Hazarika, H. Braunschweig, A. K. Phukan Binding of base-stabilized borylenes with transition metals and formation of metal only Lewis pairs Dalton Trans. 2025, 54, 842-850. |
| 738 | L. Euringer, M. Holzapfel, I. Krummenacher, H. Braunschweig, C. Lambert Switching from Transition-State Theory to Solvent-Controlled Adiabatic Charge-Transfer Regime in Bis-Triarylamine Mixed Valence Radical Cations by Modification of the Bridge Electron Density J. Phys. Chem. B 2025, 129, 4197–4206. |
For a full list of publications visit our Group homepage www.braunschweiggroup.de.
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