Deutsch Intern
Arbeitsgruppe Braunschweig

Most Recent Publications

 

Prof. Holger Braunschweig has published 770 manuscripts since 1990, the majority of which appeared in first ranking journals such as ScienceNatureNature Chemistry, Nature Communications, Science Advances, JACS, Angewandte ChemieChemical Science,...  

 

Most Recent Publications - 2025 

773 E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, M. Michel, K. Hammond, H. Braunschweig
Structural stability of a bent tetra(amino)tetraborane ring across four charge states
Chem 202511, 102338.
 
772 E. Beck, D. Bröllos, I. Krummenacher, T. Kupfer, M. Dietz, T. Wellnitz, C. Mihm, H. Braunschweig
Boron-chalcogen heterocycles and linear tetraboranes from a cyclic tetra(amino)tetraborane
Nat. Commun. 2025,16, Article number: 5304.
 
771 M. Buckel, J. Klopf, J. S. Schneider, A. Lik, N. A. Riensch, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten
A fully conjugated meso-boron-substituted porphyrinoid combining Lewis acidity with redox-switchable aromaticity
Nat. Commun. 2025,16, Article number: 1775.
 
770 E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, H. Braunschweig
Capturing carbon monoxide – Accessing bis(boryl)ketones through direct B−B bond carbonylation
Sci. Adv. 2025,11, eadz3520.
 
769 J. Han, H. Xu, A. Sharma, J. Asatryan, F. Rauch, A. Friedrich, J. Krebs, L. Swoboda, J. Schuster, S. Pagidi, N. K. Kalluvettukuzhy, M. Alqurashi, P. Thilagar, N. Schopper, I. Krummenacher, V. Stepanenko, M. Finze, H. Braunschweig, J. Martín, F. Würthner, D. Baran, T. B. Marder
Understanding Twisted Triarylboranes from Single Crystals to Heterojunction Blends and Their Applications in Organic Photovoltaics
J. Am. Chem. Soc. 2025147,28694–28713.
 
768 M. Müller, J. Klopf, A. Friedrich, S. Lutz, M. Buckel, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten
BNB-Modified Perylene, Terrylene, and Quaterrylene Diimides: Introduction of the π-Accepting and Aggregation-Suppressing Diborinic Imide Group in Rylene Dyes
J. Am. Chem. Soc. 2025147,28289–28302.
 
767 M. Neder, M. Arrowsmith, L. Endres, C. Mihm, S. Nees, R. Bertermann, H. Braunschweig
Highly Antiaromatic Naphtho-1,2-Diboretes as Precursors for Tunable, Unsymmetrical 1,4-Diboraanthracenes
J. Am. Chem. Soc. 2025147,23034–23048.
 
766 F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat
Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation
Angew. Chem. 2025137, e202508779; Angew. Chem. Int. Ed. 202564, e202508779.
 
765 T. Wellnitz, E. Zander, L. Wüst, J. Boardman, M. Neubauer, S. Nees, H. Braunschweig, C. Hering-Junghans
Reactivity of Pnictaalumenes Towards 1,3-Dipole Molecules
Angew. Chem. 2025137, e202506356; Angew. Chem. Int. Ed. 202564, e202506356.
 
764 M. Riethmann, L. Eyßelein, I. Krummenacher, R. Bertermann, H. Braunschweig, M. Gerken, M. Finze, U. Radius
A Joyful Journey: Tungsten(VI) and Tungsten(V) Fluorides Meet N-Heterocyclic Carbenes and Cyclic (Alkyl)(Amino)carbenes
Angew. Chem. 2025137, e202504498; Angew. Chem. Int. Ed. 202564, e202504498.
 
763 Y. Konrad, A. Jayaraman, I. Krummenacher, H. Braunschweig
Formation and Metallomimetic Reactivity of a Transient Dicoordinate Alkylborylene
Angew. Chem. 2025137, e202423669; Angew. Chem. Int. Ed. 202564, e202423669.
 
762 P. H. R. Oliveira, M. O. Rodrigues, C. D. G. da Silva, J. Bohlen, M. Arrowsmith, A. Jayaraman, L. Lubczyk, F. Fantuzzi, E. N. da Silva Júnior, H. Braunschweig
Straightforward Formation of Borirenes from Boroles and Dialkynes
Angew. Chem. 2025137, e202423391; Angew. Chem. Int. Ed. 202564, e202423391.
 
761 M. Michel, S. Kar, L. Endres, R. D. Dewhurst, B. Engels, H. Braunschweig
The synthesis of a neutral boryne
Nat. Synth. 20254, 869–876.
 
760 C. Markl, S. Kar, L. Lubczyk, K. Hammond, R. D. Dewhurst, H. Braunschweig
Simple, one-step syntheses of tri- and tetracyclic B,N,S-heterocycles from reactions of a diboracumulene with thiols
Chem. Sci. 202516, 18911–18918.
 
759 L. Wüst, J. Chorbacher, T. Keim, T. Wellnitz, J. Spieß, N. Wieprecht, M. Michel, H. Helten, H. Braunschweig
Tuning the emission properties of luminescent 1,2,3-diazaborinates
Chem. Sci. 202516, 15086–15096.
 
758 C. Mihm, S. Kar, A. Sachs, D. Duwe, R. D. Dewhurst, H. Braunschweig
Synthesis of symmetrical and unsymmetrical cyclic diborenes via NHC-directed C–H borylation
Chem. Sci. 202516, 11637-11643.
 
757 L. Wüst, L. Scheuring, T. Wellnitz, K. Radacki, H. Braunschweig
Alkali metal salts of 1,2,3-benzodiazaborines: platforms for late-stage N-functionalization and metal complexation
Chem. Sci. 202516, 9934-9942.
 
756 M. Agati, S. Romi, S. Fanetti, K. Radacki, M. Hanfland, H. Braunschweig, T. B. Marder, S. J. Clark, A. Friedrich, R. Bini
Insights into topochemical versus stress-induced high-pressure reactivity of azobenzene by single crystal X-ray diffraction
Chem. Sci. 202516, 9240-9254.
 
755 M. Jürgensen, T. Kunz, M. Arrowsmith, M. Dietz, S. Hagspiel, H. Braunschweig
Synthesis and reactivity of a parent phosphathioethynolato-borane and a boraarsaketene
Chem. Sci. 202516, 8870-8877.
 
754 L. Wüst, J. Chorbacher, T. Wellnitz, S. Nees, H. Helten, H. Braunschweig
Synthetic access to organyl-substituted 1,2,3-benzodiazaborines with turn-on fluorescence activity
Chem. Sci. 202516, 7284-7293.
 
753 M. Michel, L. Endres, F. Fantuzzi, I. Krummenacher, H. Braunschweig
Harnessing transient CAAC-stabilized mesitylborylenes for chalcogen activation
Chem. Sci. 202516, 5632-5639.
 
752 M. S. Luff, T. M. Filipovic, C. S. Corsei, K. Oppel, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig, U. Radius
Azolium-2-dithiocarboxylates as redox active ligands in nickel chemistry
Chem. Sci. 202516, 5142-5154.
 
751 A. V. Hauck, P. Komforth, J. Erlenbusch, J. Stickdorn, K. Radacki, H. Braunschweig, P. Besenius, S. Van Herck, L. Nuhn
Aliphatic polycarbonates with acid degradable ketal side groups as multi-pH-responsive immunodrug nanocarriers
Biomater. Sci. 202513, 1414-1425.
 
750 N. Hensiek, D. Duwe, M. Arrowsmith, M. Michel, H. Braunschweig
Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles
Chem. Commun. 202561, 14721–14724.
 
749 T. Wellnitz, L. Wüst, H. Braunschweig, C. Hering-Junghans
A BNAlP-heterocycle
Chem. Commun. 202561, 4014–4017.
 
748 A. Häfner, L. Endres, M. Arrowsmith, C. Mimh, S. Fuchs, S. Nees, K. Radacki, I. Krummenacher, R. Bertermann, F. Fantuzzi, H. Braunschweig
Synthesis and reactivity of a benzo-fused 1,2-diborete biradicaloid
Inorg. Chem. Front. 202512, 5493–5505.
 
747 M. Passargus, M. Arrowsmith, R. Bertermann, M. Finze, H. Braunschweig
Reactivity of a Diplatinum-Templated BNBN Analogue of Butatriene Toward Azides
Inorg. Chem. 202564, 21111–21129.
 
746 M. Dietz, M. Arrowsmith, A. Jayaraman, A. Lamprecht, H. Braunschweig
Reactivity of a Stable and Highly Electron-Rich (η6-Diborabenzene)nickel(0) Synthon
Inorg. Chem. 202564, 1788–1797.
 
745 K. A. M. Maibom, C. Breitenstein, S. Lorenzen, T. Knuplez, L. N. Schneider, Y. B. J. Bejaoui, J. Gierling, K. Radacki, H. Braunschweig, C. Deutsch, M. Shan, T. Fuchß, M. Schulte, N. V. Ignat’ev, M. Finze
N,N-Bis(trifluoromethyl)aminoacetonitrile: A Versatile Building Block for the Introduction of the Bis(trifluoromethyl)amino Group
Chem. Eur. J. 202531, e202501550.
 
744 J. S. Schneider, V. Zeh, J. Klopf, P. M. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten
Poly(Ferrocenylene Iminoborane) and the Merging of 1,1’-Ferrocenylene with p-Phenylene Iminoborane Building Blocks into Alternating Copolymers, Oligomers, and Macrocycles
Chem. Eur. J. 202531, e202404533.
 
743 Y. Zhang, A. Matler, J. Krebs, I. Krummenacher, Q. Ye, H. Braunschweig, T. B. Marder, L. Ji
Emission-Tunable B←N Lewis Pair-Functionalized Naphthalenes: Synthesis, Structures, and Properties
Chem. Eur. J. 202531, e202403973.
 
742 Y. Konrad, M. Arrowsmith, H. Braunschweig
Isolation and Cycloaddition Reactions of a Stable Boraketene
ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-l9qnb.
 
741 F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat
Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation
ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-m6825.
 
740 S. Dotzauer, S. Kar, T. Swoboda, C. Weidemann, A. Häfner, R. D. Dewhurst, H. Braunschweig
Synthesis of base-free boriranes and their conversion to borirenes using strong reductant
Dalton Trans. 202554, 3857–3862.
 
739 B. Chakraborty, R. R. Hazarika, H. Braunschweig, A. K. Phukan
Binding of base-stabilized borylenes with transition metals and formation of metal only Lewis pairs
Dalton Trans. 202554,  842-850.
 
738 L. Euringer, M. Holzapfel, I. Krummenacher, H. Braunschweig, C. Lambert
Switching from Transition-State Theory to Solvent-Controlled Adiabatic Charge-Transfer Regime in Bis-Triarylamine Mixed Valence Radical Cations by Modification of the Bridge Electron Density
J. Phys. Chem. B 2025129, 4197–4206.
 

 

For a full list of publications visit our Group homepage www.braunschweiggroup.de.