Deutsch Intern
Marder Group


The latest publications



M. Huang, H. Sun, F. Seufert, A. Friedrich, T.B. Marder, and J. Hu, “Photoredox/Cu-Catalyzed Decarboxylative C(sp3)–C(sp3) Coupling to Access C(sp3)-Rich gem-Diborylalkanes,” Angew. Chem. Int. Ed., 62: e202401782 (2024). DOI: 10.1002/anie.202401782. Angew. Chem., 136: e202401782 (2024). DOI: 10.1002/ange.202401782. Read more...


J. Krebs, L. Brändler, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, B.F.E. Curchod, and T.B. Marder, “Synthesis, Photophysical and Electronic Properties of a D-π-A Julolidine-like Pyrenyl-o-Carborane,” Chem. Eur. J., 30: e202401704 (2024). DOI: 10.1002/chem.202401704Read more...


W. Li, R. Ricker, K.L. Chan, P.F. Lau, N.W. Buchbinder, J. Krebs, A. Friedrich, Z. Lin, W.L. Santos, U. Radius, and T.B. Marder, “Phosphine-catalyzed 1,2-cis-diboration of 1,3-butadiynes,” Chem. Eur. J., 30: e202401235 (2024). DOI: 10.1002/chem.202401235. Read more...


R. Okumura, Y. Kusakabe, F. Rauch, L. Lubczyk, K. Suzuki, T.B. Marder, and H. Kaji, "Triarylborane-based thermally activated delayed fluorescence materials with an efficient reverse intersystem crossing," Appl. Phys. Express (APEX), (2024). DOI: 10.35848/1882-0786/ad392a. Selected as a 'Spotlights' articleRead more...


C.B. Kelly, L. Thai-Savard, J. Hu, T.B. Marder, G.A. Molander, and A.B. Charette, “Modern Cyclopropanation via Non-Traditional Building Blocks,” ChemCatChem, e202400110 (2024). DOI: 10.1002/cctc.202400110. Invited Concepts articleRead more...


Y.P. Budiman, M.H. Putra, M.R. Ramadhan, R. Hannifah, C. Luz, I.Z. Ghafara, R. Rustaman, E.E. Ernawati, T. Mayanti, A. Groß, U. Radius, and T.B. Marder, “Pd-Catalyzed Oxidative C–H Arylation of (Poly)fluoroarenes with Aryl Pinacol Boronates and Experimental and Theoretical Studies of its Reaction Mechanism,” Chem. Asian J., e202400094 (2024). DOI: 10.1002/asia.202400094. Read more...


Y.P. Budiman, R.N. Perutz, P.G: Steel, U. Radius, and T.B. Marder, “Applications of Transition Metal-Catalyzed ortho-Fluorine-Directed C-H Functionalization of (Poly)fluoroarenes in Organic Synthesis,” Chem. Rev., 124.8: 4822-4862 (2024). DOI: 10.1021/acs.chemrev.3c00793. Read more...


Í.A.O. Bozzi, L.A. Machado, E.B.T. Diogo, F.G. Delolo, L.O.F. Barros, G.A.P. Graça, M.H. Araujo, F.T. Martins, L.F. Pedrosa, L.C. da Luz, E.S. Moraes, F.S. Rodembusch, J.S.F. Guimarães, A.G. Oliveira, S. Röttger, D.B. Werz, C.P. Souza, F. Fantuzzi, J. Han, T.B. Marder, H. Braunschweig, and E.N. da Silva Júnior “Electrocatalytic Diselenation of BODIPY Fluorophores for Bioimaging Applications and Sensitization of 1O2;” Chem. Eur. J., 30: e202303883 (2024). DOI: 10.1002/chem.202303883. For cover Feature, see: Chem. Eur. J., 30: e202400244 (2024). DOI: 10.1002/chem.202400244. Read more...


D.P. Saftić, R. Ricker, P. Mentzel, J. Krebs, H. Amini, S. Lorenzen, N. Schopper, A. Kenđel, S. Miljanić, J. Morvan, M. Mauduit, Y. Trolez, I. Piantanida, T.B. MarderTetracationic bis-triarylborane tetraynes as dual fluorescence and SERS sensors for DNA, RNA and proteins,” Microchem. J., 196: 109665 (2024). DOI: 10.1016/j.microc.2023.109665. Read more...




Z. Xie and T.B. Marder, “10B-labelled Diboron(4) Reagents: Applications and Relevance to Boron Neutron Capture Therapy,” Chem, 9: 3015-3017 (2023). DOI: 10.1016/j.chempr.2023.09.003. Invited Preview article. Read more...


M. Jurković, M. Ferger, I. Drašković, T.B. Marder, and I. Piantanida, “Triayrlborane-“Click” fluorescent Tag for Orthogonal Amino Acis Labelling, Interactions with DNA, Protein, and Cyclodextrins,” Pharmaceuticals, 16: 1208 (2023). DOI: 10.3390/ph16091208. Part of Special Issue on Fluorescence Approaches in Drug Delivery. Read more...


L. Tendera, L. Kuehn, T.B. Marder, and U. Radius, “On the Reactivity of NHC Nickel Bis-Boryl Complexes: Reductive Elimination and Formation of Mono-Boryl Complexes,” Chem. Eur. J., 28: e202302310 (2023). DOI: 10.1002/chem.202302310. Read more...


J. Hu, M. Tang, J. Wang, Z. Wu, A. Friedrich, and T.B. Marder, “Photocatalyzed Borylcyclopropanation of Alkenes with a (Diborylmethyl)iodide Reagent,” Angew. Chem. Int. Ed., 62: e202305175 (2023); DOI: 10.1002/anie.202305175; Angew. Chem., 135: e202305175 (2023). DOI: 10.1002/ange.202305175. Read more...


H. Xu, J. Han, S. Chen, Y. Liu, L.H. Hernandez, J. Bertrandie, M. Babics, S. Alam, D.R. Villalva, S.H. Kumar Paleti, J. Gorenflot, C. Herok, N. Ramos, J. Troughton, A. Sharma, T.B. Marder, B. Engels, J. Martin, S. De Wolf, F. Laquai, and D. Baran, “Dissecting the Structure-Stability Relationship of Y-Series Electron Acceptors for Real-World Solar Cell Applications,” Joule7.9: 2135-2151 (2023). DOI: 10.1016/j.joule.2023.07.003. Read more...


H.H. Al Mamari, J. Borel, A. Hickey, E. Courtney, J. Merz, X. Zhang, A. Friedrich, T.B. Marder,  and G.P. McGlacken, “Regioselective Iridium-Catalyzed C8-H Borylation of 4-Quinolones via transient O-Borylated Quinolines,” Chem. Eur. J., 29: e202301734 (2023). DOI: 10.1002/chem.202301734. Read more...


L.-M. Tumir, D. S. Pavlović, I. Crnolatac, Ž. Ban, M. Maslać, S. Griesbeck, T.B. Marder, and I. Piantanida, “The nature of the (oligo/hetero)arene linker connecting two triarylborane cations controls fluorimetric and circular dichroism sensing of various ds-DNAs and ds-RNAs,” Molecules, 28: 4348 (2023). DOI: 10.3390/molecules28114348. Invited paper for special issue “New Developments in Boron Chemistry: From Oxidoborates to Hydrido(hetero)borane Derivatives – in Celebration of Professor John D. Kennedy’s 80th Birthday”.  Read more...


A. Barak, N. Dhiman, F. Sturm, F. Rauch, Y.A. Lakshmanna , K.S. Findlay, A. Beeby, T.B. Marder, and S. Umapathy, "Solvent Polarity Governs Ultrafast Structural Dynamics: A Case Study of 4-Dimethylamino-4’-Carbomethoxydiphenylacetylene," J. Phys. Chem. C127: 5855-5865 (2023). DOI: 10.1021/acs.jpcc.2c07691. J. Phys. Chem. virtual special issue “Hiro-o Hamaguchi Festschrift”. Read more...


F. Zhang, F. Rauch, A. Swain, T.B. Marder, and P. Ravat, “Efficient Narrowband Circularly Polarized Light Emitters Based on 1,4-B,N-embedded Rigid Donor–Acceptor Helicenes,” Angew. Chem. Int. Ed., 62: e20221896 (2023); DOI: 10.1002/anie.202218965; Angew. Chem., 135: e20221896 (2023). DOI: 10.1002/ange.202218965. Read more...


Z. Wu, N. Hippchen, J. Hie, L. Ji, A. Friedrich, I. Krummenacher, H. Braunschweig, J. Krebs, M. Moos, P. Biegger, O. Tverskoy, S. Maier, C. Lambert, A. Dreuw, T.B. Marder, J. Freudenberg, and U.H.F. Bunz, “The Radical Anion and Dianion of Benzo[3,4]cyclobuta[1,2-b]phenazine,” J. Org. Chem., 88: 2742-2749 (2023). DOI: 10.1021/acs.joc.2c02279.  Read more...


L. Tendera, F. Fantuzzi, T.B. Marder, and U. Radius, “Nickel boryl complexes and nickel-catalyzed alkyne borylation,” Chem. Sci., 14: 2215-2228 (2023). DOI: 10.1039/D2SC04690C. Read more...


I. Pehar, I. Fabijanić, M. Ferger, T.B. Marder, D. Majhen, and I. Piantanida, “Interactions of variously coated gold and silver nanoparticles with a bis(triarylborane) PDT-dye; their cellular uptake, cytotoxicity and photo-activity,” Periodicum Biologorum, (2023) (accepted Janaury 2023).


S. Toksabay, M. Leisegang, A. Christ, P. Härtl, J. Krebs, T.B. Marder, S. Haldar, S. Heinze, M. Bode, and A. Krueger, “Controlled formation of porous 2D lattices from C3 symmetric Ph6-Me-Tribenzotriquinacene-OAc3,” Chem. Eur. J., 28: e202203187 (2023). Read more...



M. Košćak, I. Pehar, K. Božinović, G.K. Kole, S. Sobočanec, I.I. Podgorski, M. Pinterić, K. Müller-Buschbaum, D. Majhen, I. Piantanida, T.B. Marder, “Para-N-methylpyridinium pyrenes: impact of positive charge on ds-DNA/RNA and protein recognition, photo-induced bioactivity, and intracellular localisation,” Pharmaceutics, 14: 2499 (2022). DOI: 10.3390/pharmaceutics14112499. Read more...


X. Zhang, F. Rauch, J. Niedens, R. da Silva, A. Friedrich, A. Nowak-Króll, S. Garden, and T.B. Marder, “Electrophilic C–H Borylation of Aza[5]helicenes Leading to Bowl-Shaped Quasi-[7]Circulenes with Switchable Dynamics,” J. Am. Chem. Soc., 144: 22316-22324 (2022). DOI: 10.1021/jacs.2c10865. Read more... 
Highlighted in ChemistryViews 
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Highlighted by D. Zhao and X. Bai, Synfacts, 19: 0243 (2023). DOI: 10.1055/s-0042-1753326  Read more... 


J. Krebs, A. Häfner, S. Fuchs, X. Guo, Florian Rauch, A. Eichhorn, I. Krummenacher, A. Friedrich, L. Ji, M. Finze, Z. Lin, H. Braunschweig, and T.B. Marder, “Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives,” Chem. Sci., 13: 14165-14178 (2022). DOI: 10:1039/d2sc06057d. Read more...


Arvind Barak, N. Dhiman, F. Sturm, F. Rauch, Y.A. Lakshmanna, K.S. Findlay, A. Beeby, T.B. Marder, S. Umapathy, “Excited-State Intramolecular Charge-Transfer Dynamics in 4-Dimethylamino-4’-Cyanodiphenylacetylene: An Ultrafast Raman Loss Spectroscopic Perspective,” ChemPhotoChem, 6: e202200146 (2022). DOI: 10.1002/cptc.202200146Read more...


S. Jos, C. Szwetkowski, C. Slebodnick, R. Ricker, K.L. Chan, W.C. Chan, U. Radius, Z. Lin, T.B. Marder, and W.L. Santos, “Transition Metal-Free Regio- and Stereo-Selective trans Hydroboration of 1,3-Diynes: A Phosphine-Catalyzed Access to (E)-1-Boryl-1,3-Enynes,” Chem. Eur. J., 28: e202202349 (2022). DOI: 10.1002/chem.202202349. Read more...


H.O. Omoregie, O.A. Oloba-Whenu, O.J. Olowu, T.M. Fasina, A. Friedrich, M. Haehnel, and T.B. Marder, “Mixed-ligand complexes of copper(II) with thienoyltrifluoroacetonate and nitrogen containing ligands: synthesis, structures, antimicrobial activity, cytotoxicity, Hirshfeld surface analysis and DFT studies,” RSC Adv., 12: 23513-23526 (2022). DOI: 10.1039/d2ra02428d. Read more...


T. Wiesner, Z. Wu, J. Han, L. Ji, A. Friedrich, I. Krummenacher, M. Moos, C. Lambert, H. Braunschweig, B. Rudin, H. Reiss, O. Tverskoy, F. Rominger, A. Dreuw, T.B. Marder, J. Freudenberg, and U.H.F. Bunz, "The Radical Anion, Dianion and Electron Transport Properties of Tetraiodotetraazapentacene," Chem. Eur. J., 28: e202201919 (2022). DOI: 10.1002/chem.202201919. Read more...


A. Hickey, J. Merz, H.H. Al Mamari, A. Friedrich, T.B. Marder, and G.P. McGlacken, “Iridium-Catalyzed Borylation of 6-Fluoroquinolines: Access to 6-Fluoroquinolones,” J. Org. Chem., 87: 9977-9987 (2022) DOI: 10.1021/acs.joc.2c00973. Read more...


K. Božinović, D. Nestić, C. Lambert, E. Michail, D. Majhen, M. Ferger, T.B. Marder, M. Košćak, and I. Piantanida, “Diethynylarene-linked bis(triarylborane)cations as theranostic agents for tumor cell and virus-targeted photodynamic therapy,” J. Photochem. Photobiol. B: Biology, 234: 112523 (2022). DOI: 10.1016/j.jphotobiol.2022.112523. Read more...


L. Kuehn, L. Zapf, Luis Werner, M. Stang, S. Würtemberger-Pietsch, I.Krummenacher, H. Braunschweig, E. Lacôte, T.B. Marder and U. Radius, “NHC induced Radical Formation via Homolytic Cleavage of B–B Bonds and its Role in Organic Reactions,” Chem. Sci. 13: 8321-8333 (2022). DOI: 10.1039/D2SC02096C. Read more...


M. Ferger, C. Roger, E. Köster, F. Rauch, S. Lorenzen, I. Krummenacher, A. Friedrich, M. Košćak, D. Nestić, H. Braunschweig, C. Lambert, I. Piantanida, and T.B. Marder, “Electron-Rich EDOT Linkers in Tetracationic bis-Triarylborane Chromophores: Influence on Water-Stability, Bio-macromolecule Sensing, and Photoinduced Cytotoxicity,” Chem. Eur. J., 28: e202201130. DOI: 10.1002/chem.202201130. Read more...


M.J. Wawi, C. Mahler, N. Inguimbert, T.B. Marder, and A.-C. Ribou, “A new mitochondrial probe combining pyrene and a triphenylphosphonium salt for cellular oxygen and free radical detection via fluorescence lifetime measurements,” Free Radical Research, 56 258-272 (2022). DOI: 10.1080/10715762.2022.2077202. Read more...


X. Zhang, A. Friedrich, and T.B. Marder, "Copper-Catalyzed Borylation of Acyl Chlorides with an Alkoxy Diboron Reagent: A Facile Route to Acylboron Compounds," Chem. Eur. J., 28: e202201329 (2022). DOI: 10.1002/chem.202201329. Read more...


G. Kumar Kole, Marta Košćak, Anissa Amar, Dragomira Majhen, Ksenija Božinović, Zlatko Brkljaca, Matthias Ferger, Evripidis Michail, Sabine Lorenzen, Alexandra Friedrich, Ivo Krummenacher, Michael Moos, Holger Braunschweig, Abdou Boucekkine, Christoph Lambert, Jean-François Halet, Ivo Piantanida, Klaus Müller-Buschbaum, and T.B. Marder, “Methyl Viologens of Bis-(4'-pyridylethynyl)arenes - Structures, Photophysical and Electrochemical Studies, and their Potential Application in Biology,” Chem. Eur. J., 28: e202200753 (2022). DOI: 10.1002/chem.202200753. Read more...


L. Ji, S. Riese, A. Schmiedel, M. Holzapfel, M. Fest, J. Nitsch, B.F.E. Churchod, A. Friedrich, L. Wu, H.A. Al Mamari, S. Hammer, J. Pflaum, M.A. Fox, D.J. Tozer, M. Finze, C. Lambert, and T.B. Marder, “Thermodynamic Equilibrium Between Locally Excited and Charge-Transfer States through Thermally Activated Charge Transfer in 1-(Pyrene-2’-yl)-o-carborane,” Chem. Sci., 13: 5205-5219 (2022). DOI: 10.1039/d1sc06867a. Read more...


Z. Wu, F. Dinkelbach, F. Kerner, A. Friedrich, L. Ji, V. Stepanenko, F. Würthner, Christel M. Marian, and T.B. Marder, “Aggregation-induced Dual Phosphorescence from (o-Bromophenyl)-bis(2,6-dimethylphenyl)borane at Room Temperature,” Chem. Eur. J., 28: e202200525 (2022). DOI: 10.1002/chem.202200525. Highlighted in ChemistryViews  Read more...


M. Huang, J. Hu, S. Shi, A. Friedrich, J. Krebs, S.A. Westcott, U. Radius, and T.B. Marder, “Selective, Transition Metal-free 1,2-Diboration of Alkyl Halides, Tosylates, and Alcohols,” Chem. Eur. J., 28: e202200480 (2022). DOI: 10.1002/chem.202200480. Read more...


Z. Wu, J. C. Roldao, F. Rauch, A. Friedrich, M. Ferger, F. Würthner, J. Gierschner, and T.B. Marder, “Pure Boric Acid Does Not Show Room Temperature Phosphorescence (RTP),” Angew. Chem. Int. Ed., e202200599 (2022). DOI: 10.1002/anie.202200599; Angew. Chem., e202200599 (2022). DOI: 10.1002/ange.202200599. (Designated as a Hot Paper). Highlighted in Nachrichten aus der Chemie, April 2022, vol. 70, p. 55. Read more...


M. Huang, J. Hu, I. Krummenacher, A. Friedrich, H. Braunschweig, S.A. Westcott, U. Radius, and T.B. Marder, “Base-Mediated Radical Borylation of Alkyl Sulfones,” Chem. Eur. J., 28: e202103866 (2022). DOI: 10.1002/chem.202103866. Read more...
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M. Huang, J. Hu, M. Tang, S.A. Westcott, U. Radius, and T.B. Marder, “Cu-mediated vs Cu-free Selective Borylation of Aryl Alkyl Sulfones,” Chem. Commun., 58: 395-398 (2022). DOI: 10.1039/D1CC06144E. Read more...


S.M. Berger and T.B. Marder, “Applications of Triarylborane Materials in Cell Imaging and Sensing of Bio-relevant Molecules such as DNA, RNA, and Proteins,” Invited review for special thematic issue for Seth Marder’s 60th birthday, Mater. Horiz., 9: 112-120 (2022). DOI: 10.1039/D1MH00696G. Read more...




J. Hu, M. Ferger, Z. Shi, and T.B. Marder, “Recent Advances in Asymmetric Borylation by Transition Metal Catalysis,” Chem. Soc. Rev., 50: 13129-13188 (2021). DOI: 10.1039/d0cs00843e.  Read more...


S.K. Bose, L. Mao, L. Kuehn, U. Radius, J. Nekvinda, W. Santos, S.A. Westcott, P.G. Steel, and T.B. Marder, “First-Row d-Block Element-Catalyzed Carbon-Boron Bond Formation and Related Processes,” Chem. Rev., 12113238-13341 (2021). DOI: 10.1021/acs.chemrev.1c00255.  Read more...


W. Ming, H. Soor, X. Liu, A. Trofimova, A. Yudin, and T.B. Marder, “a-Aminoboronates: Recent Advances in their Preparation and Synthetic Applications,” Chem. Soc. Rev., 5012151-12188 (2021). DOI: 10.1039/D1CS00423A. Read more...


X. Jia, J. Nitsch, Z. Wu, A. Friedrich, J. Krebs, I. Krummenacher, F. Fantuzzi, H. Braunschweig, M. Moos, C. Lambert, B. Engels and T.B. Marder, “One- and Two-Electron Reduction of Triarylborane-Based Helical Donor-Acceptor Compounds,” Chem. Sci., 12: 11864-11872 (2021). DOI: 10.1039/d1sc02409d. Read more...


Ž. Ban, Z. Karačić, S. Tomić, H. Amini, T.B. Marder, and I. Piantanida, “Triarylborane dyes as a novel non-covalent and non-inhibitive fluorimetric markers for DPP III enzyme,” Molecules, 26: 4816 (2021) DOI: 10.3390/molecules26164816. Read more...


S.M. Berger, J. Rühe, J. Schwarzmann, A. Phillipps, A.-K. Richard, M. Ferger, I. Krummenacher, L.-M. Tumir, Ž. Ban, I. Crnolatac, D. Majhen, I. Barišić, I. Piantanida, D. Schleier, S. Griesbeck, A. Friedrich, H. Braunschweig, and T.B. Marder, “Bithiophene-Cored, mono-, bis-, and tris-(Trimethylammonium)-Substituted, bis-Triarylborane Chromophores: Effect of the Number and Position of Charges on Cell Imaging and DNA/RNA Sensing,” Chem. Eur. J., 27: 14057-14072 (2021). DOI: 10.1002/chem.202102308. Read more...


X. Shao, J. Wang, T.B. Marder, Z. Xie, J. Liu, and L. Wang, “N—B←N Bridged Bithiophene: A Building Block with Reduced Bandgap to Design n-Type Conjugated Polymers,” Macromolecules, 54: 6718-6725 (2021). DOI: 10.1021/acs.macromol.1c01055. Read more...


Z. Wu, J. Nitsch, and T.B. Marder, “Persistent Room-Temperature Phosphorescence from Purely Organic Molecules and Multi-Component Systems,” Invited review, Adv. Opt. Mater., 9: 2100411 (2021). DOI: 10.1002/adom.202100411. Read more...


F. Lindl, X. Guo, I. Krummenacher, F. Rauch, A. Rempel, V. Paprocki, T. Dellermann, T.E. Stennett, A. Lamprecht, T. Brückner, K. Radacki, G. Bélanger-Chabot, T.B. Marder, Z. Lin, and H. Braunschweig, “Rethinking Borole Cycloaddition Reactivity,” Chem. Eur. J., 27: 11226-11233 (2021). DOI: 10.1002/chem.202101290. Read more...


Z. Liu, G.K. Kole, Y.P. Budiman, Y.-M. Tian, A. Friedrich, X. Luo, S.A. Westcott, U. Radius, and T.B. Marder, “Transition Metal Catalyst-Free, Base-Promoted 1,2-Additions of Polyfluorophenylboronates to Aldehydes and Ketones,” Angew. Chem. Int. Ed., 60: 16529-16538 (2021). DOI: 10.1002/anie.202103686; Angew. Chem., 133: 16665-16674 (2021). DOI: 10.1002/ange.202103686. Read more...


M. Ferger, S. Berger, F. Rauch, S. Schönitz, J. Rühe, J. Krebs, A. Friedrich, and T.B. Marder, "Synthesis of Highly Functionalizable Unsymmetrically- and Symmetrically-Substituted Triarylboranes from Bench-Stable Boron Precursors,” Chem. Eur. J., 27: 9094-9101 (2021). DOI: 10.1002/chem.202100632. Read more...


J. Krebs, M. Haehnel, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, L. Ji, and T.B. Marder, "Synthesis and Structure of an o-Carboranyl-substituted Three-coordinate Borane Radical Anion,” Chem. Eur. J., 27: 8159-8167 (2021). DOI: 10.1002/chem.202100938. Read more...


M. Huang, Z. Wu, J. Krebs, A. Friedrich, X. Luo, S.A. Westcott, U. Radius, and T.B. Marder, "Ni-Catalyzed Borylation of Aryl Sulfoxides,” Chem. Eur. J., 27: 8149-8158 (2021). DOI: 10.1002/chem.202100342. Read more...


V. Merz, J. Merz, M. Kirchner, J. Lenhart, T.B. Marder, and A. Krueger "Pyrene-Based “Turn-Off” Probe with Broad Detection Range for Cu2+, Pb2+ and Hg2+ Ions," Chem. Eur. J., 27: 8118-8126 (2021). DOI: 10.1002/chem.202100594. Read more...


J. Maier and T.B. Marder, "Mechanistic and Kinetic Factors of ortho-Benzyne Formation in Hexadehydro-Diels-Alder (HDDA) Reactions" Chem. Eur. J., 27: 7978-7991 (2021). DOI: 10.1002/chem.202100608. (Mini review)  Read more...

(Selected by the Editorial Office for their Showcase of outstanding Review-type articles)


Y.-M. Tian, X.-N. Guo, H. Braunschweig, U. Radius, and T.B. Marder, “Photoinduced Borylation for the Synthesis of Organoboron Compounds,” Chem. Rev. 121: 3561-3597 (2021). DOI: 10.1021/acs.chemrev.0c01236. Read more...


S.M. Berger, M. Ferger, and T.B. Marder, "Synthetic Approaches to Triarylboranes from 1885 to 2020,” Chem. Eur. J., 27: 7043-7058 (2021). DOI: 10.1002/chem.202005302. Read more...

(Selected by the Editorial Office for their Showcase of outstanding Review-type articles)


X. Chen, G. Meng, G. Liao, F. Rauch, J. He, A. Friedrich, T.B. Marder, N. Wang, P. Chen, S. Wang, and X. Yin, “Highly Emissive 9-Borafluorene Derivatives: Synthesis, Photophysical Properties, and Device Fabrication,” Chem. Eur. J., 27: 6274-6282 (2021). DOI: 10.1002/chem.202005185. Read more...


M.J. Wawi, A. Bijoux, N. Inguimbert, C. Mahler, S. Wagner, T.B. Marder, and A. Ribou, “Peptide Vectors Carry Pyrene to Cell Organelles Allowing Real-time Quantification of Free Radicals in Mitochondria by Time-resolved Fluorescence Microscopy,” ChemBioChem, 22: 1676-1685 (2021). DOI: 10.1002/cbic.202000845. Read more...


Y.P. Budiman, S.A. Westcott, U. Radius, and T.B. Marder, “Fluorinated Aryl Boronates as Building Blocks in Organic Synthesis,” Adv. Synth. Catal., 363: 2224-2255 (2021). DOI: 10.1002/adsc.202001291. Invited review for special thematic issue on Boron in Catalysis and Organic Synthesis (E. Fernandez, Guest Editor). Read more...

(Designated as a Very Important Paper)


Z.-F. Jiao, Y.-M. Tian, X.-N. Guo, U. Radius, H. Braunschweig, T.B. Marder, and X.-Y. Guo, “Visible-Light-Driven Graphene Supported Cu/Pd Alloy Nanoparticles Catalyzed Borylation of Alkyl Bromides and Chlorides in Air,” J. Catal., 395: 258-265 (2021). DOI: 10.1016/j.jcat.2021.01.019. Read more...


M. Ferger, Ž. Ban, I. Krošl, S. Tomić, L. Dietrich, S. Lorenzen, F. Rauch, D, Sieh, A. Friedrich, S. Griesbeck, A. Kenđel, S. Miljanić, I. Piantanida, and T.B. Marder, “Bis(phenylethynyl)arene Linkers in Tetracationic bis-Triarylborane Chromophores Control Fluorimetric and Raman Sensing of Various DNA and RNA,” Chem. Eur. J., 27: 5142-5159 (2021). DOI: 10.1002/chem.202005141. Read more...

(Designated as a Hot Paper


J. He, F. Rauch, I. Krummenacher, H. Braunschweig, M. Finze, and T.B. Marder, “Two Derivatives of Phenylpyridyl-fused Boroles with Contrasting Electronic Properties: Decreasing and Enhancing the Electron Accepting Ability,” Dalton Trans., 50: 355-361 (2021). DOI: 10.1039/D0DT03619F. Read more...


J. He, F. Rauch, A. Friedrich, J. Krebs, I. Krummenacher, R. Bertermann, J. Nitsch, H. Braunschweig, M. Finze, and T.B. Marder, “Phenylpyridyl-fused Boroles: A Unique Coordination Mode and Weak B–N Coordination-Induced Dual Fluorescence,” Angew. Chem. Int. Ed., 60: 4833-4840 (2021). DOI: 10.1002/anie.202013692; Angew. Chem., 133: 4883-4890 (2021). DOI: 10.1002/ange.202013692. Read more...

(Designated as a Hot Paper)


Y.P. Budiman, S. Lorenzen, Z. Liu, U. Radius, and T.B. Marder, “Base-Free Pd-catalyzed C-Cl Borylation of Fluorinated Aryl Chlorides,” Chem. Eur. J., 27: 3869-3874 (2021). DOI: 10.1002/chem.202004648. Read more...


G.K. Kole, J. Merz, A. Amar, B. Fontaine, A. Boucekkine, J. Nitsch, S. Lorenzen, A. Friedrich, I. Krummenacher, M. Košćak, H. Braunschweig, I. Piantanida, J.-F. Halet, K. Müller-Buschbaum, and T.B. Marder, “2- and 2,7-Substituted para-N-Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double Stranded (ds)-DNA,” Chem. Eur. J., 27: 2837-2853 (2021). DOI: 10.1002/chem.202004748. Read more...


J. He, F. Rauch, M. Finze, and T.B. Marder, “(Hetero)Arene-Fused Boroles: A Broad Spectrum of Applications,” Chem. Sci., 12: 128-147 (2021). DOI: 10.1039/d0sc05676f. Read more...



375. A. Friedrich, I.E. Collings, K.F. Dziubek, S. Fanetti, K. Radacki, J. Ruiz-Fuertes, J. Pellicer-Porres, M. Hanfland,                                                 D. Sieh, R. Bini, S.J. Clark, and T.B. Marder, “Pressure-Induced Polymerization of Polycyclic Arene-Perfluoroarene Cocrystals:                    Single Crystal X-ray Diffraction Studies, Reaction Kinetics, and Design of Columnar Hydrofluorocarbons,” J. Am. Chem. Soc., 142:          18907-18923 (2020). DOI: 10.1021/jacs.0c09021. Read more...

         JACS Spotlight: J. Am. Chem. Soc., 142: 18733-18734 (2020). DOI: 10.1021/jacs.0c11191. Read more...

374. M.W. Kuntze-Fechner, H. Verplancke, L. Tendera, M. Diefenbach, I. Krummenacher, H. Braunschweig,                                                               T.B. Marder, M.C. Holthausen, and U. Radius, “Coligand Role in the NHC Nickel catalyzed C–F Bond Activation: Investigations on          the Insertion of bis(NHC) Nickel into the C–F Bond of Hexafluorobenzene,” Chem. Sci., 11: 11009-11023 (2020). DOI:                                10.1039/D0SC04237D. Read more...

373. Y.M. Tian, X.N. Guo, I. Krummenacher, Z. Wu, J. Nitsch, H. Braunschweig, U. Radius, and T.B. Marder,                                                              “Visible-Light-Induced Ni-Catalyzed Radical Borylation of Chloroarenes,”  J. Am. Chem. Soc., 142: 18231–18242 (2020).                             DOI: 10.1021/jacs.0c08834. Read more...

372. X. Ma, J. Maier, M. Wenzel, A. Friedrich, A. Steffen, T.B. Marder, R. Mitrić and T. Brixner, “Direct observation of                                              o-benzyne formation in photochemical hexadehydro-Diels–Alder (hn-HDDA) reactions,” Chem. Sci., 11: 9198-9208 (2020).                       DOI: 10.1039/D0SC03184D. Read more...

371. U. Müller, L. Roos, M. Frank, M. Deutsch, S. Hammer, M. Krumrein, A. Friedrich, T.B. Marder, B. Engels, A. Krueger,                                       and J. Pflaum, “Role of Intermolecular Interactions in the Excited Stare Photophysics of Tetracene and “2,2’-Ditetracene,”                          J. Phys. Chem., Part C, 124: 19435-19446 (2020). DOI: 10.11021/acs.jpc.0c04066.

370. F.-P. Wu, X. Luo, U. Radius, T.B. Marder, and X.-F. Wu, “Copper-Catalyzed Synthesis of Stereodefined Cyclopropyl                                         Bis(Boronates) from Alkenes with CO as the C1 Source,” J. Am. Chem. Soc., 142: 14074-14079 (2020). DOI:                                                 10.1021/jacs.0c06800. Read more...

369. Z. Liu, Y.P. Budiman, Y.-M. Tian, A. Friedrich, M. Huang, S.A. Westcott, U. Radius, and T.B. Marder, “Copper-Catalyzed                                     Oxidative Cross-Coupling of Electron-Deficient Polyfluorophenylboronate Esters with Terminal Alkynes,” Chem. Eur. J.,                               17267-17274 (2020). DOI: 10.1002/chem.202002888. Read more...

368. J. Maier, M. Deutsch,  J. Merz, Q. Ye, O. Diamond, M.T.  Schilling, A. Friedrich, B. Engels, and T.B. Marder, “Highly                                     Conjugated π-Systems Arising from Cannibalistic Hexadehydro-Diels-Alder Couplings: Cleavage of C‒C Single and Triple                           Bonds,” Chem. Eur. J., 26: 15989-16000 (2020). DOI: 10.1002/chem.202002511. Read more...

367. Y.-M. Tian, X.-N. Guo, Zhu Wu, A. Friedrich, S.A. Westcott, H. Braunschweig, U. Radius, and T.B. Marder, “Ni-catalyzed                           traceless, directed C3 selective C-H borylation of indoles,” J. Am. Chem. Soc., 142: 13136-13144 (2020).                                                       DOI: 10.1021/jacs.0c05434. Read more...

366. Z.-F. Jiao, Y.-M. Tian, B. Zhang, C.-H. Hao, Y. Qiao, Y.-X. Wang, Y. Qin, U. Radius, H.Braunschweig, T.B. Marder, X.-N. Guo                               X.-Y. Guo, “High Photocatalytic Activity of a NiO Nanodot-decorated Pd/SiC Catalyst for the Suzuki-Miyaura Cross-coupling of Aryl          Bromides and Chlorides in Air under Visible Light,” J. Catal., 389: 517-524 (2020). DOI: 10.1016/j.jcat.2020.06.025.                                     Read more... 

365. Z. Wu, J. Nitsch, J. Schuster, A. Friedrich, K. Edkins, M. Loebnitz, F. Dinkelbach, V. Stepanenko, F.Würthner, C.M. Marian,                              L. Ji, and T.B. Marder “Persistent room temperature phosphorescence from triarylboranes,” Angew. Chem. Int. Ed.,                                     59: 17137-17144 (2020). DOI: 10.1002/anie.202007610; Angew. Chem., 132: 17285-17292 (2020).
         DOI: 10.1002/ange.202007610 Read more...  

         (Designated as a Very Important Paper).

364. H.-C. Schmitt, I. Fischer, L. Ji, J. Merz, T.B. Marder, J. Hoche, M.I.S. Röhr, and R. Mitric, “Isolated 2-Hydroxypyrene and                             its Dimer: A Frequency- and Time-Resolved Spectroscopic Study,” New J. Chem., 14949-14956 (2020). DOI: 10.1039/d0nj02391d.

363. F. Rauch, J. Krebs, J. Günther, A. Friedrich, M. Hähnel, I. Krummenacher, H. Braunschweig, M. Finze, and T.B. Marder,                                “Electronically-driven Regioselective Iridium-catalyzed C−H Borylation of Donor-π-acceptor Chromophores Containing Triarylboron          Acceptors,” Chem. Eur. J., 26: 10626-10633 (2020). DOI: 10.1002/chem.202002348. Read more...

362. F. Rauch, P. Endres, A. Friedrich, D. Sieh, M. Haehnel, I. Krummenacher, H. Braunschweig, M. Finze, L. Ji, and T.B. Marder,                            “An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers,” Chem. Eur. J., 26: 12951-129633 (2020).                             DOI: 10.1002/chem.202001985.  Read more...

         (Designated as a Hot Paper).

361. J. Merz, L. Dietrich, J. Nitsch, I. Krummenacher, H. Braunschweig, M. Moos, D. Mims, C. Lambert, and T.B. Marder,                                     “Synthesis, Photophysical and Electronic Properties of Mono-, Di-, Tri-Amino-Substituted Ortho-Perylenes, and Comparison to the          Tetra-Substituted Derivative,” Chem. Eur. J., 26: 12050-12059 (2020). DOI: 10.1002/chem.202001475.                                                          Read more...

360. J. Kubicki, M. Lorenc, P. Cochelin, O. Mongin, A. Amar, A. Boucekkine, A. Gaje,  M.G. Humphrey, M. Morshedi, S. Lorenzen,                          F. Rauch, C. Scheufler, T.B. Marder, and F. Paul, “Nitro End-Groups: Remarkable Vibrational Reporters for Charge Transfer in the               Excited States of Oligo(p-Phenyleneethynylene)-Bridged Donor-Acceptor Dyads," J. Phys. Chem. C, 124: 9755−9764 (2020).                      DOI: 10.1021/acs.jpcc.0c01532. Read more...

359. A.K. Narsaria, F. Rauch, J. Krebs, P. Endres, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Finze, J. Nitsch,                                          F.M. Bickelhaupt, and T.B. Marder, “Computationally Guided Molecular Design to Minimize the LE/CT Gap in D-π-A Fluorinated                Triarylboranes for Efficient TADF via D and π-Bridge Tuning,” Adv. Funct. Mater., 30: 2002064 (2020). (15 pages)                                          DOI: 10.1002/adfm.202002064. Read more...             

358. M.J. Krahfuß, J. Nitsch, F.M. Bickelhaupt, T.B. Marder, and Udo Radius, “N-Heterocyclic Silylenes as Ligands in Transition Metal               Carbonyl Chemistry: Nature of their Bonding and Supposed Innocence,” Chem. Eur. J., 26: 11276-11292 (2020).                                          DOI: 10.1002/chem.202001062. Read more...

357. L. Kuehn, A.F. Eichhorn, D. Schmidt, T.B. Marder, and U. Radius, “NHC-stabilized Copper(I) Aryl Complexes and their                                    Transmetalation Reaction with Aryl Halides,” invited paper for F. Ekkehardt Han 60th birthday issue, J. Organomet. Chem., 919:                121249 (2020). DOI: 10.1016/j.jorganchem.2020.121249. Read more...

356. Y.P. Budiman, A. Jayaraman, A. Friedrich, F. Kerner, U. Radius, and T.B. Marder, “Palladium-Catalyzed Homocoupling of Highly                  Fluorinated Arylboronates: Studies of the Influence of Strongly vs. Weakly Coordinating Solvents on the Reductive Elimination                Process,” J. Am. Chem. Soc., 142: 6036-6050 (2020). DOI: 10.1021/jacs.9b11871. Read more...

355. W. Ming, X. Liu, A. Friedrich, J. Krebs, Y.P. Budiman, M. Huang, and T.B. Marder, “Concise synthesis of α-amino cyclic boronates              via multicomponent coupling of salicylaldehydes, amines, and B2(OH)4,” Green Chem. 22: 2184-2190 (2020). DOI:                                       10.1039/D0GC00346H. Read more...

354. X. Liu, W. Ming, X. Luo, A. Friedrich, J. Maier, U. Radius, W.L. Santos, and T.B. Marder, “Regio- and Stereoselective Synthesis of                 1,1-Diborylalkenes via Brønsted Base-Catalyzed Mixed Diboration of Alkynyl Esters and Amides with BpinBdan,” Eur. J. Org.                     Chem. 13: 1941-1946 (2020). DOI: 10.1002/ejoc.202000128. Read more...

353. Q. Lu, G.K. Kole, A. Friedrich, K. Müller-Buschbaum, Z.-Q. Liu, X.-Q. Yu, and T.B. Marder, “Comparison Study of the Site-Effect on                Regioisomeric Pyridyl Pyrene Conjugates: Synthesis, Structures, and Photophysical Properties,” J. Org. Chem., 85: 4256-4266                  (2020). DOI: 10.1021/acs.joc.9bo3421. Read more...

352. H. Amini, Ž. Ban, M. Ferger, S. Lorenzen, F. Rauch, A. Friedrich, I. Crnolatac, A. Kenđel, S. Miljanić, I. Piantanida, and T.B. Marder,                "Tetracationic bis-triarylborane 1,3-butadiyne as a combined fluorimetric and Raman probe for simultaneous and selective                      sensing of various DNA, RNA and proteins,” Chem. Eur. J., 26: 6017 –6028 (2020). DOI: 10.1002/chem.201905328.                                    Read more...

351. F. Rauch, S. Fuchs, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Finze, and T.B. Marder, “Highly stable, readily                    reducible, fluorescent, trifluoromethylated 9-borafluorenes,” Chem. Eur. J., 26: 12794-12808 (2020).                                                                DOI: 10.1002/chem.201905559. Read more...

         (Designated as a Very Important Paper).

350. W. Ming, X. Liu, A. Friedrich, J. Krebs, and T.B. Marder, “The Borono-Strecker Reaction: Synthesis of α-Aminoboronates via a                     Multicomponent Reaction of Carbonyl Compounds, Amines and B2pin2, ” Org. Lett., 22: 365-370 (2020). DOI:                                               10.1021/acs.orglett.9b03773. Illustrated on the cover: Read more...

349. Ž. Ban, S. Griesbeck, S. Tomić, J. Nitsch, T.B. Marder, and I. Piantanida, “A quadrupolar bis-triarylborane chromophore as a                        fluorimetric and  chirooptic probe for simultaneous and selective sensing of DNA, RNA and proteins,” Chem. Eur. J.,                                   26: 2195-2203 (2020). DOI: 10.1002/chem.201903936. Read more...

         (Designated as a Hot Paper).

         Featured in ChemistryViews: Simultaneous and Selective Detection of DNA/RNA and Proteins Read more...

348. H. Belaidi, F. Rauch, Z. Zhang, C. Latouche, A. Boucekkine, T.B. Marder, and J.-F. Halet, “Insights into the Optical Properties of                  Triarylboranes with Strongly Electron-accepting Bis(fluoromesityl)boryl Groups: When Theory Meets Experiment,”                                      ChemPhotoChem 4: 173-180 (2020). DOI: 10.1002/cptc.201900256. Read more...

347. J. Merz, M. Dietz, Y. Vonhausen, F. Wöber, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Moos, M. Holzapfel,                      C. Lambert, and T.B. Marder, “Synthesis, Photophysical and Electronic Properties of New Red to NIR Emitting Donor-Acceptor                 Pyrene Derivatives,” Chem. Eur. J. 26: 438-453 (2020). DOI: 10.1002/chem.201904219. For cover image, see: DOI:                                      10.1002/chem.201905033. (Designated as a Hot Paper). Read more...

346. X. Liu, W. Ming, A. Friedrich, F. Kerner, and T.B. Marder, "Copper-Catalyzed Triboration of Terminal Alkynes Using B2pin2: Efficient              Synthesis of 1,1,2- Triborylalkenes," Angew. Chem. Int. Ed. 59: 304-309 (2020). DOI: 10.1002/anie.201908466; Angew.                               Chem. 132: 311-316 (2020). DOI: 10.1002/ange.201908466. Read more...


345. X. Liu, W. Ming, Y. Zhang, A. Friedrich, and T.B. Marder, "Copper-Catalyzed Triboration: Straightforward, Atom-Economical                         Synthesis of 1,1,1-Triborylalkanes from Terminal Alkynes and HBpin," Angew. Chem. Int. Ed. 58: 18923-18927 (2019). DOI:                       10.1002/anie.201909376; Angew. Chem. 131: 19099-19103 (2019). DOI: 10.1002/ange.201909376. Read more...

344. S. Mueller, J. Lüttig, P. Malý, L. Ji, A. Dreuw, M. Moos, C. Lambert, U. Bunz, T.B. Marder, J. Han, and T. Brixner, “Rapid Multiple-                    quantum Three-dimensional Fluorescence Spectroscopy Disentangles Quantum Pathways,” Nature Comm. 10: 4735 (2019)                   DOI: 10.1038/s41467-019-12602-x. Read more...

343. C. Lenczyk, D.K. Roy, K. Oberdorf, J. Nitsch, R.D. Dewhurst, K. Radacki, J.-F. Halet, T.B. Marder, F.M. Bickelhaupt, and H.                               Braunschweig, “Toward Transition-Metal-Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling,”                  Chem. Eur. J. 25: 16544-16549 (2019). DOI: 10.1002/chem.201904772. Read more...

342. J. He, F. Rauch, A. Friedrich, S. Sieh, T. Ribbeck, I. Krummenachaer, H. Braunschweig, M. Finze, and T.B. Marder, “N-Heterocyclic               Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-p-A                Compounds,” Chem. Eur. J. 25: 13777-13784 (2019). DOI: 10.1002/chem.201903118. Read more...

341. C. Lenczyk, D.K. Roy, J. Nitsch, K. Radacki, F. Rauch, R.D. Dewhurst, F.M. Bickelhaupt, T.B. Marder, and H. Braunschweig, “Steric                Effects Dicate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes,” Chem. Eur. J., 25:                       13566-13571 (2019). DOI: 10.1002/chem.201902890. (Designated as a Hot Paper). Read more...

340. Y.P. Budiman, A. Friedrich, U. Radius, and T.B. Marder, “Copper-Catalysed Suzuki-Miyaura Cross-
         Coupling of Highly Fluorinated Aryl Boronate Esters with Aryl Iodides and Bromides; Fluoroarenearene
         π-Stacking Interactions in the Products,” invited paper for special issue on “New Concepts in
         Homogeneous Catalysis,” ChemCatChem, 11: 5387-5396 (2019). DOI: 10.1002/cctc.201901220.

339. S. Griesbeck, E. Michail, F. Rauch, H. Ogasawara, C. Wang, Y. Sato, R. Edkins, Z. Zhang, M. Taki, C. Lambert, 
         S. Yamaguchi, and T.B. Marder, "The Effect of Branching on One- and Two-Photon Absorption, Cell Viability
         and Localization of Cationic Triarylborane Chromophores with Dipolar vs. Octupolar Charge Distributions
         for Cellular Imaging," Chem. Eur. J., 25: 13164-13175 (2019). DOI: 10.1002/chem.201902461. Read more...

338. T. Sick, J.M. Rotter, S. Reuter, S. Kandambeth, N.N. Bach, M. Döblinger, J. Merz, T. Clark, T.B.
         Marder, T. Bein, and D.D. Medina, “Switching On and Off Interlayer Correlations and Porosity in 2D
         Covalent Organic Frameworks,” J. Am. Chem. Soc.:  12570-12581 (2019). DOI: 10.1021/jacs.9b02800. Read more...

337. N.I. Zahid, L. Ji, M.F. Khyasudeen, A. Friedrich, R. Hashim, T.B. Marder, and O.K. Abou-Zaid,
         “Evidence of Increased Hydrophobicity and Dynamics inside the Tail Region of Glycolipid Self-
         Assemblies Using 2-n-Alkyl-Pyrene Derivatives to Probe Different Locations,” Langmuir:  9584-9592 (2019).
         DOI: 10.1021/acs.langmuir.9b01767.

336. J. Merz, A. Steffen, J. Nitsch, J. Fink, C.B. Schürger, A. Friedrich, I. Krummenacher, H.
         Braunschweig, M. Moos, D. Mims, C. Lambert, and T.B. Marder, “Synthesis, Photophysical and
         Electronic Properties of Tetra- Donor- or Acceptor-Substituted ortho-Perylenes Displaying Four
         Reversible Oxidations or Reductions,” Chem. Sci.:  7516-7534 (2019). DOI: 10.1039/c9sc02420d. Read more...

335. L. Kuehn, M. Stang, S. Würtemberger-Pietsch, A. Friedrich, H. Schneider, U. Radius, and T.B.
        Marder, “FBpin and its Adducts and their Role in Catalytic Borylations,” Faraday Discuss., (2019).
        DOI: 10.1039/C9FD00053D. For the Faraday Discussion on Mechanistic Processes in Organometallic
        Chemistry, York, UK, September 2019.

334. X. Jia, J. Nitsch, L. Ji, Z. Wu, A. Friedrich, F. Kerner, M. Moos, C. Lambert, and T.B. Marder
        “Triarylborane-Based Helical Donor-Acceptor Compounds: Synthesis, Photophysical and Electronic
        Properties,” Chem. Eur. J.:  10845-10857 (2019). DOI: 10.1002/chem.201902258. (Designated as a Hot Paper). Read more...

333. L. Kuehn, D.G. Jammal, K. Lubitz, T.B. Marder, and U. Radius, “Stoichiometric and Catalytic Aryl-Cl
        Activation and Borylation using NHC-stabilized Nickel(0) Complexes,” invited paper for special
        OMCOS 20 issue, Chem. Eur. J.:  9514-9521 (2019). DOI: 10.1002/chem.201900937. (Designated as a Hot
        Paper).

332. L. Kuehn, M. Huang, U. Radius and T.B. Marder, “Copper-Catalysed Borylation of Aryl Chlorides,”
         invited paper for special issue on Organoboron Chemistry, Org. Biomol. Chem. 17: 6601-6606
        (2019). DOI: 10.1039/C9OB01244C. Part of Themed Collections: Catalysis & biocatalysis in
        OBC; Organic and Biomolecular Chemistry HOT article collections; and Trends in
        Organoboron Chemistry
.

331. L. Ji, S. Hahn, P. Biegger, H. Reiss, J. Han, A. Friedrich, I. Krummenacher, H. Braunschweig, M.
        Moos, J. Freudenberg, C. Lambert, A. Dreuw, T.B. Marder, and U.H.F. Bunz, “Mono- and
        Dianion of a Bis(benzobuta)tetraazapentacene Derivative,” Chem. Eur. J.: 9840-9845  (2019). DOI:
        10.1002/chem.201901982. (Designated as a Hot Paper).

330. S. Griesbeck, E. Michail, C. Wang, H. Ogasawara, S. Lorenzen, L. Gerstner, T. Zhang, J. Nitsch, Y.
         Sato, R. Bertermann, M. Taki, C. Lambert, S. Yamaguchi, and T.B. Marder, “Tuning the pi-Bridge of
         Quadrupolar Triarylborane Chromophores for One- and Two-Photon Ecited Fluorescence Imaging of
         Lysosomes in Live Cells,” Chem. Sci. 10: 5405-5422 (2019). DOI: 10.1039/c9sc00793h. Read more...

329. T.E. Stennett, P. Bissinger, S. Griesbeck, S. Ullrich, I. Krummenacher, M. Auth, A. Sperlich, M.
        Stolte, K. Radacki, C.-J. Yao, F. Würthner, A. Steffen, T.B. Marder, and H. Braunschweig, “Near-
        Infrared Quadrupolar Chromophores Combining Three-Coordinate Boron-Based Superdonor and
        Superacceptor Units,” Angew. Chem. Int. Ed. 58: 6449-6454 (2019) DOI: 10.1002/anie.201900889.
        Angew. Chem. 131: 6516-6521 (2019) DOI: 10.1002/ange.201900889.

328. S. Griesbeck, M. Ferger, C. Czernetzki, C. Wang, R. Bertermann, A. Friedrich, M. Haehnel, D. Sieh, M.
        Taki, S. Yamaguchi, and T.B. Marder, “Optimization of Aqueous Stability versus pi-Conjugation in
        Tetracationic Bis(triarylborane) Chromophores: Applications in Live-Cell Imaging,” Chem. Eur. J.
        25: 7679 – 7688 (2019). DOI: 10.1002/chem.201900723. (Designated as a Hot Paper). Read more...

327. D.R. Chisholm, R. Lamb, T. Pallett, V. Affleck, C. Holden, J. Marrison, P. O’Toole, P.D. Ashton, K.
        Newling, A. Steffen, A.K. Nelson, C. Mahler, R. Valentine, T.S. Blacker, A.J. Bain, J. Girkin, T.B.
        Marder, A. Whiting, and C.A. Ambler, “Photoactivated Cell-Killing Involving a Low Molecular
        Weight, Donor-Acceptor Diphenylacetylene,” Chem. Sci. 10: 4673-4683 (2019). DOI:
       10.1039/C9SC00199A.

326. M. Meier, L. Ji, J. Nitsch, I. Krummenacher, A. Deissenberger, D. Auerhammer, M. Schaefer, T.B.  
        Marder, and H. Braunschweig, “Preparation and Characterization of a pi-Conjugated Donor-Acceptor
       System Containing the Strongly Electron-Accepting Tetraphenylborole Unit,” Chem. Eur. J. 25: 4707-
       4712 (2019). DOI: 10.1002/chem.201805454.

325. L. Kuehn, A.F. Eichhorn, T.B. Marder, and U. Radius, “Copper(I) Complexes of N-Alkyl.substituted
       N-Heterocyclic Carbenes,” invited paper for Richard J. Puddephatt 75th birthday issue, J. Organomet.
       Chem. 81: 25-33 (2019). DOI: 10.1016/j.jorganchem.2018.11.032.


324. Y.-M. Tian, X.-N- Guo, M. Kuntze-Fechner, I. Krummenacher, H. Braunschweig, U. Radius, A.
        Steffen, and T.B. Marder, “Selective Photocatalytic C-F Borylation of Polyfluoroarenes by Rh/Ni Dual
        Catalysis Providing Valuable Fluorinated Arylboronate Esters” J. Am. Chem. Soc. 140: 17612-17623
        (2018). DOI: 10.1021/jacs.8b09790.

323. J. Gala de Pablo, D.R. Chisholm, A. Steffen, A.K. Nelson, C. Mahler, T.B. Marder, S.A. Peyman, J.M.
       Girkin, C.A. Ambler, A. Whiting, and S.D. Evans, “Tandem Fluorescence and Raman (fluoRaman)
       Characterisation of a Novel Photosensitzer in Colorectal Cancer Cell Line SW480,” Analyst 143:
       6113-6120 (2018). DOI: 10.1039/c8an01461b.

322. J.H. Muessig, D. Prieschl, A. Dießenberger, R.D. Dewhurst, M. Dietz, J.O.C. Jimenez-Halla, A.
        Trumpp, S.R. Wang, C. Brunecker, A. Haefner, A. Gärtner, T. Thiess, J. Böhnke, K. Radacki, R.
        Bertermann, T.B. Marder, and H. Braunschweig, “Reactivity of Tetrahalo- and Difluorodiboranes(4)
        Towards Lewis Basic Platinum(0): Bis(boryl), Borylborato and Doubly Boryl-bridged Platinum
        Complexes,” J. Am. Chem. Soc. 140: 13056-13063 (2018). DOI: 10.1021/jacs.8b08428. Read more...

321. H. Reiss, L. Ji, J. Han, S. Koser, O. Tverskoy, J. Freudenberg, F, Hinkel, M. Moos, A. Friedrich, I.
         Krummenacher, C. Lambert, H. Braunschweig, A. Dreuw, T.B. Marder, U.H.F. Bunz, “Bromination
         Improves the Electron Mobility of Tetraazapentacene,” Angew. Chem. Int. Ed., 57: 9543-9547 (2018).
         DOI: 10.1002/anie.201805728. Angew. Chem. 130: 9688-9692 (2018). DOI:
         10.1002/ange.201805728.

320. L. Ji, I. Krummenacher, A. Frieddrich, A. Lorbach, M. Haehnel, K. Edkins, H. Braunschweig, and T.
         B. Marder, “Synthesis, Photophysical, and Electrochemical Properties of Pyrenes Substituted with
         Donors or Acceptors at the 4- or 4,9-Positions,” J. Org. Chem. 83: 3599-3606 (2018). DOI:
         10.1021/acs.joc.7b03227.


319. L. Mao, R. Bertermann, S.G. Rachor, K.J. Szabó, and T. B. Marder, “Palladium-Catalyzed Oxidative
       Borylation of Allylic CH Bonds in Alkenes,” Org. Lett. 19:  6590–6593 (2017).
       DOI: 10./acs.orglett.7b03296.

318. L. Mao, R. Bertermann, K. Emmert, K.J. Szabó, and T. B. Marder, “Synthesis of Vinyl, Allyl-, and 2-Boryl
       Allyl-Boronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols,” Org. Lett. 19:
        6586–6589 (2017). DOI: 10./acs.orglett.7b03294.

317. L. Ji, A. Friedrich, I. Krummenacher, A. Eichhorn, H. Braunschweig, M. Moos, S. Hahn, F. Geyer, O.
       Tverskoy, J. Han, C. Lambert, A. Dreuw, T.B. Marder, and U.H.F. Bunz, “Preparation, Properties and
       Structures of the Radical Anions, and Dianions of Azapentacenes,” J. Am. Chem. Soc. 139: 15968-15976
      (2017). DOI: 10.1021/jacs.7b09460.

316. A.F. Eichhorn, L. Kuehn, T.B. Marder, and U. Radius, “Facile Insertion of a Cyclic(amino) Carbene into the
       B-B Bond of Diboron(4) Reagents,” Chem. Commun. 53: 11694-11696 (2017).
       DOI: 10.1039/c7cc06302d.

315. Z. Wang, Y. Zhou, T.B. Marder, and Z. Lin, “DFT Studies on Reactions of Boroles with Carbon Monoxide,”
       Org. Biomol. Chem. 15: 7019-7027 (2017). DOI: 10.1039/C7OB01475A.

314. X. Song, Z. Zhang, S. Zhang, J. Wei, K. Ye, Y. Liu, T.B. Marder, and Y. Wang, “Geometric Shape
       Regulation and Non-covalent Synthesis of One-Dimensional Organic Luminescent Nano/Micro-Materials,” J.
Chem. Lett. 8: 3711-3717 (2017). DOI: 10.1021/acs.jpclett.7b01643.

313. J. Merz, J. Fink, A. Friedrich, I. Krummenacher, H.H. Al Mamari, S. Lorenzen, M. Hähnel, A. Eichhorn, M.
       Moos, M. Holzapfel, H. Braunschweig, C. Lambert, A. Steffen, L. Ji, and T.B. Marder, “Pyrene MO Shuffle –
       Controlling Excited State and Redox Properties by Changing the Nature of the Frontier Orbitals,” Chem.
       Eur. J.
23: 13164-13180 (2017). DOI: 10.1002/chem.201702594.

312. Z. Wang, Y. Zhou, W.H. Lam, R.D. Dewhurst, H. Braunschweig, T.B. Marder, and Z. Lin,  “DFT Studies of
       Dimerization Reactions of Boroles,” Chem. Eur. J. 23: 11587-11597 (2017).
       DOI: 10.1002/chem.201701737.

311. A.F. Eichhorn, S. Fuchs, M. Flock, T.B. Marder, and U. Radius, “Reversible Oxidative Addition at Carbon,”
       Angew. Chem. Int. Ed., 56: 10209-10213 (2017) . DOI: 10.1002/anie.201701679. Angew. Chem.,  129:
      10343-10347 (2017). DOI: 10.1002/ange.201701679.

310. O. Diamond and T.B. Marder, “Methodology and Applications of the Hexahydro-Diels-Alder (HDDA)
        Reaction,” Invited Review for special issue on “Novel p-Electron Molecular Scaffolds,” Org. Chem.
, 4, 891-910 (2017). DOI: 10.1039/C7QO00071E.

309. M. Eck, S. Würtemberger-Pietsch, A. Eichhorn, J.H.J. Berthel, R. Bertermann, U. Paul, H. Schneider,
       A. Friedrich, C. Kleeberg, U. Radius, and T.B. Marder, “B–B Bond Activation and NHC Ring-expansion
       Reactions of Diboron(4) Compounds, and Accurate Molecular Structures of B2(NMe2)4, B2eg2, B2neop2
       and B2pin2,” Dalton Trans., 46: 3661-3680 (2017).
       DOI: 10.1039/C7DT00334J.

308. C. Sieck, D. Sieh, M. Sapotta, M. Haehnel, K. Edkins, A. Lorbach, A. Steffen, and T.B. Marder,
        “Convenient Synthetic Access to Fluorescent Rhodacyclopentadienesvia Ligand Exchange Reactions,”
        Invited paper for John Gladysz 65th birthday issue, J. Organomet. Chem., 847: 184-192 (2017).
        DOI: 10.1016/j.jorganchem.2017.02.028.

307. L. Mao, K. Szabó, and T.B. Marder, “Synthesis of Benzyl-, Allyl-, and Allenyl-boronates via
       Copper-catalyzed Borylation of Alcohols,” Org. Lett., 19: 1204-1207 (2017).
       DOI: 10.1021/acs.orglett.7b00256.

306.  M. Lübtow, I. Helmers, V. Stepanenko, R. Q. Albuquerque, T.B. Marder, and G. Fernandez,
        “Self-Assembly of 9,10-Bis(phenylethynyl)anthracene (BPEA) Derivatives: Influence of p-p and
        Hyrdogen Bonding Interactions on Aggregate Morphology and Self-Assembly Mechanism,”
        Chem. Eur. J., 23: 6198-6205 (2017). DOI: 10.1002/chem.201605989.

305. F.K. Scharnagl, S.K. Bose, and T.B. Marder, “Acylboranes: Synthetic Strategies and Applications,”
       Invited Review, Org. Biomol. Chem., 15: 1738-1752 (2017). DOI: 10.1039/C6OB02425D.

304. L. Ji, S. Griesbeck, and T.B. Marder, “Recent Developments in and Perspectives on
       Three-CoordinateBoron Materials: A Bright Future,” Invited Review, Chem. Sci., 8: 846-863 (2017).
       DOI: 10.1039/C6SC04245G.

303. S.K. Bose, S. Brand, H.O. Omoregie, M. Haehnel, J. Maier, G. Bringmann, and T.B. Marder,
       “Highly Efficient Synthesis of Alkylboronate Esters via Cu(II)-Catalyzed Borylation of Unactivated
        Alkyl Bromides and Chlorides in Air,” ACS Catal., 6: 8332-8335 (2016). DOI: 10.1021/acscatal.6b02918.

302. S. Griesbeck, Z. Zhang, M. Gutmann, T. Lühmann, R.M. Edkins, G. Clermont, A.N.
        Lazar, M. Haehnel, K. Edkins, A. Eichhorn, M. Blanchard-Desce, L. Meinel, and
        T.B. Marder, "Water-Soluble Triarylborane Chromophores for One- and Two-
        Photon Excited Fluorescence Imaging of Mitochondria in Cells," Chem. Eur. J.,
        22: 14701-14706 (2016). DOI: 10.1002/chem.201602639.

301. S. Würtemberger-Pietsch, H. Schneider, T.B. Marder, and U. Radius, "Adduct
        Formation, B-H Activation and Ring Expansion at Room Temperature from
        Reactions of HBcat with NHCs," Chem. Eur. J., 22: 13032-13036 (2016).
        DOI: 10.1002/chem.201603328.

300. L. Ji, M. Haehnel, I. Krummenacher, P. Biegger, F.L. Geyer, O. Tverskoy, M.
        Schaffroth, J. Han, A. Dreuw, T.B. Marder, and U.H.F. Bunz, "The Radical Anion
        and Dianion of Tetraazapentacene," Angew. Chem. Int. Ed., 55: 10498-10501
        (2016). DOI: 10.1002/anie.201603177. Angew. Chem., 128: 10654-10657 (2016).
        DOI: 10.1002/ange.201603177.

299. E.C. Neeve, S.J. Geier, I.A.I. Mkhalid, S.A. Westcott, and T.B. Marder, "Diboron(4)
        Compounds: From Structural Curiosity to Synthetic Workhorse," Chem. Rev., 116:
        9091-9161 (2016). DOI: 10.1021/acs.chemrev.6b00193.

298. Z. Zhang, Z. Wang, M. Haehnel, A. Eichhorn, R.M. Edkins, A. Steffen, A.
        Krueger, Y. Lin, and T.B. Marder, "Synthesis and Fluxional Behavior of Novel
        Chloroborole Dimers," Chem. Commun., 52: 9707-9710 (2016).
        DOI: 10.1039/C6CC04831E.

297. J. Zhou, J.H.J. Berthel, M.W. Kuntze-Fechner, A. Friedrich, T.B. Marder, and U.
        Radius, "NHC Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions of
        Arylboronate Esters with Perfluorobenzenes," J. Org. Chem., 80: 5789-5794
        (2016). DOI: 10.1021/acs.joc.6b01041.

296. C. Sieck, M.G. Tay, M.-H. Thibault, R.M. Edkins, K. Costuas, J.-F. Halet, A.S.
        Batsanov, M. Haehnel, K. Edkins, A. Lorbach, A. Steffen, and T.B. Marder, "Reductive
        Coupling of Diynes at Rhodium Gives Fluorescent Rhodacyclopentadienes or
        Phosphorescent Rhodium 2,2'-Biphenyl Complexes," Chem. Eur. J., 22: 10523-10532
        (2016). DOI: 10.1002/chem.201601912.

295. U.S.D. Paul, C. Sieck, M. Haehnel, K. Hammond, T.B. Marder, and U. Radius,
        "Useful for Comparison: Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and
        Nickel and their Steric and Electronic Parameters," Chem. Eur. J., 22: 11005-11014
        (2016). DOI: 10.1002/chem.201601406.

294. J. Zhou, M.W. Kuntze-Fechner, R. Bertermann, U.S.D. Paul, J.H.J. Berthel,
        A. Friedrich, Z. Du, T.B. Marder, and U. Radius, "Preparing (Multi)Fluoroarenes
        as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes
        via C-F Bond Activation," J. Am. Chem. Soc., 138: 5250-5253 (2016).
        DOI: 10.1021/jacs.6b02337.

293. A.S. Batsanov, J.A. Cabeza, M.G. Crestani, M.R. Fructos, P. García-Álvarez,
        M. Gille, Z. Lin, and T.B. Marder, "Fully Borylated Methane and Ethane by
        Ruthenium Mediated Cleavage and Coupling of CO," Angew. Chem. Int. Ed.
        55: 4707-4710 (2016). DOI: 10.1002/anie.201601121. Angew. Chem. 128:
        4785-4788 (2016). DOI: 10.1002/ange.201601121.

292. S. Würtemberger-Pietsch, U. Radius, and T.B. Marder, "25 years of
        N-Heterocyclic Carbenes: Activation of Both Main-Group Element-Element
        Bonds and NHCs Themselves," Invited Dalton Perspective, Dalton Trans. 45:
        5880-5895 (2016). DOI: 10.1039/C5DT04106F.




291. D. Chaiyaveij, A.S. Batsanov, M.S. Fox, T.B. Marder, and A. Whiting, "An
        Experimental and Computational Approach to Understanding the Reactions of Acyl
        Nitroso Compounds in [4+2] Cycloadditions," J. Org. Chem., 80: 9518-9534 (2015).
        DOI: 10.1021/acs.joc.5b01470. Lesen Sie mehr...

290. S.K. Bose and T.B. Marder, "Metal-fee Catalytic Borylation of Carbon-Hydrogen 
        Bonds - A Leap Forward in C-H Functionalization," invited Perspective, Science,
        349: 473-474 (2015). DOI: 10.1126/science.aac9244. Lesen Sie mehr...

289. Z. Zhang, R.M. Edkins, M. Haehnel, M. Wehner, A. Eichhorn, L. Mailänder, M. Meier,
        J. Brand, F. Brede, K. Müller-Buschbaum, H. Braunschweig, and T.B. Marder,
        "Taming the Beast: Fluoromesityl Groups Induce a Dramatic Stability Enhancement 
        in Boroles," Chem. Sci., 6: 5922-5927 (2015). DOI: 10.1039/C5SC02205C.
        Lesen Sie mehr...

288. S.K. Bose, A. Deißenberger, A. Eichhorn, P.G. Steel, Z. Lin, and T.B. Marder, "Zinc-
        Catalyzed Dual C-X and C-H Borylation of Aryl Halides," Angew. Chem. Int. Ed., 54:
        11843-11847 (2015). DOI: 10.1002/anie.201505603. Angew. Chem. 127: 12009-
        12014 (2015). DOI: 10.1002/ange.201505603. Lesen Sie mehr...

287. N. Arnold, H. Braunschweig, P.B. Brenner, M. Ali Celik, R.D. Dewhurst, M. Haehnel,
        T. Kramer, I. Krummenacher, and T.B. Marder, "Correlations and Contrasts in Homo-
        Heteroleptic Cyclic (Alkyl)(amino)carbene (CAAC)-Containing Pt0 Complexes," Chem.
        Eur. J., 21: 12357-12362 (2015). DOI: 10.1002/chem.201502048.
        Lesen Sie mehr...

286. L. Ji, R.M. Edkins, A. Lorbach, I. Krummenacher, C. Brückner, A. Eichhorn, H.
        Braunschweig, B. Engels, P.J. Low, and T.B. Marder, "Electron Delocalization in
        Reduced Forms of 2-(BMes2)pyrene and 2,7-Bis(BMes2)pyrene," J. Am. Chem. Soc.,
        137: 6750-6753 (2015). DOI: 10.1021/jacs.5b03805. Lesen Sie mehr...

285. L. Ji, A. Lorbach, R.M. Edkins, and T.B. Marder, "Synthesis and Photophysics of a
        2,7-Disubstituted Donor-Acceptor Pyrene Derivative: An Example of the Application
        of Sequential Ir-Catalyzed C-H Borylation and Substitution Chemistry," J. Org. Chem.,
        80: 5658-5665 (2015. DOI: 10.1021/acs.joc.5b00618. Lesen Sie mehr...

284. S.A. Sadler, A. C. Hones, B. Roberts, D. Blakemore, T.B. Marder, and P.G. Steel,
        "Multidirectional Synthesis of Substituted Indazoles via Iridium-Catalyzed C-H
        Borylation," J. Org. Chem., 80: 5308-5314 (2015). DOI: 10.1021/acs.joc.5b00452.
        Lesen Sie mehr...

283. S. Pietsch, U. Paul, I.A. Cade, M.J. Ingleson, U. Radius, and T.B. Marder, "Room
        Temperature Ring Expansion of N-Heterocyclic Carbenes and B-B Bond Cleavage of
        Diboron(4) Compounds," Chem. Eur. J., 21: 9018-9021 (2015).
        DOI: 10.1002/chem.201501498. Lesen Sie mehr...

282. R.D. Dewhurst, E.C. Neeve, H. Braunschweig, and T.B. Marder, "sp²-sp³ Diboranes:
        Astounding Structural Variability and Mild Sources of Nucleophilic Boron for Organic
        Synthesis," Chem. Commun., 51: 9594-9607 (2015). (Featured Article).
        DOI: 10.1039/c5cc02316e. Lesen Sie mehr...

281. M.S. Cheung, F.K. Sheong, T.B. Marder, and Z. Lin, "Computational Insight into
        Nickel-Catalyzed Carbon-Carbon versus Carbon-Boron Coupling Reactions of
        Primary, Secondary and Tertiary Alkyl Bromides," Chem. Eur. J., 21: 7480-7488
        (2015). DOI: 10.1002/chem.201500110. (Designated as a Hot Paper).
        Lesen Sie mehr...

280. S. Pietsch, E.C. Neeve, D.C. Apperley, R. Bertermann, F. Mo, Di Qiu, M.S. Cheung, L.
        Dang, J. Wang, U. Radius, Z. Lin, C. Kleeberg, and T.B. Marder, "Synthesis, Structure
        and Reactivity of Anionic sp2-sp3 Diboron Compounds: Readily Accessible Boryl
        Nucleophiles," Chem. Eur. J., : 7082-7098 (2015). DOI: 10.1002/chem.201500235.
        (Designated as a Hot Paper). Lesen Sie mehr...

279. L. Ji, K. Fucke, S.K. Bose, and T.B. Marder, “Iridium-Catalyzed Borylation of Pyrene:
        Irreversibility and the Influence of Ligand on Selectivity,” J. Org. Chem., 80: 661-665
        (2015). Lesen Sie mehr...

278. Z. Zhang, R.M. Edkins, J. Nitsch, K. Fucke, A. Eichhorn, A. Steffen, Y. Wang, and
        T.B. Marder, “D-π-A Triarylboron Compounds with Tunable Push-Pull Character
        Achieved by Modification of Both the Donor and Acceptor Moieties,” Chem. Eur. J., 
        21: 177-190 (2015). DOI: 10.1002/chem.201405621. (Designated as a VIP – 
        Very Important Paper). Lesen Sie mehr...

277. Z. Zhang, R.M. Edkins, J. Nitsch, K. Fucke, A. Steffen, L.E. Longobardi,
        D.W. Stephan, C. Lambert and T.B. Marder, “ Optical and Electronic Properties
        of Air-stable Organoboron Compounds with Strongly Electron-accepting
        Bis(fluoromesityl)boryl Groups,” Chem. Sci., 6: 308-321 (2015).
        DOI: 10.1039/c4sc02410a  Lesen Sie mehr... 

276. Z.-Q. Zhang, C.-T. Yang, L.-J. Liang B. Xao, X. Lu, J.-H. Liu, Y.-Y. Sun, T.B. Marder,
        and Y. Fu, “Copper-Catalyzed/Promoted Cross-coupling of gem-Diborylalkanes
        with Nonactivated Primary Alkyl Halides: An Alternative Route to Alkylboronic
        Esters", Org. Lett., 16: 6342-6345 (2014). DOI: 10.1021/ol503111h.
       Lesen Sie mehr...

275. S.A. Sadler, H. Tajuddin, I.A.I. Mkhalid, A.S. Batsanov, D. Albesa-Jove,
        M.S. Cheung, A.C. Maxwell, L. Shukla, B. Roberts, D.C. Blakemore, Z. Lin,
        T.B. Marder, and P.G. Steel, “Iridium-Catalyzed C-H Borylation of Pyridines,”
        Org. Biomol. Chem., 12: 7318-7327 (2014). DOI: 10.1039/C4OB01565G
        Lesen Sie mehr...

274. S.K. Bose and T.B. Marder, “Efficient Synthesis of Aryl Boronates via Zinc-
        Catalyzed Cross-Coupling of Alkoxy Diboron Reagents with Aryl Halides at
        Room Temperature,” Org. Lett., 16: 4562-4565 (2014). DOI: 10.1021/ol502120q
        Lesen Sie mehr...

273. L. Ji, R.M. Edkins, L.J. Sewell, A. Beeby, A.S. Batsanov, K. Fucke, M. Drafz,
        J.A.K. Howard O. Moutounet, F. Ibersiene, A. Boucekkine, E. Furet, Z. Liu,
        J.-F. Halet, C. Katan, and T.B.Marder, “Experimental and Theoretical Studies
        of Quadrupolar Oligothiophene-cored Chromophores Containing Dimesitylboryl
        Moieties as π-Accepting End-groups: Syntheses,Structures, Fluorescence,
        One- and Two-photon Absorption,” Chem. Eur. J., 20: 13618 13635 (2014).
        DOI: 10.1002/chem.201402273. Lesen Sie mehr...

272. A. Steffen, K. Costuas, A. Boucekkine, M.-H. Thibault, A. Beeby, A.S. Batsanov,
        A. Charaf Eddin, D. Jacquemin, J.-F. Halet, and T.B. Marder, "Fluorescence in
        Rhoda- and Iridacyclopentadienes Neglecting the Spin-Orbit Coupling of the
        Heavy Atom: The Ligand Dominates" Inorg. Chem., 53: 7055-7069 (2014).
        DOI: 10.1021/ic501115k  Lesen Sie mehr...

271. X. Yin, J. Chen, R.A. Lalancette, T.B. Marder, and F. Jäkle, “Highly Electron-
        Deficient, Air Stable Conjugated Thienylboranes,” Angew. Chem. Int.
        Ed., 53: 9761-9765 (2014). DOI: 10.1002/anie.201403700.
        Lesen Sie mehr...

270. R. Dewhurst and T.B. Marder, “Cascades of Catalytic Selectivity,”
        invited News and Views paper,  Nature Chemistry, 6: 279-280 (2014).
        Lesen Sie mehr...

269. A. Steffen, R.M. Ward, M.G. Tay, R.M. Edkins, F. Seeler, M. van Leeuwen,
        L.-O. Pålsson, A. Beeby, A.S. Batsanov, J.A.K. Howard, and T.B. Marder,
        “Regiospecfic formation and Unusual Optical Properties of 2,5-Bis(arylethynyl
        rhodacyclopentadienes: A New Class of Luminescent Organometallics,”
        Chem. Eur. J., 20: 3652-3666 (2014). DOI:10.1002/chem.201304068. 
        Lesen Sie mehr...

268. R.E. Lopez-Real, J.J.R. Budge, T.B. Marder, A. Whiting, P.N. Hunt, and 
        S.A. Przyborski, “Application of Synthetic Photostable Retinoids Induces 
        Novel Limb and Facial Phenotypes During Chick Embryogenesis In Vivo,” 
        J. Anat., 224: 392-411 (2014). DOI: 10.1111/joa.12147. Lesen Sie mehr... 
        Corrigendum: J. Anat., 224: 529 (2014).  DOI: 10.1111/joa.12161. 

267. S. Konishi, S. Kawamorita, T. Iwai, P.G. Steel, T.B. Marder, and M. Sawamura, 
        “Site-Selective C-H Borylation of Quinolines at the C8 Position Catalyzed by a Silica
        Supported Phosphane-Iridium System,” Chem. Asian J., 9: 434-438 (2014). 
        DOI: 10.1002/asia.201301423 Lesen Sie mehr...

266. S.K. Bose, K. Fucke, L. Liu, P.G. Steel, and T.B. Marder, “Zinc-Catalyzed Borylation
        of Primary, Secondary and Tertiary Alkyl Halides with Alkoxy Diboron Reagents 
        at Room Temperature,” Angew. Chem. Int. Ed., 53: 1799-1803 (2014). 
        DOI: 10.1002/anie.201308855 (Designated as a Hot Paper).
        Lesen Sie mehr...

265. J.A. Foster, R.M. Edkins, G.J. Cameron, N. Coglin, K. Fucke, S. Ridgeway, 
        A.G. Crawford, T.B. Marder, A. Beeby, S.L. Cobb, and J.W. Steed, 
       “Blending Gellators to Tune Gel Structure and Probe Anion-Induced Disassembly,” 
        Chem. Eur. J., 20: 279-291 (2014). DOI: 10.1002/chem.201303153
        Lesen Sie mehr...




264. P.R. Matthes, J. Nitsch, A. Kuzmanoski, C. Feldmann, A. Steffen, T.B. Marder, 
        and K. Müller-Buschbaum, “ The Series of Rare Earth Complexes 
        [Ln2Cl6(m-4,4’-bipy)(py)6], Ln=Y, Pr, Nd, Sm-Yb: A Molecular Model System for
        Luminescence Properties in MOFs Based on LnCl3 and 4,4’-Bipyridine,”
        Chem. Eur. J., 19: 17369-17378 (2013). DOI: 10.1002/chem.201302504
        Lesen Sie mehr...

263. G. Clemens, K.R. Flower, P. Gardener, A.P. Henderson, J.P. Knowles, T.B. Marder, 
        A. Whiting, and S.A. Przyborski, "Design and Biological Evaluation of Synthetic
        Retinoids: Probing Length vs. Stability vs. Activity," Mol. BioSyst., 9: 3124-3134
        (2013). DOI: 10.1039/c3mb70273a
        Lesen Sie mehr...

262. H. Braunschweig, F. Guethlein, L. Mailänder, and T.B. Marder, "Synhesis of
        Catechol-, Pinacol-, and Neopentaneglyclborane via Heterogeeous Catalytic B-B
        Bond Hydrogenolysis of Diboranes(4)," Chem. Eur. J., early view (2013).
        DOI: 10.1002/chem.201302677
        Lesen Sie mehr...

261. R.M. Edkins, K. Fucke, M.J.G. Peach, A.G. Crawford, T.B. Marder, and A. Beeby,
        "Syntheses, Structures and Comparison of the Photophysical Properties of
        Cyclometalated Iridium Complexes Containing the Isomeric 1- and 2-(2'-pyridyl)
        Pyrene Ligands," Inorg. Chem. 52: 9842-9860 (2013). DOI: 10.102/ic400819f
        Lesen Sie mehr...

260. G.L. Zhou, D.M. Tams, T.B. Marder, R. Valentine, A. Whiting, and S. Przyborski,
        "Synthesis and Applications of 2,4-Sisubstituted Thiazole Derivatives as Small 
        Molecule Modulators of Cellular Development," Org. Biomol. Chem., 11:
        2323-2334 (2013). DOI: 10.1039/C3OB00005B (Designated as a Hot Article).
        Lesen Sie mehr...       

259. M.-H. Thibault, M.G. Tay, A.S. Batsanov, J.A.K. Howard, and T.B. Marder,
        “Oxidative Addition of (Bromoethynyl)benzen to
        k²-Acetylacetonatobis(trimethylphosphine)rhodium(I),” invited paper for
        ICOMC/F.G.A. Stone Special Issue, J. Organomet. Chem. 730: 104-107 (2013).
        DOI: 10.1016/j.jorganchem.2012.11.19.
        Lesen Sie mehr...

258. H. Tajuddin, P. Harrisson, B. Bitterlich, J.C. Collings, N. Sim, A.S. batsanov,
        M.S. Cheung, S. Kawamorita,A.C. Maxwell, L. Shukla, J. Morris, Z. Lin, T.B. Marder,
        and P.G. Steel, “Iridium-Catalyzed C-H Borylation of Quinolines and Substituted
        Benzenes: Insights Into Steric and Electronic Effects on Selectivity,”
        Chem. Sci., 3: 3505-3515 (2012). DOI: 10.1039/c2sc20776a.
        Lesen Sie mehr...

257. A.S. Batsanov, J.A.K. Howard, N. Wu, Z. Yang, and T.B. Marder, “An Irreversible
        Phase Transition in 1-n-butylindeno[2,1,c]pyran-3,9-dione,” Acta Crystallogr.,
        C68: o413-o416 (2102). DOI: 10.1107/S010827011203805X.
        Lesen Sie mehr...

256. N. Wu, A. Messinis, A.S. Batsanov, Z. Yang, A. Whiting, and T.B. Marder,
        “Palladium(II)-Catalysed Tandem Cyclisation of Electron-Deficient Aromatic Enynes,”
        Chem. Commun., 48: 9986-9988 (2012). DOI: 10.1039/C2CC35114E.
        Lesen Sie mehr...

255. Z. Liu, Y. Wang, Y. Chen, J. Liu, Q. Fang, C. Kleeberg, and T.B. Marder, “Ir-Catalyzed
        Direct Borylation at the 4-Position of Pyrene,” J. Org. Chem., 77: 7124-7128 (2012).
        Lesen Sie mehr...

254.  A.S. Batsanov, J.A.K. Howard, D. Albesa-Jové, J.C. Collings, Z. Liu, I.A.I. Mkhalid,
        M.-H. Thibault and T.B. Marder, “Structural Versatility of Pyrene-2-(4,4,5,5
        tetramethyl-[1,3,2]dioxaborolane) and Pyrene 2,7-bis(4,4,5,5
        tetramethyl-[1,3,2]dioxaborolane)” Cryst. Growth Des., 12: 2794-2802.
        DOI: 10.1021/cg201554t.
        Lesen Sie mehr...

253.  B. Liu, M. Gao, L. Dang, H. Zhao, T. B. Marder, and Z. Lin, “DFT Studies on the
        Mechanisms of the Platinum-Catalyzed Diboration of Acyclic alpha,beta-Unsaturated
        Carbonyl Compounds,” Organometallics, 31: 3410-3425, (2012).
        Lesen Sie mehr...

252.  A.G. Crawford, Z. Liu, I.A.I. Mkhalid, M.-H. Thibault, N. Schwarz, G. Alcaraz,
        A. Steffen, J.C. Collings, A.S. Batsanov, J.A.K. Howard, and T.B. Marder, “Synthesis
        of 2- and 2,7-Functionalized Pyrene Derivatives: An Application of Selective
        C–H Borylation,” Chem. Eur. J., 18: 5022-5035 (2012).
        Lesen Sie mehr...

251.  L. Weber, D. Eickhoff, T.B. Marder, M.A. Fox, P.J. Low, A.D. Dwyer, D.J. Tozer,
        S. Schwedler, A. Brockhinke, H.G. Stammler, and B. Neumann, “Experimental and
        Theoretical Studies on Organic D-Pi-A Systems Containing 3-Coordinate Boron
        Moieties as Both Pi-Donor and Pi-Acceptor,” Chem. Eur. J., 18: 1369-1382 (2012).
        DOI: 10.1002/chem.201102059.
        Lesen Sie mehr...

250.  C. Kleeberg, A.G. Crawford, A.S. Batsanov, P. Hodgkinson, D.C. Apperley,
        M.S. Cheung, Z.Y. Lin and T.B. Marder, “Spectroscopic and Structural
        Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State,”
        J. Org. Chem., 77: 785-789 (2012). DOI: 10.1021/jo202127
        Lesen Sie mehr...

249.  C.-T. Yang, Z.-Q. Zhang, H. Tajuddin, C.-C. Wu, J. Liang, J.-H. Liu, Y.F.,
        M. Czyzewska, P.G. Steel, T.B. Marder, and L. Liu, “Alkylboronic Esters from
        Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and
        Pseudo-Halides,” Angew. Chem. Int. Ed., 51: 528-532 (2012).
        DOI: 10.1002/anie.201106299.
        Lesen Sie mehr...
248.  J. Zheng, S. Lin, B.-W. Jiang, T.B. Marder, and Z. Yang, “The Role of the Magnetic
        Nanoparticles (MNP) as Reducing Agent in an MNP-Supported Pd-Catalyst for the
        Reductive Homocoupling of Aryl Halides,” special issue for T.-H. Chan,
        Can. J. Chem., 90: 138-144 (2012). DOI: 10.1002/chin.201225085.
        Lesen Sie mehr...

247.  C. Kleeberg, M.S. Cheung, Z. Lin, and T.B. Marder, “A Copper Mediated Reduction of
        CO2 with pinB–SiMe2Ph via CO2 Insertion into a Copper-Silicon Bond,”
        J. Am. Chem. Soc.,133: 19060-19063 (2011).
       Lesen Sie mehr...
246.  A.G. Crawford, A.D. Dwyer, Z. Liu, A. Steffen, A. Beeby, L.-O. Pålsson, D.J. Tozer,
        and T.B. Marder, “Experimental and Theoretical Studies of the Photophysical
        Properties of 2- and 2,7-Functionalized Pyrene Derivatives,” J. Am. Chem. Soc.,
        133:13349-13362 (2011).
         Lesen Sie mehr...
245.  J.B. Bauer, W.P. Lippert, S. Dörrich, D. Tebbe C. Burschka, V.B. Christie,
        B.A. Murray, T.B. Marder, S.A. Przyborski, and R Tacke, “Novel Silicon-Containing
        Analogues of the Retinoid Agonist Bexarotene: Syntheses and Biological Effects
        on Human Pluripotent Stem Cells,” Chem. Med. Chem., 6: 1509-1517 (2011).
        Lesen Sie mehr...

244.  D. Chaiyaveij, L. Cleary, A.S. Batsanov, T.B. Marder, K.J. Shea, and A. Whiting,
        “Copper(II)-Oxazoline Catalyzed Room Temperature Aerobic Oxidation of
        Hydroxamic Acids and Hydrazides to Acyl-Nitroso and Azo Intermediates,
        and their Diels­–Alder Trapping,” Org. Lett., 13: 3442-3445 (2011).
        Lesen Sie mehr...

243.  M.S Cheung, T.B. Marder, and Z. Lin, “Mechanisms of Reactions of Lithium Boryl
        with Organohalides,” Organometallics, 30: 3018-3028 (2011).
        Lesen Sie mehr...
242.  M. Gao, S.B. Thorpe, C. Kleeberg, C. Slebodnick, T.B. Marder, and W. Santos,
        “Structure and Reactivity of a Preactivated sp2-sp3 Diboron Reagent: Catalytic
        Regioselective Boration of a,b-Unsaturated Conjugated Compounds,”
        J. Org. Chem., 76: 3997-4007 (2011).
        Lesen Sie mehr...
241.  H. Tajuddin, L. Shukla, A.C. Maxwell, T.B. Marder, and P.G. Steel, “A “One-Pot”
        Tandem C-H Borylation/1,4-Conjugate Addition/Reduction Sequence,”
        Org. Lett., 12: 5700-5703 (2010).
        Lesen Sie mehr...
240.  J.L. Palma, E. Atas, L. Hardison, T.B. Marder, J.C. Collings, A. Beeby, J.S. Melinger,
        J.L. Krause, V.D. Kleiman, and A.E. Roitberg, “Electronic Spectra of the Nanostar
        Dendrimer: Theory and Experiment,” J. Phys. Chem. C, 114: 20702-20712 (2010).
        Lesen Sie mehr...

239.  V.B. Christie, D.J. Maltman, A. Whiting, T.B. Marder, and S.A. Przyborski,
        “Retinoid Supplementation Leads to Increased Neuronal Maturity During
        Differentiation of a Commercial Human Neural Progenitor Cell Line,”
        J. Neurosci. Methods, 193: 239-245 (2010).
       Lesen Sie mehr...

238.  Y.-X. Gao, L. Chang, H. Shi, B. Liang, K. Wongkhan, D. Chaiyaveij, A.S. Batsanov,
        T.B. Marder, C.-C. Li, Z. Yang and Y. Huang, “A Thiourea-oxazoline Library with
        Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed
        Enantioselective Bis(methoxycarbonylation) of Terminal Olefins,” Adv. Synth. Catal.,
        352: 1955-1966 (2010).
        Lesen Sie mehr...

 237.  A. Steffen, R.M. Ward, W.D. Jones, and T.B. Marder, “Dibenzometall-
         acyclopentadienes, Boroles and Selected Transition Metal and Main Group
         Heterocyclopentadienes: Synthesis, Catalytic and Optical Properties,”
         Coord. Chem. Rev., 254: 1950-1976 (2010).
         Lesen Sie mehr...

236.  T.E. Hurst, T.K. Macklin, M. Becker, E. Hartmann, W. Kügel, J.-C. Parisienne-
        La Salle, A.S. Batsanov, T.B. Marder, and V. Snieckus, “Iridium-Catalyzed C-H
        Activation versus Directed ortho Metalation (DoM): Complementary Borylation
        of Aromatics and Heteroaromatics,” Chem. Eur. J., 16: 8155-8161 (2010).
        Lesen Sie mehr...

235.  K.C. Lam, T.B. Marder, and Z. Lin, “Mechanism of the Palladium-Catalyzed Borylation
        of Aryl Halides with Pinacolborane,” Organometallics, 29: 1849-1857 (2010).
        Lesen Sie mehr...

234.  L. Dang, Z. Lin, and T.B. Marder, “DFT Studies on the Carboxylation of Arylboronate
        Esters with CO2 Catalyzed by Copper(I) Complexes,” Organometallics, 29: 917-92
        Lesen Sie mehr...

233.  A. Steffen, M.G. Tay, A.S. Batsanov, J.A.K. Howard, A. Beeby, K.Q. Vuong,
        X.-Z. Sun, M.W. George, and T.B. Marder, “2,5-Bis(p-Arylethynyl)-
        Rhodacyclopentadienes Show Intense Fluorescence: Denying the Presence
        of a Heavy Atom,” Angew. Chem. Int. Ed., 49: 2349-2353 (2010).
       Lesen Sie mehr...

232.  Q. Li, K. Wongkhan, X. Luo, A.S. Batsanov, J.A.K. Howard, Y. Lan, Y. Wu, A. Lei,
        and T.B. Marder, “A Novel Self-Promoted Morita-Baylis-Hillman-Like Dimerisation,”
        invited paper, Chinese Science Bull., 55: 2794-2798 (2010).
        Lesen Sie mehr...

231.  I.A.I. Mkhalid, J.H. Barnard, T.B. Marder, J.M. Murphy, and J.F. Hartwig,
        “C-H Activation for the Construction of C-B Bonds,” invited review, Chem. Rev.,
        110: 890-931 (2010).
         Lesen Sie mehr...

230.  H.M. Colquhoun, Z. Zhu, D.J. Williams, M.G.B. Drew, C.J. Cardin, Y. Gan,
        A.G. Crawford, and T.B. Marder, “Induced-fit Binding of p-Electron Donor
        Substrates to Macrocyclic Aromatic Ether-imide-sulfones: A Versatile Approach to
        Molecular Assembly,” Chem. Eur. J., 16: 907-918 (2010).
        Lesen Sie mehr...



     Archive 2009-2008    

     Archive 2007-2006     

     Archive 2005-2004

     Archive 2003-2000

     Archive 1999-1995

     Archive 1994-1990

     Archive 1989-1985

     Archive 1984-1980

Books, Papers, Reports

Book Chapters

1.         T.B. Marder, “Diborane(4) Compounds,” in Science of Synthesis, Houben-Weyl Methods of Molecular Transformations, Volume 6 - Boron Compounds, D. Kaufmann and D.S. Matteson, eds., Chapter 6.1.3, pp. 117-137, Georg Thieme Verlag, Stuttgart, 2004.


Book Reviews

2.         Descriptive Inorganic Chemistry, 2nd Edition, by G. Rayner-Canham, W.H. Freeman, 1999.
In Educ. Chem. 37: 139 (2000).

 1.        Mechanisms of Inorganic and Organometallic Reactions, Vol. 6, M.V. Twigg, ed., Plenum Press, 1989.
In American Scientist 79: 471-472 (1991).


Other Invited Papers

 1.        T.B. Marder, "Molecular Materials for Nonlinear Optics," Canadian Chemical News, 44: No. 10 (Nov./Dec.), 22-23 (1992).


Other Papers and Reports

 1.        A. Beeby, K.S. Findlay, P.J. Low, T.B. Marder, S.R. Rutter, P. Matousek, A.W. Parker, and M. Towrie, “Studies of the S1 State in a Prototypical Molecular Wire Using Picosecond Time-resolved Spectroscopies,” Central Laser Facility, CCLRC, Rutherford Appleton Laboratory, Annual Report, 2002-2003, 119-121.


Books Edited

2.         T.B. Marder and Z. Lin (Eds.), “Contemporary Metal Boron Chemistry I: Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides,” Structure and Bonding, Volume 130, Springer, Heidelberg, May 2008 (218 pages).

 1.         M.G. Davidson, A.K. Hughes, T.B. Marder, and K. Wade (Eds.), "Contemporary Boron Chemistry," Spec. Publ. No. 253, The Royal Society of Chemistry, Cambridge, 2000.


Journal Issues Edited

3.         T.B. Marder, P.W.Dyer, I.J.S. Fairlamb, S. Gibson, P. Scott, “Dalton Discussion 12: Catalytic C-H and C-X Bond Activation (DD12),” Dalton Trans., 39: 10335-10337 (2010), editorial introduction to Dalton Transactions themed issue 43, pages 10321-10540.

2.         T.B. Marder (Guest Editor), Dalton Transactions, 2008: “Collection of articles dedicated to Professor Ken Wade, F.R.S. in celebration of his seventy-fifth birthday.”

1.          T.B. Marder, Editorial for special issue of Journal of Organometallic Chemistry: “Frontiers in Boron Chemistry, Dedicated to Professor M. Frederick Hawthorne in Celebration of his 75th Birthday,” J. Organometal. Chem., 680: 1-2 (2003).


Patent Applications

Patents: 7 applications submitted, 1 granted thus far, 6 pending

1. Stefan Przyborski, Andrew Whiting, Todd Marder, “Retinoid compounds and their use”,
    CA2662218 A1, PCT/GB2007/003237, Mar. 6, 2008, Pending

2. Todd Marder , Stefan Przyborski, Andrew Whiting, “Retinoid compounds and their use”,
    WO2008025965 A3, PCT/GB2007/003237, Oct. 2, 2008, Pending

3. Todd Marder , Stefan Przyborski, Andrew Whiting, “Retinoid compounds and their use”,
    EP2054504 A2, May 6, 2009, Pending

4. Stefan Przyborski, Andrew Whiting, Todd Marder, “Retinoid compounds and their use”,
    EP2130908 A3, Jan. 6, 2010, Pending

5. Stefan Przyborski, Andrew Whiting, Todd Marder, “Retinoid compounds and their use”,
    US20100093088 A1, PCT/GB2007/003237, Apr. 15, 2010, Pending

6. Todd Marder , Stefan Przyborski, Andrew Whiting, “Retinoid compounds and their use”,
     WO2012076842 A1, PCT/GB2007/003237, Jun. 14, 2012, Pending

7. Stefan Przyborski, Andrew Whiting, Todd Marder, “Synthetic retinoids for control of cell
    differentiation”, US8293803 B2, PCT/GB2007/003237, Oct. 23, 2012, Issued

8. Andrew Whiting, Todd Marder, “Fluorescent synthetic retinoids,” CA2962150A1, EP3204357A2,
    WO2016055800A2, WO2016055800A3, US20170217893 A1, PCT/GB2015/052956, Oct 9, 2015,

    CN107250112 (A), publication date: 2017-10-13;
    AU2015329798 (A1), 2017-05-11;
    CA2962150 (A1), 2016-04-14;
    JP2017537140 (A), 2017-12-14;
    EP3204357 (A2), 2017-08-16;
    US2017217893 (A1), 2017-08-03;
    WO2016055800 (A2), 2016-04-14.