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Arbeitsgruppe Prof. Dr. Maik Finze

Lehrstuhlinhaber - Prof. Dr. Maik Finze

Prof. Dr. Maik Finze

Lehrstuhlinhaber
Institut für Anorganische Chemie, Lehrstuhl III
Am Hubland
97074 Würzburg
Gebäude: Hubland Süd, Geb. C2
Raum: 02.024
Telefon: +49 931 31-85857
Prof. Dr. Maik Finze

Akademische Laufbahn

seit 10.2019 Dekan der Fakultät für Chemie und Pharmazie
seit 2016 Co-Direktor des Instituts für nachhaltige Chemie & Katalyse mit Bor (ICB)
seit 06.2016 Professor für Anorganische Chemie (W3) an der Julius-Maximilians-Universität Würzburg
Lehrstuhl für Anorganische Chemie III
10.2015 - 09.2019 Prodekan der Fakultät für Chemie und Pharmazie
2015 Ruf auf eine Professur für Anorganische Chemie (W3) an die Universität Hamburg (abgelehnt)
05.2010 - 05.2016 Universitätsprofessor (W2) für Anorganische Chemie an der Julius-Maximilians-Universität Würzburg
2011 Ruf auf eine Professur für Anorganische Chemie (W2) an die Universität Würzburg (angenommen)
2011 Ruf auf eine Professur für Anorganische Chemie (W2) an die Universität Wuppertal (abgelehnt)
12.2010 - 04.2011 Privatdozent/Akademischer Oberrat auf Zeit, Heinrich-Heine-Universität Düsseldorf
12.2004 - 11.2010 Wissenschaftlicher Assistent (C1), Heinrich-Heine-Universität Düsseldorf
02.2004 - 11.2004 Wissenschaftlicher Mitarbeiter, Bergische-Universität Wuppertal
01.2002 - 01.2004 Wissenschaftlicher Mitarbeiter, Universität Duisburg-Essen
   

Studium

 

12.2004 - 04.2010

Habilitation in Anorganischer Chemie an der Heinrich-Heine-Universität Düsseldorf
Thema: "Salze neuer funktionalisierter Carba-closo-dodecaboratanionen - Synthesen und Eigenschaften"

10.2004 - 11.2004

Postdoc im Arbeitskreis von Professor Helge Willner (Universität Wuppertal)

02.2002 - 09.2004

Promotion im Arbeitskreis von Professor Helge Willner (Universitäten Duisburg, Wuppertal und Hannover)
Thema: "Die Chemie des Carbonyltris(trifluormethyl)borans"

07.2001 - 01.2002     

Diplomarbeit im Arbeitskreis von Professor Helge Willner (Universität Duisburg)
Thema: "Stabilisierung elektrophiler Kationen mit den neuen schwach koordinierenden Borat-Anionen [B(CF3)4]- und [B(CN)4]-"

1995 - 2002 

Chemiestudium an der Universität Hannover
1999 - 2000 Auslandsaufenthalt im Arbeitskreis von Professor Robert M. Waymouth (Stanford University)
Thema "Novel 1,2-bridged Bisindenyl Zirconium Complexes"
   
   
   

 

 
   
   
   
   
 

 

  • Polyfluorierte Borcluster

  • Regioselektive Funktionalisierung von Borclustern

  • Münzmetallcluster mit Ethinylliganden

  • Komplexe mit Carboranylliganden

  • Einfache Boratanionen

  • Ionische Flüssigkeiten

Publikationen

  Gesamte Publikationsliste des AK Finze siehe   "Alle Publikationen ab 2002"
  ­
_ Florian Rauch, Sonja Fuchs, Alexandra Friedrich, Daniel Sieh, Ivo Krummenacher, Holger Braunschweig, Maik Finze, and Todd B. Marder
Highly stable, readily reducible, fluorescent, trifluoromethylated 9-borafluorenes
Chem. Eur. J. 2020, accepted.
 
_ Zhenguo Huang, Suning Wang, Rian D. Dewhurst, Nikolai V. Ignat’ev, Maik Finze, Holger Braunschweig
Boron: Its role in energy related research and applications
Angew. Chem. Int. Ed.  2020, in press.
 
_ Michael Hailmann, Krzysztof Radacki, and Maik Finze
Silver(I) Clusters Stabilized by the Carba‐closo‐dodeca¬boranyl¬ethynyl Ligand with O‐Donor Coligands and Template Ions
Z. Anorg. Allg. Chem. 2020646, 1–8.
 
_ Anna E. Thomas, Steven D. Chambreau, Neil D. Redeker, Alan A. Esparza, Evgeny Shafirovich, Tatjana Ribbeck, Jan A. P. Sprenger, Maik Finze, Ghanshyam L. Vaghjiani
Thermal Decomposition and Hypergolic Reaction of a
Dicyanoborohydride Ionic Liquid
J. Phys. Chem. A  2020, 124(5), 864874.
 
_ Ilka Simon, Julius Hornung, Juri Barthel, Jörg Thomas, Maik Finze, Roland A. Fischer and Christoph Janiak
Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids

Beilstein J. Nanotechnol. 2019, 10, 1754–1767.
 
_ Tatjana Ribbeck, Christoph Kerpen, Christian Schmidle, Fabian Keppner, Jan A. P. Sprenger, Merle Arrowsmith, Holger Braunschweig, Nikolai V. Ignat’ev, Maik Finze
Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties

Inorg. Chem.  2019, 58(24), 1668916702.
 
_ Jiang He, Florian Rauch, Alexandra Friedrich, Daniel Sieh, Tatjana Ribbeck, Ivo Krummenacher, Holger Braunschweig, Maik Finze, and Todd B. Marder
N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–p–A Compounds

Chem. Eur. J. 2019, 25, 13777–13784.

_ Nikolai V. Ignat'ev and Maik Finze
Cyaonoborates

Eur. J. Inorg. Chem. 2019, 35393560
Cover Profile
- Front Cover -
 
_

M. Hailmann, A. Himmelspach, F. Keppner, Philipp T. Hennig, R. Bertermann, M. Finze, B. Hupp, and A. Steffen
Carba-closo-dodecaboranylethynyl ligands facilitating luminescent reversed charge-transfer excited states in gold/silver complexes

Chem. Commun. 2019, 55(63), 9351–9354.

_ P. T. Hennig, J. A. P. Sprenger, L. N. Schneider, N. V. Ignat'ev and M. Finze
The pentafluoroethylhydridoborate anion: From shock sensitive salts to stable room temperature ionic liquids    
Chem. Commun. 2019, 55, 6110–6113.
 
_ Ru-Jin Li, Muxin Han, Jacopo Tessarolo, Julian J. Holstein, Jens Lübben, Birger Dittrich, Christian Volkmann, Maik Finze, Carsten Jenne, and Guido H. Clever
Successive Photoswitching and Derivatization Effects in Photochromic Dithienylethene-Based Coordination Cages

ChemPhotoChem  2019, 378383.
 
_ Lisa A. Bischoff, Michael Drisch, Christoph Kerpen, Philipp T. Hennig, Johannes Landmann, Jan A. P. Sprenger, Rüdiger Bertermann,  Matthias Grüne,  Qinqin Yuan, Jonas Warneke, Xuebin Wang,  Nikolai Ignat'ev, and Maik Finze
Cyanohydridoborate Anions: Synthesis, Salts, and Low-viscosity Ionic Liquids

Chem. Eur. J.  2019, 25, 3560–3574.

_ Tatjana Ribbeck, Christoph Kerpen, Dominic Löw, Alexander E. Sedykha, Klaus Müller-Buschbaum, Nikolai V. Ignat’ev, Maik Finze
Lanthanide trifluoromethyltricyanoborates: Synthesis, crystal structures and thermal properties

J. Fluor. Chem2019, 219, 70–78.    
 
_ Michael Lucas, Stephen J. Brotton, Jan A. P. Sprenger, Maik Finze, Shiv K. Sharma, and Ralf I. Kaiser
Oxidation of a Levitated 1‑Butyl-3-methylimidazolium Dicyanoborate Droplet by Nitrogen Dioxide
J. Phys. Chem. A   2019, 123, 780–795.
 
_ Jonas Warneke, Markus Rohdenburg, Judy K. Y. Liu, Erynn Johnson, Xin Ma, Rashmi Kumar, Pei Su, Edoardo Aprà, Xue-Bin Wang, Carsten Jenne, Maik Finze, Hilkka I. Kenttämaa, Julia Laskin
Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions
Int. J. Mass Spectr.  2019, 436, 71–78.
 
_ Jonas Warneke, Szymon Z. Konieczka, Gao-Lei Hou, Edoardo Aprà, Christoph Kerpen, Fabian Keppner, Thomas C. Schäfer, Michael Deckert, Zheng Yang, Eric J. Bylaska, Grant E. Johnson, Julia Laskin, Sotiris S. Xantheas, Xue-Bin Wang and Maik Finze
Properties of perhalogenated {closo-B10} and {closo-B11} multiply charged anions and a critical comparison with {closo-B12} in the gas and the condensed phase

Phys. Chem. Chem. Phys2019, 21, 5903–5915.

 

28.   M. Drisch, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verbindungen mit ein-, bis- und mehrfach geladenen schwach koordinierenden Anionen
DE102016010488A1, 01.03.18 (30.08.2016)
27.   J. A. P. Sprenger, P. T. Hennig, L. N. Schneider, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylhydrido- und Fluoralkylcyanohydridoborate
DE102016009846A1, 22.02.2018 (16.08.2016)
26.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Monofluorotricyanoboratanionen
DE102015016401A1, 22.06.2017 (18.12.2015)
25.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Perfluoralkyltricyanoboratanionen oder Tetracyanoboratanionen
DE102015016400A1, 22.06.2017 (18.12.2015)
24.   L. A. Bischoff, J. A. P. Sprenger, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Kaliummonofluorotricyanoborat
DE102016001344A1, 16.03.2017 (08.02.2016)
23.   J. A. P. Sprenger, M. Finze, J. Landmann, A. Lennert, U. Schmid-Großmann, J. Eichhorn
Merck Patent GmbH, 64293 Darmstadt (Germany)
Polymere enthaltend polymerisierte ionische Flüssigkeiten und deren Anwendung in Membranen
DE102015006493A1, 24.11.2016 (22.05.2015)
22.  

J. Landmann, F. Keppner, J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Verbindungen mit Tricyanoborat-Dianionen
DE20141018103 20141209, 09.06.2016 (09.12.2014)

21.  

M. Drisch, L. A. Bischoff, L. Herkert, J. A. P. Sprenger, M. Finze, N. Ignatyev, R. Van Hal
Merck patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions
WO2016074760A1, 19.05.2016 (19.10.2015)

20.  

J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing perfluoralkylfluoroborate salts
WO2016074756A1, 19.05.2016 (15.10.2015)

19.  

J. A. P. Sprenger, L. A. Bischoff, M. Drisch, L. Herkert, M. Finze, H. Willner, E. Bernhardt, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing compounds with monofluorotricyanoborate anions
WO2016058665A1, 21.04.2016 (18.09.2015)

18.  

J. A. P. Sprenger, L. A. Bischoff, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions 
WO2016015811A1, 04.02.2016 (03.07.2014).

17.   J. A. P. Sprenger, J. Landmann, L. A. Bischoff, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing salts containing monohydrido-cyano-borate anions 
WO2015185183A1, 17.12.2015 (06.06.2014).
16.   J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing tetracyanoborate salts    
WO2015185178A1, 17.12.2015 (06.06.2014).
15.   J. A. P. Sprenger, J. Landmann, M. Finze, N. Ignatyev, E. Bernhardt, H. Willner, M. Schulte, K. Kawata, T. Goto
Merck Patent GmbH, 64293 Darmstadt (Germany)
Kobaltkomplexsalze    
DE102013021029A1, 02.07.2015 (17.12.2013).
14.   J. A. P. Sprenger, J. Landmann, M. Finze, V. Bernhardt-Pitchougina, N. Ignatyev, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Hexacyanodiborates    
WO2015/022048A1, 19.02.2015 (16.08.2013).
13.   N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for Producing Salts having Hydridocyanoborate Anions    
WO2014/198401A1, 18.12.2014 (14.06.2013).
12.   N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for Producing Salts having Monofluoro-Tricyanoborate Anions    
WO2014/198402A1, 18.12.2014 (14.06.2013).
11.   N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing alkyl-cyano-borate or alkyl-cyano-fluoroborate anions
WO2013/010641A1, 24.01.2013 (15.07.2011).
10.   N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing alkyl-alkoxy-cyano-borate anions
WO2013/010640A1, 24.01.2013 (15.07.2011).
9.   N. Ignatyev, M. Schulte, K. Kawata, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Electrolyte formulations containing cyano-alkoxy-borate anions
WO2012/041434A1, 05.04.2012 (28.09.2010).
8.   H. Shinohara, K. Kawata, H. Yoshizaki, P. Kirsch, N. Ignatyev, W.-R. Pitner, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing perfluoroalkyl-cyano-alkoxy-borate anions or perfluoroalkyl-cyano-alkoxy-fluoro-borate anions
WO2011/085967A1, 21.07.2011 (18.01.2010).
7.   N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing perfluoroalkyl cyanoborates or perfluoroalkyl cyanofluoroborates
WO2011/085966A1, 21.07.2011 (18.01.2010).
6.   K. Kawata, Yoshizaki, H. Shinohara, H. P. Kirsch, N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Electrolyte Formulations
WO2011/085965A1, 21.07.2011 (18.01.2010).
5.   M. Finze, E. Bernhardt, H. Willner, U. Welz-Biermann, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Their Binary and Complex Salts
WO2006045405, 04.05.2006 (04.10.2005).
4.   N. Ignatyev, U. Welz-Biermann, M. Finze, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Preparation of Salts Containing Alkoxytris(fluoroalkyl)borate Anions as Ionic Liquids
WO2006010455, 02.02.2006 (09.07.2005).
3.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
New stable, organic solvent-soluble cationic dyes with cyanoborate, fluoroalkyl phosphate, fluoroalkyl borate or imidate anion, useful e.g. for dyeing plastics, synthetic fibers or flexographic printing inks    
DE2003157359, 07.07.2005 (12.09.2003).
2.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylborat-Farbstoffe
DE200310338834, 24.03.2005 (21.08.2003);
N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt, A. Kucheryna
Merck Patent GmbH, 64293 Darmstadt (Germany)
Cyanoborate, Fluoroalkyl Phosphate, Fluoroalkyl Borate or Imide Dyes
WO2005021661, 10.03.2005 (22.07.2004).
1.   U. Welz-Biermann, N. Ignatyev, E. Bernhardt, M. Finze, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Salze mit Cyanoborat-Anionen
DE20031006617, 26.08.2004 (14.02.2003);
Salts Comprising Cyanoborate Anions
WO2004072089, 26.08.2004 (15.01.2004).

     
4.   Zhenguo Huang, Suning Wang, Rian D. Dewhurst, Nikolai V. Ignat’ev, Maik Finze, Holger Braunschweig
Boron: Its role in energy related research and applications
Angew. Chem. Int. Ed.  2020, in press.
3.   Nikolai V. Ignat'ev and Maik Finze
Cyaonoborates

Eur. J. Inorg. Chem. 2019, 35393560
Cover Profile
- Front Cover -
2.   N. V. Ignat'ev, M. Finze, J. A. P. Sprenger, C. Kerpen, E. Bernhardt, H. Willner
New Hydrophobic Ionic Liquids with Perfluoroalkylphosphate and Cyanofluoroborate Anions
J. Fluorine Chem. 2015, 177, 46–54.
1.   M. Finze, E. Bernhardt, H. Willner
Trifluoromethylboranes and -Borates: New Synthetic Strategies and Applications
Angew. Chem. Int. Ed. 2007, 46, 9180–9196. 

3. Anorganische und Allgemeine Chemie
M. Binnewies, M. Finze, M. Jäckel, P. Schmidt, H. Willner, G. Rayner-Canham
3. Auflage – 2016
Springer Spektrum – ISBN-13: 978-3662450666




 
2. Studienhefte zur Anorganischen Chemie
Fernstudium Bachelor Chemie
P. Schmidt, M. Binnewies, M. Finze
  • Anorganische Chemie I – Elemente, Wasserstoff, Gruppe 1
    Springer Spektrum – ISBN 978-3-662-47557-7
 
  • Anorganische Chemie II – Gruppe 2, Gruppe 13
    Springer Spektrum – ISBN 978-3-662-47549-2
 
  • Anorganische Chemie III – Gruppe 14, Ressourceneffizienz
    Springer Spektrum – ISBN 978-3-662-47561-4
 
  • Anorganische Chemie IV – Gruppen 15 und 16
    Springer Spektrum – ISBN 978-3-662-47565-2
 
  • Anorganische Chemie V – Gruppen 17 und 18, Chemie und Umwelt
    Springer Spektrum – ISBN 978-3-662-47547-8

 

1. Anorganische Chemie – Prinzipien von Struktur und Reaktivität
J. E. Huheey, E. A. Keiter. R. L. Keiter
5. vollständig überarbeitete Auflage – 2014
Hrsg. R. Steudel
Bearb. v. F. Breher, M. Finze, D. Johrendt, H.-J. Lunk, M. Kaupp, U. Radius, U. Schatzschneider
Kap. 11 Koordinationschemie: Struktur und Bindung (M Finze und U. Radius)
Kap. 12 Charakterisierung von Koordinationsverbindungen (U. Radius und M. Finze)
Kap. 13 Strukturen von Koordinationsverbindungen (M. Finze und U. Radius)
Kap. 14 Reaktionen von Koordinationsverbindungen: Kinetik und Mechanismen (U. Radius und M. Finze)
de Gruyter Studium – ISBN-13: 978-3110304336

   

3.   17. Deutscher Fluortag
J. A. P. Sprenger, M. Finze, Nachrichten aus der Chemie, 2017, 65, 77.
2.   14. Fluorchemikertreffen in Schmitten
M. Finze, C. Knapp, S. Riedel, Nachrichten aus der Chemie, 2011, 59, 378.
1.   12. Deutscher Fluortag
M. Finze, Nachrichten aus der Chemie, 2006, 54, 1247.

2020

127.   Zhenguo Huang, Suning Wang, Rian D. Dewhurst, Nikolai V. Ignat’ev, Maik Finze, Holger Braunschweig
Boron: Its role in energy related research and applications
Angew. Chem. Int. Ed.  2020, in press.
126.   Florian Rauch, Sonja Fuchs, Alexandra Friedrich, Daniel Sieh, Ivo Krummenacher, Holger Braunschweig, Maik Finze, and Todd B. Marder
Highly stable, readily reducible, fluorescent, trifluoromethylated 9-borafluorenes
Chem. Eur. J.  2020, accepted.
125.   Michael Hailmann, Krzysztof Radacki, and Maik Finze
Silver(I) Clusters Stabilized by the Carba‐closo‐dodeca¬boranyl¬ethynyl Ligand with O‐Donor Coligands and Template Ions
Z. Anorg. Allg. Chem. 2020646, 1–8.
124.   Anna E. Thomas, Steven D. Chambreau, Neil D. Redeker, Alan A. Esparza, Evgeny Shafirovich, Tatjana Ribbeck, Jan A. P. Sprenger, Maik Finze, Ghanshyam L. Vaghjiani
Thermal Decomposition and Hypergolic Reaction of a
Dicyanoborohydride Ionic Liquid
J. Phys. Chem. A  2020, 124(5), 864874.

2019

123.   Ilka Simon, Julius Hornung, Juri Barthel, Jörg Thomas, Maik Finze, Roland A. Fischer and Christoph Janiak
Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids

Beilstein J. Nanotechnol.  2019, 10, 1754–1767.
122.   Tatjana Ribbeck, Christoph Kerpen, Christian Schmidle, Fabian Keppner, Jan A. P. Sprenger, Merle Arrowsmith, Holger Braunschweig, Nikolai V. Ignat’ev, Maik Finze
Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties

Inorg. Chem.  201958(24), 1668916702.
121.   Jiang He, Florian Rauch, Alexandra Friedrich, Daniel Sieh, Tatjana Ribbeck, Ivo Krummenacher, Holger Braunschweig, Maik Finze, and Todd B. Marder
N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–p–A Compounds

Chem. Eur. J2019, 25, 13777–13784.

120.   Nikolai V. Ignat'ev and Maik Finze
Cyaonoborates

Eur. J. Inorg. Chem. 2019, 35393560
Cover Profile
- Front Cover -
119.   M. Hailmann, A. Himmelspach, F. Keppner, Philipp T. Hennig, R. Bertermann, M. Finze, B. Hupp, and A. Steffen
Carba-closo-dodecaboranylethynyl ligands facilitating luminescent reversed charge-transfer excited states in gold/silver complexes

Chem. Commun2019, 55(63), 9351–9354.
118.   P. T. Hennig, J. A. P. Sprenger, L. N. Schneider, N. V. Ignat'ev and M. Finze
The pentafluoroethylhydridoborate anion: From shock sensitive salts to stable room temperature ionic liquids    
Chem. Commun.   2019, 55, 6110–6113.
117.   Ru-Jin Li, Muxin Han, Jacopo Tessarolo, Julian J. Holstein, Jens Lübben, Birger Dittrich, Christian Volkmann, Maik Finze, Carsten Jenne, and Guido H. Clever
Successive Photoswitching and Derivatization Effects in Photochromic Dithienylethene-Based Coordination Cages

ChemPhotoChem  2019, 378383.
116.   Lisa A. Bischoff, Michael Drisch, Christoph Kerpen, Philipp T. Hennig, Johannes Landmann, Jan A. P. Sprenger, Rüdiger Bertermann,  Matthias Grüne,  Qinqin Yuan, Jonas Warneke, Xuebin Wang,  Nikolai Ignat'ev, and Maik Finze
Cyanohydridoborate Anions: Synthesis, Salts, and Low-viscosity Ionic Liquids
Chem. Eur. J.  2019, 25, 3560–3574.
115.   Tatjana Ribbeck, Christoph Kerpen, Dominic Löw, Alexander E. Sedykha, Klaus Müller-Buschbaum, Nikolai V. Ignat’ev, Maik Finze
Lanthanide trifluoromethyltricyanoborates: Synthesis, crystal structures and thermal properties

J. Fluor. Chem2019, 219, 70–78.
114.   Michael Lucas, Stephen J. Brotton, Jan A. P. Sprenger, Maik Finze, Shiv K. Sharma, and Ralf I. Kaiser
Oxidation of a Levitated 1‑Butyl-3-methylimidazolium Dicyanoborate Droplet by Nitrogen Dioxide
J. Phys. Chem. A   2019, 123, 780–795.
113.   Jonas Warneke, Markus Rohdenburg, Judy K. Y. Liu, Erynn Johnson, Xin Ma, Rashmi Kumar, Pei Su, Edoardo Aprà, Xue-Bin Wang, Carsten Jenne, Maik Finze, Hilkka I. Kenttämaa, Julia Laskin
Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions
Int. J. Mass Spectr.  2019, 436, 71–78.
112.   Jonas Warneke, Szymon Z. Konieczka, Gao-Lei Hou, Edoardo Aprà, Christoph Kerpen, Fabian Keppner, Thomas C. Schäfer, Michael Deckert, Zheng Yang, Eric J. Bylaska, Grant E. Johnson, Julia Laskin, Sotiris S. Xantheas, Xue-Bin Wang and Maik Finze
Properties of perhalogenated {closo-B10} and {closo-B11} multiply charged anions and a critical comparison with {closo-B12} in the gas and the condensed phase

Phys. Chem. Chem. Phys2019, 21, 5903–5915.
- Back Cover -

2018

111.   Sven H. Zottnick, Wiebke G. Daul, Christoph Kerpen, Maik Finze, and Klaus Müller-Buschbaum
Lanthanide Coordination Polymers and MOFs based on the Dicyanodihydridoborate Anion
Chem. Eur. J.  2018, 24, 15287–15294.
110.   Sven H. Zottnick, Jan A.  P. Sprenger, Maik Finze, and Klaus Müller-Buschbaum
Transformation of [EMIm][BPB] into a Cationic Luminescent Ln‐Coordination Polymer with the Bis(phthalato)borate Anion
Z. Anorg. Allg. Chem2018, 644, 11445–1450.
109.   Lisa A. Bischoff, Jan A. P. Sprenger, Philipp T. Hennig, Nikolai V. Ignat'ev, Maik Finze
Chlorocyanoborates: Synthesis, Spectroscopic and Structural Characterization, and Properties of Ionic Liquids
Z. Anorg. Allg. Chem2018, 644, 1285–1292.
108.   Szymon Z. Konieczka, Florian Schlüter, Christoph Sindorf, Christoph Kerpen, Eduard Bernhardt, and Maik Finze
Stepwise Introduction of Cyano Groups into nido- and closo-Undecaborate Clusters
Chem. Eur. J.  2018, 24, 3528–3538.
107.   Silke Santner, Jan A. P. Sprenger, Maik Finze and Stefanie Dehnen
The Role of [BF4] and [B(CN)4] Anions in the Ionothermal Synthesis of Chalcogenidometalates
Chem. Eur. J201824, 3474–3480.
106.   Jan A. P. Sprenger, Christoph Kerpen, Nikolai Ignat'ev and Maik Finze
Convenient Synthesis of Perfluoroalkyltrifluoroborates
J. Fluor. Chem.  2018, 206, 54–60.
105.   Johannes Landmann, Jan A. P. Sprenger, Philipp T. Hennig, Rüdiger Bertermann, Matthias Grüne, Frank Würthner, Nikolai V. Ignat'ev, and Maik Finze
Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscoity Ionic Liquids
Chem. Eur. J.  2018, 24, 608–623.
- Front Cover -
104.   M. Drisch, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verbindungen mit ein-, bis- und mehrfach geladenen schwach koordinierenden Anionen
DE102016010488A1, 01.03.18 (30.08.2016).
103.   J. A. P. Sprenger, P. T. Hennig, L. N. Schneider, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylhydrido- und Fluoralkylcyanohydridoborate
DE102016009846A1, 22.02.2018 (16.08.2016).

2017

102.   M Hailmann, N. Wolf, R. Renner, B. Hupp, A. Steffen, M. Finze
Silver(I) Clusters with Carba-closo-dodecaboranylethynyl Ligands: Synthesis, Structure, and Phosphorescence
Chem. Eur. J.  2017, 23, 11684–11693.
101.   S. H. Zottnick, M. T. Seuffert, C. Kerpen, M. Finze
Homoleptic Luminescent Lanthanide Frameworks with the Tricyanohydridoborate Anion
Eur. J. Inorg. Chem.  2017, 4668–4672.
100.   J. Landmann, P. T. Hennig, N. V. Ignat'ev, M. Finze
Borylation of Fluorinated Arenes with the Boron-centered Nucleophile B(CN)32-– a Unique Entry to Aryltricyanoborates
Chem. Sci.  2017, 8, 5962–5968.
99.   Y. T. A. Wong, J. Landmann, M. Finze, D. L. Bryce
Dynamic Disorder and Electronic Structures of Electron-Precise Dianionic Diboranes: Insights from Solid-State Multinuclear Magnetic Resonance Spectroscopy
J. Am. Chem. Soc.  2017, 139, 8200–8211.
98.   N. Wolf, M. Hailmann, M. Finze
Silver(I) Complexes of 12-Phenylalkynyl- and 12-Triisopropylalkynylcarba-closo-dodecaborate Anions
Eur. J. Inorg. Chem.  2017, 4459-4466.
97.   S. H. Zottnick, M. Finze, K. Müller-Buschbaum
Transformation of the Ionic Liquid [EMIM][B(CN)4] into Anionic and Neutral Lanthanum Tetracyanoborate Coordination Polymers by Ionothermal Reactions
Chem. Commun.  2017, 53, 5193.
96.   F. Falk, L. Herkert, L. Hackbarth, K. Müller-Buschbaum, M. Finze, M. Köckerling
Syntheses and Structures of New Rare Earth Metal Tetracyanidoborates
Z. Anorg. Allg. Chem.  2017, 643, 625–630.
95.   S. Zottnick, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum
Bis-Salicylatoborate as Versatile Sensitizer for Highly Luminescent Ln-oxoborates from UV to NIR with 4f- and 5d-Participation of the Lanthanides
Eur. J. Inorg. Chem.  2017, 10, 1355–1363.
94.   T. Ribbeck, S. H. Zottnick, C. Kerpen, J. Landmann, N. V. Ignat'ev, K. Müller-Buschbaum, M. Finze
Anhydrous, Homoleptic Lanthanide Frameworks with the Pentafluoroethyltricyanoborate Anion
Inorg. Chem.  2017, 56, 2278–2286.
93.  

C. Kerpen, J. A. P. Sprenger, L. Herkert, M. Schäfer, L. A. Bischoff, P. Zeides, M. Grüne, R. Bertermann, F. A. Brede, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze
Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions
Angew. Chem. Int. Ed.  2017, 56, 2800–2804.
- Front Cover -

92.   J. Landmann, F. Keppner, D. B. Hoffmann, J. A. P. Sprenger, M. Häring, S. H. Zottnick, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze
Deprotonation of Hydridoborate Anion
Angew. Chem. Int. Ed.  2017, 56, 2795–2799.

91.

  S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum
Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates
Z. Anorg. Allg. Chem 2017, 643, 53–59.
90.   N. Arnold, R. Bertermann, F. M. Bickelhaupt, H. Braunschweig, M. Drisch, M. Finze, F. Hupp, J. Poater, J. A. P. Sprenger
Formation of a Trifluorophosphane Platinum (II) Complex via P-F Bond Activation of Phosphorus Pentafluoride with a Pt(0) Complex
Chem. Eur. J.  2017, 23, 5948–5952.
89.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Monofluorotricyanoboratanionen
DE102015016401A1, 22.06.2017 (18.12.2015).
88.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Perfluoralkyltricyanoboratanionen oder Tetracyanoboratanionen
DE102015016400A1, 22.06.2017 (18.12.2015).
87.   L. A. Bischoff, J. A. P. Sprenger, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Kaliummonofluorotricyanoborat
DE102016001344A1, 16.03.2017 (08.02.2016).

2016

86.   K. Duda, A. Himmelsbach, J. Landmann, F. Kraus, M. Finze
Synthesis of the Fluorohydridoborate Anions [BHF3] and [1-HF2B-9,12-X2-closo-1,2-C2B10H9] (X = H, I): Deboronation of 1,2- and 1,7-dicarba-closo-dodecaboranes with anhydrous [Me4N]F
Chem. Commun.  2016, 52, 13241–13244.
85.   M. Arrowsmith, D. Auerhammer, R. Bertermann, H. Braunschweig, G. Bringmann, M. A. Celik, R. D. Dewhurst, M. Finze, M. Grüne, M. Hailmann, T. Hertle, I. Krummenacher
Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square
Angew. Chem. Int. Ed.  2016, 55, 14464–14468.
84.   M. Hailmann, N. Wolf, R. Renner, T. C. Schäfer, B. Hupp, A. Steffen, M. Finze
Unprecedented Efficient Structure Controlled Phosphorescence of Silver(I) Clusters Stabilized by Carba-closo-dodecaboranylethynyl Ligands
Angew. Chem. Int. Ed2016, 55, 10507–10511.
83.   J. Warneke, T. Dülcks, D. Kemken, M. Finze
Identification of a neutral loss from precursor ions with nearly Gaussian-shaped isotopic patterns via inverted isotopic patterns of product ions 
Rapid Commun. Mass. Spectrom.  2016, 30, 985–991.
82.   J. A. P. Sprenger, M. Finze, J. Landmann, A. Lennert, U. Schmid-Großmann, J. Eichhorn
Merck Patent GmbH, 64293 Darmstadt (Germany)
Polymere enthaltend polymerisierte ionische Flüssigkeiten und deren Anwendung in Membranen
DE102015006493A1, 24.11.2016 (22.05.2015).
81.   J. Landmann, F. Keppner, J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Verbindungen mit Tricyanoborat-Dianionen
DE20141018103 20141209, 09.06.2016 (09.12.2014).
80.   M. Drisch, L. A. Bischoff, L. Herkert, J. A. P. Sprenger, M. Finze, N. Ignatyev, R. Van Hal
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions
WO2016074760A1, 19.05.2016 (19.10.2015).
79.   J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing perfluoralkylfluoroborate salts
WO2016074756A1, 19.05.2016 (15.10.2015).
78.   J. A. P. Sprenger, L. A. Bischoff, M. Drisch, L. Herkert, M. Finze, H. Willner, E. Bernhardt, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing compounds with monofluorotricyanoborate anions
WO2016058665A1, 21.04.2016 (18.09.2015).
77   J. A. P. Sprenger, L. A. Bischoff, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions 
WO2016015811A1, 04.02.2016 (03.07.2014).

2015

76.   J. A. P. Sprenger, S. Z. Konieczka, F. A. Brede, C. Kerpen, M. Hailmann, K.-D. Franz, N. Ignat'ev, G. J. Reiss, W. Frank, M. Finze
N,N'-Bis(trifluoromethylsulfonyl)oxamidates – Syntheses, Thermal, Electrochemical, Spectroscopic, and Structural Properties 
Eur. J. Inorg. Chem.  2015, 5639–5649.
75.    J. Landmann, J. A. P. Sprenger, M. Hailmann, V. Bernhardt-Pitchougina, H. Willner, N. Ignat'ev, E. Bernhardt, M. Finze
The Hexacyanodiborane(6) Dianion [B2(CN)6]2 
Angew. Chem. Int. Ed.  201554, 11259–11264.
74.    S. Z. Konieczka, M. Drisch, K. Edkins, M. Hailmann, M. Finze
Polyfluorinated carba-closo-dodecaboranes with amino and ammonio substituents bonded to boron 
Dalton Trans.  2015, 44, 19576–19586.
– Hot Article –
73.    J. A. P. Sprenger, J. Landmann, M. Drisch, N. Ignat'ev, M. Finze
Syntheses of Tricyanofluoroborates M[BF(CN)3] (M = Na, K): (CH3)3SiCl Catalysis, Countercation Effect, and Reaction Intermediates 
Inorg. Chem.  201554, 3403–3412.
72.    J. Landmann, J. A. P. Sprenger, R. Bertermann, N. Ignat'ev, V. Bernhardt-Pitchougina, E. Bernhardt, H. Willner, M. Finze
Convenient Access to the Tricyanoborate Dianion B(CN)32– and Selected Reactions as a Boron-centred Nucleophile
Chem. Commun.  201551, 4989–4992.
71.    A. Himmelspach, J. Warneke, M. Schäfer, M. Hailmann, M. Finze
Salts of the Dianions [Hg(12-X-closo-1-CB11H10)2] (X = I, CCH, CCFc, CCSiiPr3): Synthesis and Spectroscopic and Structural Characterization 
Organometallics  201534, 462–469.
70.   M. Schäfer, I. Krummenacher, H. Braunschweig, M. Finze
Boron Clusters with a Ferrocenylalkynyl Group Bonded to Boron: Synthesis, Characterization, and Electrochemical Trends
Z. Anorg. Allg. Chem.  2015641, 660–668.
69.    S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum
1[Pr(BSB)3(py)2]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions 
Z. Anorg. Allg. Chem.  2015641, 164–167.
68.    J. A. P. Sprenger, M. Schäfer, N. Ignatiev, M. Finze
Salts of Novel Chelatoborate Anions: [RFBX(ox)] (RF = CF3C2F5; X = F, OMe; ox = oxalato) and [RFB(OMe)(cat)] (RF = CF3C2F5; cat = catecholato)
J. Fluorine Chem.  2015174, 30–35.
67.   J. A. P. Sprenger, J. Landmann, L. A. Bischoff, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing salts containing monohydrido-cyano-borate anions 
WO2015185183A1, 17.12.2015 (06.06.2014).
68.   J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing tetracyanoborate salts    
WO2015185178A1, 17.12.2015 (06.06.2014).
67.   J. A. P. Sprenger, J. Landmann, M. Finze, N. Ignatyev, E. Bernhardt, H. Willner, M. Schulte, K. Kawata, T. Goto
Merck Patent GmbH, 64293 Darmstadt (Germany)
Kobaltkomplexsalze    
DE102013021029A1, 02.07.2015 (17.12.2013).
66.   J. A. P. Sprenger, J. Landmann, M. Finze, V. Bernhardt-Pitchougina, N. Ignatyev, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Hexacyanodiborates    
WO2015/022048A1, 19.02.2015 (16.08.2013).

2014

65.   M. Hailmann, S. Z. Konieczka, A. Himmelspach, J. Löblein, G. J. Reiss, M. Finze
Carba-closo-dodecaborate Anions with Two Functional Groups: [1-R-12-HCC-closo-1-CB11H10] (R = CN, NC, CO2H, C(O)NH2, NHC(O)H)
Inorg. Chem.  201453, 9385–9399.
64.   K. Junold, J. A. Baus, C. Burschka, M. Finze, R. Tacke
Selective C–H Bond Activation of 1,2-Dicarba-closo-dodecaborane
by the Donor-Stabilized Silylene
Bis[N,N'-diisopropylbenzamidinato(–)]silicon(II)

Eur. J. Inorg. Chem.  2014, 5099–5102.
63.   N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for Producing Salts having Hydridocyanoborate Anions    
WO2014/198401A1, 18.12.2014 (14.06.2013).
62.   N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for Producing Salts having Monofluoro-Tricyanoborate Anions    
WO2014/198402A1, 18.12.2014 (14.06.2013).

2013

61.   M. Hailmann, L. Herkert, A. Himmelspach, M. Finze
Difunctionalized {closo-1-CB11} Clusters: 1- and 2-Amino-12-ethynylcarba-closo-dodecaborates
Chem. Eur. J.  2013, 51, 15745–15758.
60.   M. Drisch, J. A. P. Sprenger, M. Finze
Carba-closo-dodecaborate Anions with Cluster
Carbon‒Phosphorous Bonds

Z. Anorg. Allg. Chem.  2013, 639, 1134–1139.
59.   S. Schlecht, M. Finze, R. Bertermann, W. Frank, A. Domann, M. Braun
Cocrystallising Rotamers of a Pentacoordinate Silicon Complex with a Chiral Aminodiol Ligand
Eur. J. Inorg. Chem2013, 1488–1492.
58.   R. T. Boeré, C. Bolli, M. Finze, A. Himmelspach, C. Knapp, T. L. Roemmele
Quantum-Chemical and Electrochemical Investigation of the Electrochemical Windows of Halogenated Carborate Anions
Chem. Eur. J.  2013, 51, 1784–1795.
57.   S. Z. Konieczka, A. Himmelspach, M. Hailmann, M. Finze
Synthesis, Characterization, and Selected Properties of
7- and 12-Ammoniocarba-closo-dodecaboranes

Eur. J. Inorg. Chem.  2013, 134–146.
56.   N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing alkyl-cyano-borate or alkyl-cyano-fluoroborate anions
WO2013/010641A1, 24.01.2013 (15.07.2011).
55.   N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing alkyl-alkoxy-cyano-borate anions
WO2013/010640A1, 24.01.2013 (15.07.2011).

2012

54.  

A. Himmelspach, M. Finze, A. Vöge, D. Gabel
Cesium and Tetrabutylammonium Salt of the Ethynyl-closo-dodecaborate Dianion
Z. Anorg. Allg. Chem2012, 638, 512–519.
Cover Picture

53.   A. Himmelspach, G. J. Reiss, M. Finze
Microwave-assisted Kumada-type Cross-coupling Reactions of Iodinated Carba-closo-dodecaborate Anions
Inorg. Chem.  2012, 51, 2679–2688.
52.   A. Himmelspach, J. A. P. Sprenger, J. Warneke, M. Zähres, M. Finze
Mercury(II) Complexes of the Carba-closo-dodecaboranyl Ligands [closo-1-CB11X11]2 (X = H, F, Cl, Br, I) – Special Issue: Fluorine in Organometallic Chemistry
Organometallics  2012, 31, 1566–1577.
51.   M. Finze, G. J. Reiß
Ammonium 4,4-difluoro-1,3,2-dithiazetin-2-ide 1,1,3,3-tetraoxide
Acta Crystallogr.  2012, E68, o1992–o1993.
50.   M. Finze, G. J. Reiß, H.-J. Frohn
2,3,5,6-Tetrafluoro-1,4-bis(trimethylsilyl)benzene
Acta Crystallogr.  2012, E68, o1082.
49.   M. Finze, G. J. Reiß
Trimethylsulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodecaborate
Acta Crystallogr.  2012, E68, o640.
48.   N. Ignatyev, M. Schulte, K. Kawata, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Electrolyte formulations containing cyano-alkoxy-borate anions
WO2012/041434A1, 05.04.2012 (28.09.2010).

2011

47.   E. Bernhardt, M. Finze, H. Willner
Mechanistic Study on the Fluorination of K[B(CN)4] with ClF Enabling the High Yield and Large Scale Synthesis of K[B(CF3)4] and K[(CF3)3BCN]
Inorg. Chem.  2011, 50, 10268–10273.
46.   A. Himmelspach, M. Finze, S. Raub
Tetrahedral Gold(I) Clusters with Carba-closo-dodecaboranylethynido Ligands: [{12-(R3PAu)2C≡C-closo-1-CB11H11}2]
Angew. Chem. Int. Ed.  2011, 50, 2628–2631.
45.   A. Himmelspach, M. Zähres, M. Finze
Salts of the Lewis-Acidic Dianion [Hg(closo-1-CB11F11)2]2: Coordination of Acetonitrile and Water
Inorg. Chem.  2011, 50, 3186–3188.
44.   G. J. Reiß, M. Finze
4-s-cis-1,3-Butadiene)tetracarbonylchromium(0)
Acta Crystallogr.  2011, E67, m333.
43.   A. Himmelspach, G. J. Reiß, M. Finze
2-Azaniumylcarba-closo-dodecaborate ethanol monosolvate
Acta Crystallogr.  2011, E67, o704.
42.   G. J. Reiß, M. Finze
μ2:2-s-trans-Butadieneoctacarbonyldiiron(0) – Structural and Spectroscopic Properties
J. Organomet. Chem.  2011, 696, 512–516.
41.   H. Shinohara, K. Kawata, H. Yoshizaki, P. Kirsch, N. Ignatyev, W.-R. Pitner, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing perfluoroalkyl-cyano-alkoxy-borate anions or perfluoroalkyl-cyano-alkoxy-fluoro-borate anions
WO2011/085967A1, 21.07.2011 (18.01.2010).
40.   N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing perfluoroalkyl cyanoborates or perfluoroalkyl cyanofluoroborates
WO2011/085966A1, 21.07.2011 (18.01.2010).
39.   K. Kawata, Yoshizaki, H. Shinohara, H. P. Kirsch, N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Electrolyte Formulations
WO2011/085965A1, 21.07.2011 (18.01.2010).

2010

38.   S. Konietzny, M. Finze, G. J. Reiß
Tricarbonyl-6,6’-dimethylfulvene chromium(0) – Structural Properties
J. Organomet. Chem.  2010, 695, 512–516.
37.   M. Finze, J. A. P. Sprenger
1-Amino-2-fluoromonocarba-closo-dodecaborates: K[1-H2N-2-F-closo-1-CB11H10] and [Et4N][1-H2N-2-F-closo-1-CB11I10]
Z. Anorg. Allg. Chem.  2010, 636, 1538–1542.
36.   M. Finze, G. J. Reiss
9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodecaborane
(1,2-Me2-9-HCC-closo-1,2-C2B10H9)

Acta Crystallogr.  2010, E66, o1709–o1710.
35.   A. Himmelspach, M. Finze
Dicarba-closo-dodecaboranes with One and Two Ethynyl Groups Bonded to Boron
Eur. J. Inorg. Chem.  2010, 2012–2024.
34.   A. Himmelspach, M. Finze
Ethynylmonocarba-closo-dodecaborates: M[12-HCC-closo-1-CB11H11] and M[7,12-(HCC)2-closo-1-CB11H10] (M= Cs+, [Et4N]+)
J. Organomet. Chem.  2010, 695, 1337–1345.
33.   J. A. P. Sprenger, M. Finze, B. B. Schaack
Salts of the 1-cyanocarba-closo-dodecaborate anions
[1-NC-closo-1-CB11X11](X = H, F, Cl, Br, I)
Dalton Trans.  2010, 39, 2708-2716.

2009

32.   M. Finze, J. A. P. Sprenger
Anionic Gold(I) Complexes – Twelve- and Ten-Vertex Monocarba-closo-borate Anions with Carbon-Gold s-Bonds
Chem. Eur. J.  2009, 15, 9918–9927.
31.   M. Finze, G. J. Reiss
Tetraethylammonium-12-phenylethinylcarba-closo-dodecaborate – [Et4N][12-PhCC-closo-CB11H11]
Acta Crystallogr.  2009, E65, o1048.
30.   M. Finze
Regioselective Monoiodination of Carba-closo-dodecaborates: M[7-I-12-X-closo-CB11H10] (M = Cs+, [Et4N]+; X = F, Cl, Br, OH)
Eur. J. Inorg. Chem.  2009, 501–507.
29.   M. Finze
Synthesis and Characterization of 2-Mono- and 1,2-Diaminocarba-closo-dodecaborates M[1-R-2-H2N-closo-CB11H10] (R=H, Ph, H2N, CyHN)
Chem. Eur. J.  2009, 15, 947–962.

2008

28.   M. Finze
Carba-closo-dodecaborates with One or Two Alkynyl Substituents Bonded to Boron
Inorg. Chem.  2008, 47, 11857–11867.
27.   M. Finze, G. J. Reiss
Salts with the Triborate Anion [B3O3F2(OH)2]: A Combined Experimental and Theoretical Study
Eur. J. Inorg. Chem.  2008, 2321–2325.

2007

26.   M. Finze
Carbon Extrusion/Cluster Contraction: Synthesis of the Fluorinated Cyano-closo-Undecaborate K2[3-NC-closo-B11F10]
Angew. Chem. Int. Ed.  2007, 46, 8880–8882.
25.   M. Finze, G. J. Reiss, M. Zähres
[1-H2N-CB11F11] – Synthesis and Reactions of a Functionalized Fluorinated Carbadodecaborate Anion
Inorg. Chem.  2007, 46, 9873–9883.
24.   E. Bernhardt, D. J. Brauer, M. Finze, H. Willner
closo-[B21H18]: A Face-Fused Diicosahedral Borate Ion
Angew. Chem. Int. Ed.  2007, 46, 2927–2930.

2006

23.   E. Bernhardt, M. Finze, H. Willner, C. W. Lehmann
Salts of the Cobalt(I) Complexes [Co(CO)5]+ and [Co(CO)2(NO)2]+ and the Lewis Acid-Base Adduct [Co2(CO)7CO-B(CF3)3]
Chem. Eur. J.  2006, 12, 8276–8283.
22.   E. Bernhardt, D. J. Brauer, M. Finze, H. Willner
[B(CO2H)4] and [B(CNCH3)4]3+: Homoleptic Boron Complexes Containing Carboxy and Methylisonitrile Ligands
Angew. Chem. Int. Ed.  2006, 45, 6383–6386.
21.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
(PPh3)3RhCNB(CF3)3 and (PPh3)3RhNCB(CF3)3 – Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphin)rhodium(I)
Organometallics  2006, 25, 3070–3075.
20.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
Reactions of (CF3)3BCO with Amines and Phosphines
Inorg. Chem.  2006, 45, 669–678.
19.   E. Bernhardt, M. Finze, H. Willner
Eine neue Synthese für Nitrosyl-Salze mit schwach koordinierenden Anionen am Beispiel von NO[B(CF3)4]
Z. Anorg. Allg. Chem.  2006, 632, 248–250.
18.   M. Finze, E. Bernhardt, H. Willner, U. Welz-Biermann, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Their Binary and Complex Salts
WO2006045405, 04.05.2006 (04.10.2005).
17.   N. Ignatyev, U. Welz-Biermann, M. Finze, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Preparation of Salts Containing Alkoxytris(fluoroalkyl)borate Anions as Ionic Liquids
WO2006010455, 02.02.2006 (09.07.2005).

2005

16.   M. Finze, E. Bernhardt, M. Berkei, H. Willner, J. Hung, R. M. Waymouth
[H(OEt2)2]+ and [Ph3C]+ Salts of the Borate Anions [B(CF3)4],
[(CF3)3BCN], and [B(CN)4]

Organometallics 2005, 24, 5103–5109.
15.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
Cyano- and Isocyanotris(trifluoromethyl)borates, K[(CF3)3BCN] and K[(CF3)3BNC] – Synthesis, Spectroscopic Properties and Solid State Structures
J. Am. Chem. Soc. 2005, 127, 10712–10722.
14.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
Haloacylcomplexes of Boron, [(CF3)3BC(O)Hal] (Hal = F, Cl, Br, I)
Chem. Eur. J. 2005, 11, 6653–6665.
13.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann, F. Aubke
[M(CO)6][BF4]2 (M = Fe, Ru, Os): Thermally Stable Salts of Superelectrophilic Metal Carbonyl Cations with Fluoroborate Anions
Inorg. Chem. 2005, 44, 4206–4214.
12.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
New stable, organic solvent-soluble cationic dyes with cyanoborate, fluoroalkyl phosphate, fluoroalkyl borate or imidate anion, useful e.g. for dyeing plastics, synthetic fibers or flexographic printing inks    
DE2003157359, 07.07.2005 (12.09.2003).
11.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylborat-Farbstoffe
DE200310338834, 24.03.2005 (21.08.2003);
N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt, A. Kucheryna
Merck Patent GmbH, 64293 Darmstadt (Germany)
Cyanoborate, Fluoroalkyl Phosphate, Fluoroalkyl Borate or Imide Dyes
WO2005021661, 10.03.2005 (22.07.2004).

2004

10.   M. Finze, E. Bernhardt, H. Willner, C. W. Lehmann
[(CF3)3BCP] and [(CF3)3BCAs]: Thermally Stable Phosphaethynyl and Arsaethynyl Complexes
Angew. Chem. Int. Ed. 2004, 43, 4159–4163.
9.   E. Bernhardt, M. Finze, H. Willner
Synthesis and NMR spectroscopic investigation of salts containing the novel [Au(CF3)nX4–n](n = 4 – 1, X = F, CN, Cl) anions
J. Fluorine Chem. 2004, 125, 967–973.
8.   M. Finze, E. Bernhardt, M. Zähres, H. Willner
Rearrangement Reactions of the Transient Lewis Acids (CF3)3B and
(CF3)3BCF2: An Experimental and Theoretical Study

Inorg. Chem. 2004, 43, 490–505.
7.   U. Welz-Biermann, N. Ignatyev, E. Bernhardt, M. Finze, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Salze mit Cyanoborat-Anionen
DE20031006617, 26.08.2004 (14.02.2003);
Salts Comprising Cyanoborate Anions
WO2004072089, 26.08.2004 (15.01.2004).

2003

6.    M. Finze, S. E. Reybuck, R. M. Waymouth
Propylene Polymerization with 1,2’-Bridged Bis(indenyl)zirconium Dichlorides
Macromolecules 2003, 36, 9325–9334.
5.   E. Bernhardt, M. Finze, H. Willner
Eine effiziente Synthese von Tetracyanoboraten durch Sinterprozesse
Z. Anorg. Allg. Chem. 2003, 629, 1229–1234.
4.   E. Bernhardt, M. Finze, H. Willner, C. W. Lehmann, F. Aubke
[Co(CO)5][(CF3)3BF]: A Stable Salt of a Homoleptic Trigonal-Bipyramidal Metal-Carbonyl Cation
Angew. Chem. Int. Ed. 2003, 42, 2077–2079.
3.   E. Bernhardt, M. Finze, H. Willner, C. W. Lehmann, F. Aubke
The Fluoracyltris(trifluoromethyl)borate Ion, [(CF3)3BC(O)F]
Angew. Chem. Int. Ed. 2003, 42, 1052–1055.

2002

2.    R. M. Waymouth, G. M. Wilmes, M. Finze, S. E. Reybuck, S. Lin
Conformationally-Dynamic Metallocenes: Hypersensitive Systems for Modulating Stereochemistry
Polym. Mat. Sci. and Eng. 2002, 87, 48–49.
1.   M. Finze, E. Bernhardt, A. Terheiden, M. Berkei, H. Willner, D. Christen,
H. Oberhammer, F. Aubke
Tris(trifluoromethyl)borane Carbonyl, (CF3)3BCO – Synthesis, Physical, Chemical and Spectroscopic Properties, Gas Phase and Solid State Structure
J. Am. Chem. Soc. 2002, 124, 15385–15398.