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The Finze Group

Chair Holder - Prof. Dr. Maik Finze

Prof. Dr. Maik Finze

Chair Holder
Institute of Inorganic Chemistry, Chair III
Am Hubland
97074 Würzburg
Building: C2, Hubland Süd
Room: 02.024
Prof. Dr. Maik Finze

1995 - 2002 

Study of chemistry at the University of Hannover
1999 - 2000 Research stay with Professor Robert M. Waymouth (Stanford University)
Topic "Novel 1,2-bridged Bisindenyl Zirconium Complexes"

07.2001 - 01.2002     

Diploma thesis with Professor Helge Willner (University of Duisburg)
Topic: "Stabilization of electrophilic cations with the new weakly coordinating borate anions [B(CF3)4]- and [B(CN)4]-"

02.2002 - 09.2004

PhD with Professor Helge Willner (Universities of Duisburg, Wuppertal, and Hannover)
Topic: "The chemistry of the carbonyltris(trifluoromethyl)borane"

10.2004 - 11.2004

Postdoc with Professor Helge Willner (University of Wuppertal)

12.2004 - 04.2010

Habilitation (University of Düsseldorf)
Topic: "Salts of new functionalized carba-closo-dodecaborate anions - syntheses and properties"

2011 Professorship in Inorganic Chemistry (W2) offered at the University of Würzburg (accepted)
2011 Professorship in Inorganic Chemistry (W2) offered at the University of Wuppertal (declined)

05.2010 - 04.2011

Privatdozent (University of Düsseldorf)

05.2010 - 05.2016

Professor of Inorganic Chemistry - W2 (University of Würzburg)
2015 Professorship in Inorganic Chemistry (W3) offered at the University of Hamburg (declined)
since 10.2015 Vicedean of the Faculty of Chemistry and Pharmacy
since 06.2016

Professor of Inorganic Chemistry (W3) (University of Würzburg)
Chair of Inorganic Chemistry III

 

 

Publications

  For the complete publication list of the Research Group Prof. Finze please see   "All Publications from 2002"
_ Florian Rauch, Peter Endres, Alexandra Friedrich, Daniel Sieh, Martin Hähnel, Ivo Krummenacher, Holger Braunschweig, Maik Finze, Lei Ji, and Todd B. Marder
An iterative divergent approach to conjugated starburst borane dendrimers
Chem. Eur. J.  2020, accepted.
 
_ Lisa A. Bischoff, Jarno Riefer, Raphael Wirthensohn, Tobias Bischof, Rüdiger Bertermann, Nikolai V. Ignat'ev, and Maik Finze
Pentafluoroethylaluminates: A Combined Synthetic, Spectroscopic, and Structural Study
Chem. Eur. J.  2020, accepted.
 
_ Florian Rauch, Sonja Fuchs, Alexandra Friedrich, Daniel Sieh, Ivo Krummenacher, Holger Braunschweig, Maik Finze, and Todd B. Marder
Highly Stable, Readily Reducible, Fluorescent, Trifluoromethylated 9-Borafluorenes
Chem. Eur. J.  2020, 26, 12794–12808- Very Important Paper -
 
_ Michael Drisch, Lisa A. Bischoff, Jan A. P. Sprenger, Philipp T. Hennig, Raphael Wirthensohn, Szymon Z. Konieczka, Michael Hailmann, Nikolai V. Ignat'ev, and Maik Finze
Innovative Syntheses of Cyano(fluoro)borates: Catalytic Cyanation, Electrochemical and Electrophilic Fluorination
Chem. Eur. J.  2020, 26, 11625 –11633. - Hot Paper -
 
_ Florian Rauch, Johannes Krebs, Julian Günther, Alexandra Friedrich, Martin Hähnel, Ivo Krummenacher, Holger Braunschweig, Maik Finze, Todd B. Marder
Electronically Driven Regioselective Iridium‐Catalyzed C−H Borylation of Donor‐π‐Acceptor Chromophores Containing Triarylboron Acceptors
Chem. Eur. J. 2020, 26, 1062610633.
 
_ A. K. Narsaria, F. Rauch, J. Krebbs, P. Endres, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Finze, J. Nitsch, F. M. Bickelhaupt, and T. B. Marder 
Computationally Guided Molecular Design to Minimize the LE/CT Gap in D-π-A Fluorinated Triarylboranes for Efficient TADF via
D and π-Bridge
Tuning
Adv. Func. Mater.  2020, 30, 2002064.
 
_ Zhenguo Huang, Suning Wang, Rian D. Dewhurst, Nikolai V. Ignat’ev, Maik Finze, Holger Braunschweig
Boron: Its role in energy related research and applications
Angew. Chem. Int. Ed.  2020, 132, 88008816.
Bor in energiebezogenen Prozessen und Anwendungen
Angew. Chem.  2020, 59, 88828900.
 
_ Michael Hailmann, Krzysztof Radacki, and Maik Finze
Silver(I) Clusters Stabilized by the Carba‐closo‐dodeca¬boranyl¬ethynyl Ligand with O‐Donor Coligands and Template Ions
Z. Anorg. Allg. Chem. 2020646, 777–783.
 
_ Anna E. Thomas, Steven D. Chambreau, Neil D. Redeker, Alan A. Esparza, Evgeny Shafirovich, Tatjana Ribbeck, Jan A. P. Sprenger, Maik Finze, Ghanshyam L. Vaghjiani
Thermal Decomposition and Hypergolic Reaction of a
Dicyanoborohydride Ionic Liquid
J. Phys. Chem. A  2020, 124(5), 864874.
 
_ Ilka Simon, Julius Hornung, Juri Barthel, Jörg Thomas, Maik Finze, Roland A. Fischer and Christoph Janiak
Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids

Beilstein J. Nanotechnol. 2019, 10, 1754–1767.
 
_ Tatjana Ribbeck, Christoph Kerpen, Christian Schmidle, Fabian Keppner, Jan A. P. Sprenger, Merle Arrowsmith, Holger Braunschweig, Nikolai V. Ignat’ev, Maik Finze
Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties

Inorg. Chem.  2019, 58(24), 1668916702.
 
_ Jiang He, Florian Rauch, Alexandra Friedrich, Daniel Sieh, Tatjana Ribbeck, Ivo Krummenacher, Holger Braunschweig, Maik Finze, and Todd B. Marder
N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–p–A Compounds

Chem. Eur. J. 2019, 25, 13777–13784.

_ Nikolai V. Ignat'ev and Maik Finze
Cyaonoborates

Eur. J. Inorg. Chem. 2019, 35393560
Cover Profile
- Front Cover -
 
_

M. Hailmann, A. Himmelspach, F. Keppner, Philipp T. Hennig, R. Bertermann, M. Finze, B. Hupp, and A. Steffen
Carba-closo-dodecaboranylethynyl ligands facilitating luminescent reversed charge-transfer excited states in gold/silver complexes

Chem. Commun. 2019, 55(63), 9351–9354.

_ P. T. Hennig, J. A. P. Sprenger, L. N. Schneider, N. V. Ignat'ev and M. Finze
The pentafluoroethylhydridoborate anion: From shock sensitive salts to stable room temperature ionic liquids    
Chem. Commun. 2019, 55, 6110–6113.
 
_ Ru-Jin Li, Muxin Han, Jacopo Tessarolo, Julian J. Holstein, Jens Lübben, Birger Dittrich, Christian Volkmann, Maik Finze, Carsten Jenne,
and Guido H. Clever
Successive Photoswitching and Derivatization Effects in Photochromic Dithienylethene-Based Coordination Cages

ChemPhotoChem  2019, 378383.
 
_ Lisa A. Bischoff, Michael Drisch, Christoph Kerpen, Philipp T. Hennig, Johannes Landmann, Jan A. P. Sprenger, Rüdiger Bertermann,  Matthias Grüne,  Qinqin Yuan, Jonas Warneke, Xuebin Wang,  Nikolai Ignat'ev, and Maik Finze
Cyanohydridoborate Anions: Synthesis, Salts, and Low-viscosity Ionic Liquids

Chem. Eur. J.  2019, 25, 3560–3574.

_ Tatjana Ribbeck, Christoph Kerpen, Dominic Löw, Alexander E. Sedykha, Klaus Müller-Buschbaum, Nikolai V. Ignat’ev, Maik Finze
Lanthanide trifluoromethyltricyanoborates: Synthesis, crystal structures and thermal properties

J. Fluor. Chem2019, 219, 70–78.    
 
_ Michael Lucas, Stephen J. Brotton, Jan A. P. Sprenger, Maik Finze, Shiv K. Sharma, and Ralf I. Kaiser
Oxidation of a Levitated 1‑Butyl-3-methylimidazolium Dicyanoborate Droplet by Nitrogen Dioxide
J. Phys. Chem. A   2019, 123, 780–795.
 
_ Jonas Warneke, Markus Rohdenburg, Judy K. Y. Liu, Erynn Johnson, Xin Ma, Rashmi Kumar, Pei Su, Edoardo Aprà, Xue-Bin Wang, Carsten Jenne,
Maik Finze, Hilkka I. Kenttämaa, Julia Laskin
Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions
Int. J. Mass Spectr.  2019, 436, 71–78.
 
_ Jonas Warneke, Szymon Z. Konieczka, Gao-Lei Hou, Edoardo Aprà, Christoph Kerpen, Fabian Keppner, Thomas C. Schäfer, Michael Deckert, Zheng Yang, Eric J. Bylaska, Grant E. Johnson, Julia Laskin, Sotiris S. Xantheas, Xue-Bin Wang and Maik Finze
Properties of perhalogenated {closo-B10} and {closo-B11} multiply charged anions and a critical comparison with {closo-B12} in the gas and the condensed phase

Phys. Chem. Chem. Phys2019, 21, 5903–5915.

 

28.   M. Drisch, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verbindungen mit ein-, bis- und mehrfach geladenen schwach koordinierenden Anionen
DE102016010488A1, 01.03.18 (30.08.2016)
27.   J. A. P. Sprenger, P. T. Hennig, L. N. Schneider, N. Ignatiev, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylhydrido- und Fluoralkylcyanohydridoborate
DE102016009846A1, 22.02.2018 (16.08.2016)
26.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Monofluorotricyanoboratanionen
DE102015016401A1, 22.06.2017 (18.12.2015)
25.   J. A. P. Sprenger, M. Finze, N. Ignatiev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Salzen mit Perfluoralkyltricyanoboratanionen oder Tetracyanoboratanionen
DE102015016400A1, 22.06.2017 (18.12.2015)
24.   L. A. Bischoff, J. A. P. Sprenger, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Kaliummonofluorotricyanoborat
DE102016001344A1, 16.03.2017 (08.02.2016)
23.   J. A. P. Sprenger, M. Finze, J. Landmann, A. Lennert, U. Schmid-Großmann, J. Eichhorn
Merck Patent GmbH, 64293 Darmstadt (Germany)
Polymere enthaltend polymerisierte ionische Flüssigkeiten und deren Anwendung in Membranen
DE102015006493A1, 24.11.2016 (22.05.2015)
22.  

J. Landmann, F. Keppner, J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Verfahren zur Herstellung von Verbindungen mit Tricyanoborat-Dianionen
DE20141018103 20141209, 09.06.2016 (09.12.2014)

21.  

M. Drisch, L. A. Bischoff, L. Herkert, J. A. P. Sprenger, M. Finze, N. Ignatyev, R. Van Hal
Merck patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions
WO2016074760A1, 19.05.2016 (19.10.2015)

20.  

J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing perfluoralkylfluoroborate salts
WO2016074756A1, 19.05.2016 (15.10.2015)

19.  

J. A. P. Sprenger, L. A. Bischoff, M. Drisch, L. Herkert, M. Finze, H. Willner, E. Bernhardt, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing compounds with monofluorotricyanoborate anions
WO2016058665A1, 21.04.2016 (18.09.2015)

18.  

J. A. P. Sprenger, L. A. Bischoff, M. Finze, N. Ignatyev, M. Schulte
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing salts having hydridocyanoborate anions 
WO2016015811A1, 04.02.2016 (03.07.2014).

17.   J. A. P. Sprenger, J. Landmann, L. A. Bischoff, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing salts containing monohydrido-cyano-borate anions 
WO2015185183A1, 17.12.2015 (06.06.2014).
16.   J. A. P. Sprenger, M. Finze, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for preparing tetracyanoborate salts    
WO2015185178A1, 17.12.2015 (06.06.2014).
15.   J. A. P. Sprenger, J. Landmann, M. Finze, N. Ignatyev, E. Bernhardt, H. Willner, M. Schulte, K. Kawata, T. Goto
Merck Patent GmbH, 64293 Darmstadt (Germany)
Kobaltkomplexsalze    
DE102013021029A1, 02.07.2015 (17.12.2013).
14.   J. A. P. Sprenger, J. Landmann, M. Finze, V. Bernhardt-Pitchougina, N. Ignatyev, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Hexacyanodiborates    
WO2015/022048A1, 19.02.2015 (16.08.2013).
13.   N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for Producing Salts having Hydridocyanoborate Anions    
WO2014/198401A1, 18.12.2014 (14.06.2013).
12.   N. Ignatyev, J. A. P. Sprenger, J. Landmann, M. Finze
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for Producing Salts having Monofluoro-Tricyanoborate Anions    
WO2014/198402A1, 18.12.2014 (14.06.2013).
11.   N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing alkyl-cyano-borate or alkyl-cyano-fluoroborate anions
WO2013/010641A1, 24.01.2013 (15.07.2011).
10.   N. Ignatyev, M. Schulte, K. Kawata, T. Goto, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing alkyl-alkoxy-cyano-borate anions
WO2013/010640A1, 24.01.2013 (15.07.2011).
9.   N. Ignatyev, M. Schulte, K. Kawata, J. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Electrolyte formulations containing cyano-alkoxy-borate anions
WO2012/041434A1, 05.04.2012 (28.09.2010).
8.   H. Shinohara, K. Kawata, H. Yoshizaki, P. Kirsch, N. Ignatyev, W.-R. Pitner, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Compounds containing perfluoroalkyl-cyano-alkoxy-borate anions or perfluoroalkyl-cyano-alkoxy-fluoro-borate anions
WO2011/085967A1, 21.07.2011 (18.01.2010).
7.   N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Method for producing perfluoroalkyl cyanoborates or perfluoroalkyl cyanofluoroborates
WO2011/085966A1, 21.07.2011 (18.01.2010).
6.   K. Kawata, Yoshizaki, H. Shinohara, H. P. Kirsch, N. Ignatyev, M. Schulte, J. A. Sprenger, M. Finze, W. Frank
Merck Patent GmbH, 64293 Darmstadt (Germany)
Electrolyte Formulations
WO2011/085965A1, 21.07.2011 (18.01.2010).
5.   M. Finze, E. Bernhardt, H. Willner, U. Welz-Biermann, N. Ignatyev
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Their Binary and Complex Salts
WO2006045405, 04.05.2006 (04.10.2005).
4.   N. Ignatyev, U. Welz-Biermann, M. Finze, E. Bernhardt, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Preparation of Salts Containing Alkoxytris(fluoroalkyl)borate Anions as Ionic Liquids
WO2006010455, 02.02.2006 (09.07.2005).
3.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
New stable, organic solvent-soluble cationic dyes with cyanoborate, fluoroalkyl phosphate, fluoroalkyl borate or imidate anion, useful e.g. for dyeing plastics, synthetic fibers or flexographic printing inks    
DE2003157359, 07.07.2005 (12.09.2003).
2.   N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt
Merck Patent GmbH, 64293 Darmstadt (Germany)
Fluoralkylborat-Farbstoffe
DE200310338834, 24.03.2005 (21.08.2003);
N. Ignatyev, U. Welz-Biermann, H. Willner, M. Finze, E. Bernhardt, A. Kucheryna
Merck Patent GmbH, 64293 Darmstadt (Germany)
Cyanoborate, Fluoroalkyl Phosphate, Fluoroalkyl Borate or Imide Dyes
WO2005021661, 10.03.2005 (22.07.2004).
1.   U. Welz-Biermann, N. Ignatyev, E. Bernhardt, M. Finze, H. Willner
Merck Patent GmbH, 64293 Darmstadt (Germany)
Process for Preparation of Hydrogen Fluoroalkylborate Strong Acids and Salze mit Cyanoborat-Anionen
DE20031006617, 26.08.2004 (14.02.2003);
Salts Comprising Cyanoborate Anions
WO2004072089, 26.08.2004 (15.01.2004).

     
4.   Zhenguo Huang, Suning Wang, Rian D. Dewhurst, Nikolai V. Ignat’ev, Maik Finze, Holger Braunschweig
Boron: Its role in energy related research and applications
Angew. Chem. Int. Ed.  2020, in press.
3.   Nikolai V. Ignat'ev and Maik Finze
Cyaonoborates

Eur. J. Inorg. Chem. 2019, 35393560
Cover Profile
- Front Cover -
2.   N. V. Ignat'ev, M. Finze, J. A. P. Sprenger, C. Kerpen, E. Bernhardt, H. Willner
New Hydrophobic Ionic Liquids with Perfluoroalkylphosphate and Cyanofluoroborate Anions
J. Fluorine Chem. 2015, 177, 46–54.
1.   M. Finze, E. Bernhardt, H. Willner
Trifluoromethylboranes and -Borates: New Synthetic Strategies and Applications
Angew. Chem. Int. Ed. 2007, 46, 9180–9196. 

 

3.
Anorganische und Allgemeine Chemie
M. Binnewies, M. Finze, M. Jäckel, P. Schmidt, H. Willner, G. Rayner-Canham
3. Auflage – 2016
Springer Spektrum – ISBN-13: 978-3662450666

2.
Studienhefte zur Anorganischen Chemie
Fernstudium Bachelor Chemie
P. Schmidt, M. Binnewies, M. Finze

  • Anorganische Chemie I – Elemente, Wasserstoff, Gruppe 1
    Springer Spektrum – ISBN 978-3-662-47557-7
 
  • Anorganische Chemie II – Gruppe 2, Gruppe 13
    Springer Spektrum – ISBN 978-3-662-47549-2
 
  • Anorganische Chemie III – Gruppe 14, Ressourceneffizienz
    Springer Spektrum – ISBN 978-3-662-47561-4
 
  • Anorganische Chemie IV – Gruppen 15 und 16
    Springer Spektrum – ISBN 978-3-662-47565-2
 
  • Anorganische Chemie V – Gruppen 17 und 18, Chemie und Umwelt
    Springer Spektrum – ISBN 978-3-662-47547-8
 

1.
Anorganische Chemie – Prinzipien von Struktur und Reaktivität
J. E. Huheey, E. A. Keiter. R. L. Keiter
5. vollständig überarbeitete Auflage – 2014
Hrsg. R. Steudel
Bearb. v. F. Breher, M. Finze, D. Johrendt, H.-J. Lunk, M. Kaupp, U. Radius, U. Schatzschneider
Kap. 11 Koordinationschemie: Struktur und Bindung (M Finze und U. Radius)
Kap. 12 Charakterisierung von Koordinationsverbindungen (U. Radius und M. Finze)
Kap. 13 Strukturen von Koordinationsverbindungen (M. Finze und U. Radius)
Kap. 14 Reaktionen von Koordinationsverbindungen: Kinetik und Mechanismen (U. Radius und M. Finze)
de Gruyter Studium – ISBN-13: 978-3110304336

3.   17. Deutscher Fluortag
J. A. P. Sprenger, M. Finze, Nachrichten aus der Chemie, 2017, 65, 77.
2.   14. Fluorchemikertreffen in Schmitten
M. Finze, C. Knapp, S. Riedel, Nachrichten aus der Chemie, 2011, 59, 378.
1.   12. Deutscher Fluortag
M. Finze, Nachrichten aus der Chemie, 2006, 54, 1247.