Deutsch Intern
    Prof. Dr. Reinhold Tacke

    Original Works 2009 - 2010

    Publications 2009-2010

    28.J. B. G. Gluyas, C. Burschka, P. Kraft, R. Tacke, 5,6-disubstituted 1,2,3-trisilaindanes as silicon analogues of phantolide-type musk odorants: synthesis, structure, reactivity, and olfactory properties, Organometallics 29, 5897-5903 (2010). read more ...

    27.A. Berkefeld, D. Troegel, C. Burschka, R. Tacke, Synthesis and characterization of {[tris(trimethylsilyl)silyl]methyl}silanes of the formula type Me4–nSi[CH2Si(SiMe3)3]n (n = 1–3) and derivatives, Organometallics 29, 4548-4554 (2010). read more ...

    26.U.-P. Apfel, D. Troegel, Y. Halpin, S. Tschierlei, U. Uhlemann, M. Schmitt, J. Popp, H. Gorls, P. Dunne, M. Venkatesan, M. Coey, M. Rudolph, J. Vos, R. Tacke, W. Weigand, Models for the active site in [FeFe] hydrogenase with iron-bound ligands derived from bis-, tris-, and tetrakis(mercaptomethyl)silanes, Inorg. Chem. 695, 2614-2617 (2010). read more ...

    25.S. Falgner, G. Buchner, R. Tacke, Synthesis of rac-2′-(trimethylsilyl)isovaline: A novel silicon-containing α, α-dialkylated α-amino acid, J. Organomet. Chem. 695, 2614-2617 (2010). read more...

    24.K. Junold, C. Burschka, R. Bertermann, R. Tacke, Novel neutral hexacoordinate silicon(IV) complexes with two bidentate monoanionic benzamidinato ligands, Dalton Transactions 39, 9401-9413 (2010). read more ...

    23.A. Sunderkötter, S. Lorenzen, R. Tacke, P. Kraft, Novel silicon-based patchouli odorants of the trialkyl(1-hydroxy-1-methylethyl)silane type: design synthesis, and olfactory properties, Chem. Eur. J., 16, 7404-7421 (2010). read more...

    22.S. Metz, B. Theis, C. Burschka, R.Tacke, Neutral pentacoordinate halogeno- and pseudohalogenosilicon(IV) complexes with an SiSONCX skeleton ( X = F, Cl, Br, I, N, C): Synthesis and structural characterization in the solid state and in solution, Chem. Eur. J. 16, 6844-6856 (2010). read more ...

    21.S. Cota, M. Beyer, R. Bertemann, C. Burschka, K. Götz, M. Kaupp, R. Tacke, Neutral penta- and hexacoordinate silicon(IV) complexes containing two bidentate ligands derived from the α-amino acids (S)-alanine, (S)-phenylalanine, and (S)-tert-leucine, Chem. Eur. J. 16, 6582-6589 (2010). read more...

    20.D. Troegel, W. P. Lippert, F. Möller, C. Burschka, R. Tacke, New C-functionalized silacycloalkanes (CH2)nSi(CH2X)2 and (CH2)nSi(CH2X)CH2X′ (n = 3, 4; X, X′ = functional group): Synthesis and reactivity studies of analogous silacyclobutanes and silacyclopentanes, J. Organomet. Chem. 695, 1700-1707 (2010). read more...

    19.C. Evangelisti, T.M. Klapötke, B. Krumm, A. Nieder, R.J.F. Berger, S.A. Hayes, N.W. Mitzel, D. Troegel, R. Tacke, Sila-substitution of alkyl nitrates: synthesis, structural characterization, and sensitivity studies of (nitratomethyl)-, bis(nitratomethyl)- and tris(nitratomethyl)silanes and their corresponding carbon analogues, Inorg. Chem. 49, 4865-4880 (2010). read more...

    18.R.Tacke, B. Nguyen, C. Burschka, W.P. Lippert, A. Hamacher, C. Urban, M.U. Kassack, Sila-trifluperidol, a silicon analogue of the dopamine (D2) receptor antagonist trifluperidol: synthesis and pharmacological characterization, Organometallics 29, 1652-1660 (2010). read more...

    17.

    J.B. Nätscher, N. Laskowski, P. Kraft, R. Tacke, Lower homologs of okoumal and disila-okoumal: syntheses and olfactory characterization of novel ambergris odorants, ChemBioChem 11, 315-319 (2010). read more...

     

    16.

    D. Troegel, F. Möller, R. Tacke, (2-Halogeno-5-pyridyl)dimethyl(oxiran-2-ylmethyl)silanes: new potential building blocks for the synthesis of silicon-containing drugs, J. Organomet. Chem. 695, 310-313 (2010). read more...

     

    15.

    T. Johansson, L. Weidolf, F. Popp, R. Tacke, U. Jurva, In vitro metabolism of haloperidol and sila-haloperidol – new metabolic pathways resulting from carbon/silicon exchange, Drug Metab. Dispos. 38, 73-82 (2009). read more...

     

    14.

    T. Weidner, N. Ballav, U. Siemeling, D. Troegel, T. Walter,  R. Tacke, D.G. Castner, M. Zharnikov, Tripodal binding units for self-assembled monolayers on gold: a comparison of thiol and thioether headgroups, J. Phys. Chem. 113, 19609-19617 (2009). read more...

     

    13.

    S. Falgner, C. Burschka, S. Wagner, A. Böhm, J.O. Daiß, R. Tacke, Asymmetric synthesis of the nonproteinogenic silicon-containing alpha-amino acids (R)- and (S)-
    alpha-[trimethylsilyl)methyl]alanine, Organometallics 28, 6059-6066 (2009). read more...

     

    12.

    R. Tacke, V. Müller, M.W. Büttner, W.P. Lippert, R. Bertermann, J.O. Daiss, H. Khanwalkar, A. Bindler, C. Gaudon, H. Gronemeyer, Synthesis and pharmacological characterization of disila-AM80 (disila-tamibarotene) and disila-AM580, silicon analogues of the RARa-selective retinoid agonists AM80 (tamibarotene) and AM580, ChemMedChem 4, 1797-1802 (2009). read more...

     

    11.

    D. Troegel, F. Möller, C. Burschka, R. Tacke, Synthesis and characterization of new trifunctional tetraorganylsilanes of the formula types MeSi(CH2X)3, MeSi(CH2X)2CH2X′, and MeSi(CH2X)(CH2X′)CH2X′′, Organometallics 28, 5765-5770 (2009). read more...

     

    10.

    S. Metz, J. B. Nätscher, C. Burschka, K. Götz, M. Kaupp, P. Kraft, R. Tacke, Disila-phantolide and derivatives: synthesis and olfactory characterization of silicon-containing derivatives of the musk odorant phantolide, Organometallics 28, 4700-4712 (2009). read more ...

     

    9.

    B. Theis, S. Metz, F. Back, C. Burschka, R. Tacke, Neutral pentacoordinate silicon(IV) complexes with SiClO2NC, SiClON2C, SiO3NC, or SiO2N2C skeletons, Z. Anorg. Allg. Chem. 635, 1306-1312 (2009). read more ...

     

    8.

    B. Theis, S. Metz, C. Burschka, R. Bertermann, S. Maisch, R. Tacke, Neutral pentacoordinate silicon(IV) complexes with silicon-chalcogen (S, Se, Te) bonds, Chem. Eur. J. 15, 7329-7338 (2009). read more ...

     

    7.

    W. P. Lippert, C. Burschka, K. Götz, M. Kaupp, D. Ivanova, C. Gaudon, Y. Sato, P. Antony, N. Rochel, D. Moras, H. Gronemeyer, R. Tacke, Silicon analogues of the RXR-selective retinoid agonist SR11237 (BMS649): chemistry and biology, ChemMedChem 4, 1143-1152 (2009). read more ...

     

    6.

    D. Troegel, F. Möller, C. Burschka, R. Tacke, 4-((2-Halogeno-5-pyridyl)dimethylsilyl)phenylboronic acids: new potential building blocks for the synthesis of silicon-containing drugs, Organometallics 28, 3218-3224 (2009). read more ...

     

    5.

    S. Falgner, D. Schmidt, R. Bertermann, C. Burschka, R. Tacke, Novel synthesis and crystal structure analysis of rac-beta-(trimethylsilyl)alanine, Organometallics 28, 2927-2930 (2009). read more ...

     

    4.

    D. Troegel, T. Walter, C. Burschka, R. Tacke, Synthesis and characterization of tris(mercaptomethyl)(2,4,6-trimethoxyphenyl)silane and its use for the immobilization of the Si(CH2SH)3 moiety on silica via an Si–O–Si linkage, Organometallics 28, 2756-2761 (2009). read more ...

     

    3.

    S. Metz, C. Burschka, R.  Tacke, Neutral hexacoordinate silicon(IV) complexes with an SiSO3NC skeleton and a neutral pentacoordinate silicon(IV) complex containing a trianionic tetradentate O,N,O,O ligand, Organometallics 28, 2311-2317 (2009). read more ...

     

    2.

    S. Metz, C. Burschka, R. Tacke, Synthesis and structural characterization of neutral hexacoordinate silicon(IV) complexes with SiO2N4 skeletons, Chem. Asian Journal  4, 581-586 (2009). read more ...

     

    1.  

    A. Jahnke, C. Burschka, R. Tacke, P. Kraft, Synthesis and olfactory evaluation of (4aR*,8aR*)-1,1,8a-trimethyldecahydronaphtalen-4a-ol: a cis-decalol intersection structure of (–)-patchoulol and (5R*,6S*)-1,1,6-trimethylspiro[4.5]decan-6-ol, Synthesis 1, 62-68 (2009).read more ...