Deutsch Intern
    Prof. Dr. Reinhold Tacke

    Original Works 2007 - 2008

    Publications 2007 - 2008

    21.  S. Metz, C. Burschka, R. Tacke, A neutral pentacoordinate silicon(IV) complex with a monodentate nitrato ligand: synthesis and structural characterization, Organometallics 27, 6032-6034 (2008). read more ... .

    20.

    J.B. Warneck, F.H.M. Cheng, M.J. Barnes, J.S. Mills, J. G. Montana, R.J. Naylor, M.-P. Ngan, M.-K. Wai, J.O. Daiss, R. Tacke, J.A. Rudd, Action of (R)-sila-venlafaxine and reboxetine to antagonize cisplatin-induced acute and delayed emesis in the ferret, Toxicol. Appl. Pharmacol. 232, 369-275 (2008). read more ...

    19.S. Metz, C. Burschka, R. Tacke, Synthesis and structural characterization of novel neutral hexacoordinate silicon(IV) complexes with SiS2O2N2 skeletons, Eur. J. Inorg. Chem., 4433-4439 (2008). read more ...

    18.

    R. Haga, C. Burschka, R. Tacke, Syntheses, structures, and reactions of 2,2,3,3-tetrakis(trifluoromethanesulfonato)tetrasilanes: hexacoordination ([4+2] coordination) of the two central silicon atoms, Organometallics 17, 4395-4400 (2008). read more ...

    17.G. González-García, J.A. Gutierrez, S. Cota, S. Metz, R. Bertermann, C. Burschka, R. Tacke, Synthesis and structural characterization of novel neutral higher-coordinate silicon(IV) complexes with SiON3C and SiON4C Skeletons, Z. Anorg. Allg. Chem. 634, 1281-1286 (2008). read more ...

    16.B. Theis, C. Burschka, R. Tacke, Optically active zwitterionic lambda5Si,lambda5Si'-disilicates: syntheses, crystal structures, and behavior in aqueous solution, Chem. Eur. J. 14, 4618-4630 (2008).read more ...


    15.

    R.Tacke, F. Popp, B. Müller, B. Theis, C. Burschka, A. Hamacher, M.U. Kassack, D. Schepmann, B. Wünsch, U. Jurva, E. Wellner, Sila-haloperidol, a silicon analogue of the dopamine (D2) receptor antagonist haloperidol: synthesis, pharmacological properties, and metabolic fate, ChemMedChem 3, 152-164 (2008). read more



    14.

    F. Popp, J.B. Nätscher, J.O. Daiss, C. Burschka, R. Tacke, The 2,4,6-trimethoxyphenyl unit as a unique protecting group for silicon in synthesis and the silylation potential of (2,4,6-trimethoxyphenyl)silanes, Organometallics 26, 6014-6028 (2007). read more ...



    13.


    L. Doszczak, R. Tacke, Syntheses of 1,3-disilaindanes, 1,4-disilatetralines, and 1,3-disila-1,3-dihydroisobenzofuranes using cobalt-catalyzed [2+2+2] cycloadditions, Organometallics 26, 5722-5723 (2007).read more ...




    12.



     
    O. Seiler, C. Burschka, K. Götz, M. Kaupp, S. Metz, R. Tacke, The new lambda6Si-silicate dianion [Si(NCO)6]2-: synthesis and structural characterization of [K(18-crown-6]2[Si(NCO)6], Z. Anorg. Allg. Chem. 633, 2667-2670 (2007). read more ...


    11.

    M.W. Büttner, C. Burschka, J.O. Daiss, D. Ivanova, N. Rochel, S. Kammerer, C. Petuso-Iltis, A. Bindler, C. Gaudon, P. Germain, D. Moras, H. Gronemeyer, R. Tacke, Silicon analogues of the retinoid agonists TTNPB and 3-methyl-TTNPB, disila-TTNPB and disila-3-methyl-TTNPB: Chemistry and Biology, ChemBioChem 8, 1688-1699 (2007). read more ...



    10.

    S. Metz, C. Burschka, D. Platte, R. Tacke, Pentacoordination of silicon by five different ligand atoms: neutral silicon(IV) complexes with SiClSONC and SiISONC skeletons, Angew. Chem. 119, 7136-7139 (2007); Angew. Chem. Int. Ed. 46, 7006-7009 (2007).read more ...


     

    9.



    D. Troegel, C. Burschka, S. Riedel, M. Kaupp, R. Tacke, Unusual silicon coordination polyhedra: non-VSEPR structures of zwiterrionic lambda5-Si silicon(IV) complexes with an SiS2N2C or SiS2O2C skeleton, Angew. Chem. 119, 7131-3135 (2007); read more ... ; Angew. Chem. Int. Ed. 46, 7001-7005 (2007).

    8.

    M.W. Büttner, J.B. Nätscher, C. Burschka, R. Tacke, Development of a new building block for the synthesis of silicon-based drugs and odorants: alternative synthesis of the retinoid agonist disila-bexarotene, Organometallics 26, 4835-4838 (2007). read more ...

    http://dx.doi.org/10.1021/om700570f
    7. M.W. Büttner, C. Burschka, K. Junold, P. Kraft, R. Tacke, Disila-okoumal: a silicon analogue of the ambergris odorant okoumal, ChemBioChem 8, 1447-1454 (2007). read more ...



    6.  

    M.W. Büttner, S. Metz, P. Kraft, R. Tacke, Silicon-based noncyclic woody-ambery odorants: synthesis and olfactory characterization of 4,4,6,6-tetramethylheptan-2-one and its sila-analogues, Organometallics 26, 3925-3929 (2007). read more ...

    http://dx.doi.org/10.1021/om700260q

    5.
     
     
    O. Seiler, C. Burschka, T. Fenske, D. Troegel, R. Tacke, Neutral hexa- and pentacoordinate silicon(IV) complexes with SiO6 and SiO4N skeletons, Inorg. Chem. 46, 5419-5424 (2007). read more ...

    4.

    T.M. Klapötke, B. Krumm, R. Ilg, D. Troegel, R. Tacke, The sila-explosives Si(CH2N3)4 and Si(CH2ONO2)4: silicon analogues of the common explosives pentaerythrityl tetraazide, C(CH2N3)4, and pentaerythritol tetranitrate, C(CH2ONO2)4, J. Am. Chem. Soc. 129, 6908-6915 (2007). read more ...

    http://dx.doi.org/10.1021/ja071299p
    3. L. Doszczak, P. Kraft, H.-P. Weber, R. Bertermann, A. Triller, H. Hatt, R. Tacke, Prediction of perception: probing the hOR17-4 olfactory receptor model with silicon-analogues of bourgeonal and lilial, Angew. Chem. 119, 3431-3436 (2007); Angew. Chem. Int. Ed. 46, 3367-3371 (2007). read more ...




      2. 


    L. Doszczak, P. Fey, R. Tacke, Novel ligand-free, cobalt-catalyzed [2+2+2] cycloadditions: syntheses of 1,4-disilatetralines and 1,3-disilaindanes, Synlett, 753-756 (2007). read more ...


     

    1.


    M.W. Büttner, M. Penka, L. Doszczak, P. Kraft, R. Tacke, Silicon analogues of the musk odorant versalide, Organometallics 26, 1295-1298 (2007). read more ...