Deutsch Intern
Arbeitsgruppe Braunschweig

Latest Publications


Prof. Holger Braunschweig has published over 600 manuscripts since 1990, the majority of which appeared in first ranking journals such as ScienceNatureNature ChemistryAngewandte ChemieChemistry - A European Journal,...  

Latest Publications 2021 

635 J. Ramler, F. Fantuzzi, F. Geist, A. Hanft, H. Braunschweig, B. Engels, C. Lichtenberg
The Dimethylbismuth Cation: Entry into Dative Bi–Bi Bonding and Unconventional Methyl Exchange
Angew. Chem. 2021133, 24592–24598; Angew. Chem. Int. Ed. 202160, 24388–24394.
634 S. Nees, F. Fantuzzi, T. Wellnitz, M. Fischer, J.-E. Siewert, J. T. Goettel, A. Hofmann, M. Härterich, H. Braunschweig, C. Hering-Junghans
Angew. Chem. 2021133, 24520–24528; Angew. Chem. Int. Ed. 202160, 24318–24325.
633 F. Zhang, K. Radacki, H. Braunschweig, C. Lambert, P. Ravat
Zinc-[7]helicenocyanine and Its Discrete π-Stacked Homochiral Dimer
Angew. Chem. 2021133, 23848–23852; Angew. Chem. Int. Ed. 202160, 23656–23660.
632 C. Czernetzki, M. Arrowsmith, F. Fantuzzi, A. Gärtner, T. Tröster, I. Krummenacher, F. Schorr, H. Braunschweig
A Neutral Beryllium(I) Radical
Angew. Chem. 2021133, 20944–20948; Angew. Chem. Int. Ed. 202160, 20776–20780.
631 C. Brunecker, M. Arrowsmith, F. Fantuzzi, H. Braunschweig
Platinum-Templated Coupling of B=N units: Synthesis of BNBN Analogues of 1,3-Dienes and a Butatriene
Angew. Chem. 2021133, 17000–17004; Angew. Chem. Int. Ed. 202160, 16864–16868.
630 S. Hagspiel, F. Fantuzzi, R. D. Dewhurst, A. Gärtner, F. Lindl, A. Lamprecht, H. Braunschweig
Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry
Angew. Chem. 2021133, 13780–13784; Angew. Chem. Int. Ed. 202160, 13666–13670.
629 T. Brückner, F. Fantuzzi, T. E. Stennett, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig
Isolation of Neutral, Mono-, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron-Boron Triple Bond
Angew. Chem. 2021133, 13774–13779; Angew. Chem. Int. Ed. 202160, 13661–13665.
628 M. Crumbach, J. Bachmann, L. Fritze, A. Helbig, I. Krummenacher, H. Braunschweig, H. Helten
Dithiophene-Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics
Angew. Chem. 2021133, 9376–9381; Angew. Chem. Int. Ed. 202160, 9290–9295.
627 S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, A. Hermann, T. Brückner, H. Braunschweig
Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates
Angew. Chem. 2021133, 6519–6524; Angew. Chem. Int. Ed. 202160, 6446–6450.
626 J. He, F. Rauch, A. Friedrich, J. Krebs, I. Krummenacher, R. Bertermann,J. Nitsch, H. Braunschweig, M. Finze, T. B. Marder
Phenylpyridyl-fused Boroles: A Unique Coordination Mode and Weak B–N Coordination Induced Dual Fluorescence
Angew. Chem. 2021133, 4883–4890; Angew. Chem. Int. Ed. 202160, 4833–4840.
625 D. K. Roy, T. Tröster, F. Fantuzzi, R. D. Dewhurst, C. Lenczyk, K. Radacki, C. Pranckevicius, B. Engels, H. Braunschweig
Isolation and Reactivity of an Antiaromatic s-Block Metal Compound
Angew. Chem. 2021133, 3856–3863; Angew. Chem. Int. Ed. 202160, 3812–3819.
624 M. Rang, F. Fantuzzi, M. Arrowsmith, E. Beck, R. Witte, A. Matler, A. Rempel, T. Bischof, K. Radacki, B. Engels, H. Braunschweig
Reduction and Rearrangement of a Boron(I) Carbonyl Complex
Angew. Chem. 2021133, 3000–3005; Angew. Chem. Int. Ed. 202160, 2963–2968.
623 T. Brückner, M. Heß, T. E. Stennett, A. Rempel, H. Braunschweig
Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron-Boron Triple Bond
Angew. Chem. 2021133, 747–752; Angew. Chem. Int. Ed. 202160, 736–741.
622 M. Härterich, B. Ritschel, M. Arrowsmith, J. Böhnke, I. Krummenacher, A. K. Phukan, H. Braunschweig
Hybrid Inorganic-Organic Cross-Metathesis between Diborenes and Acetylene
J. Am. Chem. Soc. 2021143, 18339–18345.
621 M. Fischer, S. Nees, T. Kupfer, J. T. Goettel, H. Braunschweig, C. Hering-Junghans
Isolable Phospha- and Arsaalumenes
J. Am. Chem. Soc. 2021143, 4106–4111.
620 A. Maiti, F. Zhang, I. Krummenacher, M. Bhattacharyya, S. Mehta, M. Moos, C. Lambert, B. Engels, A. Mondal, H. Braunschweig, P. Ravat, A. Jana
Anionic Boron- and Carbon-Based Hetero-Diradicaloids Spanned by a p-Phenylene Bridge
J. Am. Chem. Soc. 2021143, 3687–3692.
619 Y. –M. Tian, X.-N. Guo, H. Braunschweig, U. Radius, T. B. Marder
Photoinduced Borylation for the Synthesis of Organoboron Compounds
Chem. Rev. 2021121, 3561–3597.
618 K. Saha, D. K. Roy, R. D. Dewhurst, S. Ghosh, H. Braunschweig
Recent Advances in the Synthesis and Reactivity of Transition-Metal σ-Borane/-Borate Complexes
Acc. Chem. Res. 202154, 1260–1273.
617 X. Jia, J. Nitsch, Z. Wu, A. Friedrich, J. Krebs, I. Krummenacher, F. Fantuzzi, H. Braunschweig, M. Moos, C. Lambert, B. Engels, T. B. Marder
One- and two-electron reduction of triarylborane-based helical donor-acceptor compounds
Chem. Sci. 202112, 11864–11872.
616 L. Englert, U. Schmidt, M. Dömling, M. Passargus, T. E. Stennett, A. Hermann, M. Arrowsmith, M. Härterich, J. Müssig, A. Phillipps, D. Prieschl, A. Rempel, F. Rohm, K. Radacki, F. Schorr, T. Thiess, J. O. C. Jiménez-Halla, H. Braunschweig
Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and C≡C triple bond scission
Chem. Sci. 202112, 9506–9515.
615 S. Hagspiel, D. Elezi, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, M. Härterich, I. Krummenacher, H. Braunschweig
Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity
Chem. Sci. 202112, 7937–7942.
614 R. Rausch, M. Roehr, D. Schmid, I. Krummenacher, H. Braunschweig, F. Würthner
Tuning phenoxyl-substituted diketopyrrolopyrroles from quinoidal to biradical ground states through (hetero-)aromatic linkers
Chem. Sci. 202112, 793–802.
613 A. Mahata, N. Chrysochos, I. Krummenacher, S. Chandra, H. Braunschweig, C. Schulzke, B. Sarkar,C. B. Yildiz, A. Jana
α,α’-Diamino-p-tetrafluoroquinodimethane: Stability of One- and Two-Electron Oxidized Species and Fixation of Molecular Oxygen
J. Org. Chem. 202186, 10467–10473.
612 R. Rausch, A.-M. Krause, I. Krummenacher, H. Braunschweig, F. Würthner
Nitronyl Nitroxide Bifunctionalized Electron–Poor Chromophores: Synthesis of Stable Dye Biradicals by Lewis Acid Promoted Desilylation
J. Org. Chem. 202186, 2447–2457.
611 M. Arrowsmith, S. Endres, M. Heinz, V. Nestler, M. C. Holthausen, H. Braunschweig
Probing the Boundaries between Lewis-Basic and Redox Behavior of a Parent Borylene
Chem. Eur. J. 202127, 17660–17668.
610 F. Schorr, N. Schopper, N. Riensch, F. Fantuzzi, M. Neder, R. Dewhurst, T. Thiess, T. Brückner, K. Hammond, H. Helten, M. Finze, H. Braunschweig
Controlled Synthesis of Oligomers Containing Main-Chain B(sp2)-B(sp2) Bonds
Chem. Eur. J. 202127, 16043–16048.
609 J. Cui, M. Dietz, M. Härterich, F. Fantuzzi, W. Lu, R. D. Dewhurst, H. Braunschweig
Diphosphino-Functionalized 1,8-Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes
Chem. Eur. J. 202127, 15751–15756.
608 S. M. Berger, J. Rühe, J. Schwarzmann, A. Phillipps, A.-K. Richard, M. Ferger, I. Krummenacher, L.-M. Tumir, Ž. Ban, I. Crnolatac, D. Majhen, I. Barišić, I. Piantanida, D. Schleier, S. Griesbeck, A. Friedrich, H. Braunschweig, T. B. Marder
Triarylborane Chromophores: Effect of the Number and Position of Charges on Cell Imaging and DNA/RNA Sensing
Chem. Eur. J. 202127, 14057–14072.
607 F. Lindl, X. Guo, I. Krummenacher, F. Rauch, A. Rempel, V. Paprocki, T. Dellermann, T. E. Stennett, A. Lamprecht, T. Brückner, K. Radacki, G. Bélanger-Chabot, T. B. Marder, Z. Lin, H. Braunschweig
Rethinking Borole Cycloaddition Reactivity
Chem. Eur. J. 202127, 11226–11233.
606 A. Gärtner, M. Marek, M. Arrowsmith, D. Auerhammer, K. Radacki, D. Prieschl, R. D. Dewhurst, H. Braunschweig
Boron- versus Nitrogen-Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2-Aza-1,4-diborabutatrienes
Chem. Eur. J. 202127, 9694–9699.
605 M. Heß, I. Krummenacher, T. Dellermann, H. Braunschweig
Rhodium-Mediated Stoichiometric Synthesis of Mono-, Bi-, and Bis-1,2-Azaborinines: 1-Rhoda-3,2-azaboroles as Reactive Precursors
Chem. Eur. J. 202127, 9503–9507.
604 J. Krebs, M. Haehnel, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, L. Ji, T. B. Marder
Synthesis and Structure of an o-Carboranyl-substituted Three-coordinate Borane Radical Anion
Chem. Eur. J. 202127, 8159–8167.
603 P. Schmid, F. Fantuzzi, J. Klopf, N. B. Schröder, R. D. Dewhurst, H. Braunschweig, V. Engel, B. Engels
Twisting versus Delocalization in CAAC- and NHC-stabilized Boron-Based Biradicals: The Role of Sterics and Electronics
Chem. Eur. J. 202127, 5160–5170.
602/td> G. K. Kole, J. Merz, A. Amar, B. Fontaine, A. Boucekkine, J. Nitsch, S. Lorenzen, A. Friedrich, I. Krummenacher, M. Košćak, H. Braunschweig, I. Piantanida, J.-F. Halet, K. Müller-Buschbaum, T. B. Marder
2- and 2,7-Substituted para-N-Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double Stranded (ds)-DNA
Chem. Eur. J. 202127, 2837–2853.
601 M. Dietz, M. Arrowsmith, A. Gärtner, K. Radacki, R. Bertermann, H. Braunschweig
Harnessing the electronic differences between CAAC-stabilised 1,4-diborabenzene and 9,10-diboraanthracene for synthesis
Chem. Commun. 202157, 13526–13529.
600 D. Dhara, P. K. Pal, R. Dolai, N. Chrysochos, H. Rawat, B. J. Elvers, I. Krummenacher, H. Braunschweig, C. Schulzke, V. Chandrasekhar, U. D. Priyakumar, A. Jana
Synthesis and reactivity of NHC-coordinated phosphinidene oxide
Chem. Commun. 202157, 9546–9549.
599 R. Drescher, B. Ritschel, R. D. Dewhurst, A. Deißenberger, A. Hofmann, H. Braunschweig
Synthesis of novel six-, seven- and eight-membered aluminum-containing rings by alumole ring expansion
Chem. Commun. 202157, 7505–7508.
598 F. Schorr, F. Fantuzzi, R. D. Dewhurst, H. Braunschweig
Dialkynyldiboranes(4) and the selectable reactivity of their C-H, C-C and B-B bonds
Chem. Commun. 202157, 2645–2648.
597 L. Fritze, M. Fest, A. Helbig, T. Bischof, I. Krummenacher, H. Braunschweig, M. Finze, H. Helten
Boron-Doped α-Oligo- and Polyfurans: Highly Luminescent Hybrid Materials, Color-Tunable through the Doping Density
Macromolecules 202154, 7653–7665.
596 A. Stoy, M. Arrowsmith, M. Eyßelein, T. Dellermann, J. Mies, K. Radacki, T. Kupfer, H. Braunschweig
NHC-Stabilized 1,2-Dihalodiborenes: Synthesis, Characterization and Reactivity Toward Elemental Chalcogens
Inorg. Chem. 202160, 12625–12633.
595 Z.-F. Jiao, Y.-M. Tian, X.-N. Guo, U. Radius, H. Braunschweig, T. B. Marder, X.-Y. Guo
Visible-light-driven graphene supported Cu/Pd alloy nanoparticle-catalyzed borylation of alkyl bromides and chlorides in air
J. Catal. 2021395, 258–265.
594 L. Wu, R. D. Dewhurst, H. Braunschweig, Z. Lin
C-C versus C-H Activation: Understanding How the Carbene π-Accepting Ability Controls the Intramolecular Reactivities of Mono(carbene)-Stabilized Borylenes
Organometallics 202140, 766–775.
593 W. D. do Pim, I. F. Silva, E. N. da Silva Júnior, H. O. Stumpf, W. X. C. Oliveira, E. F. Pedroso, C. B. Pinheiro, Y. Journaux, F. Fantuzzi, I. Krummenacher, H. Braunschweig, B. Engels, J. Cano, M. Julve, C. L. M. Pereira
Unexpected formation of a dodecanuclear {CoII6CuII6} Nanowheel under ambient conditions: magneto-structural correlations
Dalton Trans. 202150, 12430–12434.
592 R. Drescher, L. Wüst, C. Mihm, I. Krummenacher, A. Hofmann, J. Goettel, H. Braunschweig
Synthesis, structure and insertion reactivity of Lewis acidic 9-aluminafluorenes
Dalton Trans. 202150, 10400–10404.
591 C. Brunecker, M. Arrowsmith, J. H. Müssig, J. Böhnke, A. Stoy, M. Heß, A. Hofmann, C. Lenczyk, C. Lichtenberg, J. Ramler, A. Rempel, H. Braunschweig
Synthesis and characterisation of boranediyl- and diboranediyl-bridged diplatinum A-frame complexes
Dalton Trans. 202150, 3506–3515.
590 J. He, F. Rauch, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
Two derivatives of phenylpyridyl-fused boroles with contrasting electronic properties: decreasing and enhancing the electron accepting ability
Dalton Trans. 202150, 355–361.
589 N. A. Riensch, M. Fest, L. Fritze, A. Helbig, I. Krummenacher, H. Braunschweig, H. Helten
Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes
New. J. Chem. 202145, 14920–14924.
588 M. Gerlach, S. Monninger, D. Schleier, P. Hemberger, J. T. Goettel, H. Braunschweig, I. Fischer
Photoelectron Photoion Coincidence Spectroscopy of NCl3 and NCl2
ChemPhysChem 202122, 2164–2167.
587 A. Matler, M. Arrowsmith, F. Schorr, A. Hermann, A. Hofmann, C. Lenczyk, H. Braunschweig
Reactivity of Terminal Iron Borylenes and Bis(borylenes) with Carbodiimides: Cycloaddition, Metathesis, Insertion and C–H Activation Pathways
Eur. J. Inorg. Chem.  2021, 4619–4631.
586 R.-S. Sauer, I. Krummenacher, E. E. Bankoglu, S. Yang, B. Oehler, F. Schöppler, M. Mohammadi, P. Güntzel, A. Ben-Kraeim, U. Holzgrabe, H. Stopper, J. A. Broscheit, H. Braunschweig, N. Roewer, A. Brack, H. Rittner
Stabilization of Delphinidin in Complex with Sulfobutylether-β-Cyclodextrin Allows for Antinociception in Inflammatory Pain
Antioxid. Redox Signal. 202134, 1260–1279.
585 N. A. Riensch, L. Swoboda, A. Lik, I. Krummenacher, H. Braunschweig, H. Helten
Conjugated Bis(triarylboranes) with Disconnected Conjugation
Z. Anorg. Allg. Chem. 2021647, 421–424.


For a full list of publications visit our Group homepage www.braunschweiggroup.de.