Deutsch Intern



    45) Synthesis of a blue-emissive azaborathia[9]helicene by silicon-boron exchange from unusual atropisomeric teraryls
    D. Volland, J. Niedens, P. T. Geppert, M. J. Wildervanck, F. Full, A. Nowak-Król*
    Angew. Chem. Int. Ed. 2023, e202304291.
    DOI: 10.1002/anie.202304291

    44) Amber light control of peptide secondary structure by a perfluoroaromatic azobenzene photoswitch
    E. Cataldi, M. Raschig M. Gutmann, P. T. Geppert, M. Ruopp, M. Schock, H. Gerwe, R. Bertermann, L. Meinel, M. Finze, A. Nowak-Król, M. Decker, T. Lühmann*
    ChemBioChem, 2023, 24, e202200570.
    DOI: 10.1002/cbic.202200570.


    43) Electrophilic C–H Borylation of Aza[5]helicenes Leading to Bowl-Shaped Quasi-[7]Circulenes with Switchable Dynamics
    X. Zhang,* F. Rauch, J. Niedens, R. B. da Silva, A. Friedrich, A. Nowak-Król,* Simon J. Garden,* T. B. Marder*
    J. Am. Chem. Soc. 2022, 144,  22316–22324.
    DOI: 10.1021/jacs.2c10865
    highlighted in ChemistryViews
    highlighted in Synfacts:
    N→B-Bridged Quasi-[7]circulenes
    D. Zhao, X. Bai
    Synfacts 2023, 19, 0243.
    DOI: 10.1055/s-0042-1753326

    42) 55th Bürgenstock Conference under the banner of sustainability
    A. Nowak-Król,* P. Dydio*
    Angew. Chem. Int. Ed. 2022, 61, e202214722.
    DOI: 10.1002/anie.202214722
    Angew. Chem. 2022, 134, e202214722.
    DOI: 10.1002/ange.202214722
    Meeting Report

    41) Synthesis and strong solvatochromism of push-pull thienylthiazole boron complexes
    M. J. Wildervanck, R. Hecht, A. Nowak-Król*
    Molecules 2022, 27, 5510.
    DOI: 10.3390/molecules27175510.
    Special Collection ‘New Boron Chemistry: Current Advances and Future Prospects’, invited

    40) Synthesis of enantioenriched azaborole helicenes by chirality transfer from axially chiral biaryls
    F. Full, M. J. Wildervanck, D. Volland, A. Nowak-Król*
    Synlett 202334, 477–482.
    DOI: 10.1055/a-1914-1799.
    SYNLETT Special Edition ‘Thieme Chemistry Journals Awardees 2022’

    39) Enhanced Optical Properties of Azaborole Helicenes by Lateral and Helical Extension
    F. Full, Q. Wölflick, K. Radacki, H. Braunschweig, A. Nowak-Król*
    Chem. Eur. J. 2022, e202202280. (Hot Paper)
    DOI: 10.1002/chem.202202280.
    highlighted in Synfacts:
    Azaborole Helicenes with Double Helical Axes
    D. Zhao, X. Bai
    Synfacts 2023, 19, 0143.
    DOI: 10.1055/s-0042-1751818

    38) Enhanced N-directed electrophilic C-H borylation generates BN- [5]- and [6]helicenes with improved photophysical properties
    K. Yuan, D. Volland, S. Kirschner, M. Uzelac, G. S. Nichol, A. Nowak-Król,* M. J. Ingleson*
    Chem. Sci. 202213, 1136–1145.
    DOI: 10.1039/D1SC06513K


    37) Modular synthesis of organoboron helically chiral compounds: cutouts from extended helices
    J. Full, S. P. Panchal, J. Gӧtz, A.-M. Krause, A. Nowak-Król*
    Angew. Chem. Int. Ed. 2021, 60, 4350–4357. (Hot Paper)
    DOI: 10.1002/anie.202014138
    Angew. Chem. 2021, 133, 4396–4403
    DOI: 10.1002/ange.202014138
    highlighted in ChemistryViews


    36) Access to corrole-appended persubstituted benzofurans by a multicomponent reaction: the dual role of p-chloranil
    A. Nowak-Król,* B. Koszarna, M. Krzeszewski, T. D. Lohrey, J. Arnold,* D. T. Gryko*
    Org. Lett. 2020, 22, 8139–8143.
    DOI: 10.1021/acs.orglett.0c03133


    35) Ultrafast coherent exciton dynamics in size-controlled perylene bisimide aggregates
    S. Kang, C. Kaufmann, Y. Hong, W. Kim, A. Nowak-Król, F. Würthner, D. Kim
    Struct. Dyn. 2019, 6, 064501.
    DOI: 10.1063/1.5124148
    34) Tetrahydroxy-perylene bisimide embedded in a zinc oxide thin film as an electron-transporting layer 
    for high-performance non-fullerene organic solar cells
    X. Wen,# A. Nowak-Król,# O. Nagler, F. Kraus, N. Zhu, N. Zheng, M. Müller, D. Schmidt, Z. Xie, F. Würthner
    Angew. Chem. Int. Ed. 2019, 58, 13051-13055.      
    DOI: 10.1002/anie.201907467
    Angew. Chem. 2019, 131, 13185-13189 
    # equal contribution
    Press release
    33) Low-melting porphyrins and their photophysical properties
    A. Nowak-Król, D. T. Gryko
    in Functional Organic Liquids; Ed. T. Nakanishi; Wiley-VCH, 2019



    32) Solvent-modulated charge-transfer resonance enhancement in the excimer state of a bay-substituted perylene bisimide 
    W. Kim, A. Nowak-Król, Y. Hong, F. Schlosser, F. Würthner, D. Kim
    J. Phys. Chem. Lett. 2019, 10, 1919–1927.
    DOI: 10.1021/acs.jpclett.9b00357



    31) Progress in the synthesis of perylene bisimide dyes
    A. Nowak-Król, F. Würthner
    Org. Chem. Front. 2019, 6, 1272-1318 (review).
    DOI: 10.1039/C8QO01368C



    30) Naphthalene and perylene diimides – better alternatives to fullerenes for organic electronics?
    A. Nowak-Król, K. Shoyama, M. Stolte, F. Würthner
    Chem. Commun. 2018, 54, 13763-13772 (review).
    DOI: 10.1039/C8CC07640E



    29) Ultrafast exciton delocalization, localization, and excimer formation dynamics in a highly defined 
    perylene bisimide quadruple π‑stack
    C. Kaufmann, W. Kim, A. Nowak-Król, Y. Hong, D. Kim, F. Würthner
    J. Am. Chem. Soc. 2018, 140, 4253-4258.
    DOI: 10.1021/jacs.7b11571



    28) n-Channel organic semiconductors derived from air-stable four-coordinate boron complexes of substituted thienylthiazoles
    R. Hecht, J. Kade, D. Schmidt, A. Nowak-Król*
    Chem. Eur. J. 2017, 23, 11620-11628 (Hot Paper).
    DOI: 10.1002/chem.201701922



    27) A crystalline π-stack containing five stereoisomers: insights into conformational isomorphism, chirality inversion, and disorder
    A. Nowak-Król, M. I. S. Röhr, D. Schmidt, F. Würthner
    Angew. Chem. Int. Ed. 2017, 56, 11774-11778.
    DOI: 10.1002/anie.201705445
    Angew. Chem. 2017, 129, 11936-11940.
    DOI: 10.1002/ange.201705445



    26) Direct observation of excimer-mediated intramolecular electron transfer in a cofacially-stacked perylene bisimide pair
    J. Sung, A. Nowak-Król, F. Schlosser, B. Fimmel, W. Kim, D. Kim, F. Würthner
    J. Am. Chem. Soc. 2016, 138, 9029-9032.
    DOI: 10.1021/jacs.6b04591

    25) Stable, low-melting trans-A2B-corroles
    A. Nowak-Król, E. Fourie, C. C. Joubert, D. Gryko, D. T. Gryko, J. C. Swarts
    J. Porphyrins Phthalocyanines 2016, 20, 1244-1255.
    DOI: 10.1142/S1088424616500942

    24) Modulation of band gap and p- versus n-semiconductor character of ADA dyes by core and acceptor group variation
    A. Nowak-Król, R. Wagener, F. Kraus, A. Mishra, P. Bäuerle, F. Würthner
    Org. Chem. Front. 2016, 3, 545-555.
    DOI: 10.1039/C6QO00046K

    23) Tetramethoxy-bay-substituted perylene bisimides by copper-mediated cross-coupling
    P. Leowanawat, A. Nowak-Król, F. Würthner
    Org. Chem. Front. 2016, 3, 537-544 (front cover).
    DOI: 10.1039/C6QO00047A


    22) Photoinduced electron transfer (PET) versus excimer formation in supramolecular p/n-heterojunctions of perylene bisimide dyes and implications for organic photovoltaics
    A. Nowak-Król, B. Fimmel, M. Son, D. Kim, F. Würthner
    Faraday Discuss. 2015, 185, 507-527.
    DOI: 10.1039/C5FD00052A

    21) Liquid-crystalline properties of trans-A2B2-porphyrins with extended π-electron systems
    M. Salamończyk, D. Pociecha, A. Nowak-Król, D. Koszelewski, D. T. Gryko, E. Górecka
    Chem.Eur.J. 2015, 21 ,7384–7388.
    DOI: 10.1002/chem.201500296

    20) An efficient synthesis of porphyrins with different meso substituents that avoids scrambling in aqueous media
    A. Nowak-Król, R. Plamont, G. Canard, J. A. Edzang, D. T. Gryko, T. S. Balaban
    Chem. Eur. J. 2015, 21, 1488-1498 (inside cover).
    DOI: 10.1002/chem.201403677

    19) The 1H, 13C, 15N, and 19F NMR chemical shifts assignments in 5,10,15-tris(penta-fluorophenyl)tetra-15N corrole at 191 K
    W. Bocian, P. Paluch, A. Nowak-Król, D. T. Gryko, M. Potrzebowski, J. Śniechowska, J. Sitkowski, E. Bednarek, L. Kozerski
    Magn. Res. Chem. 2015, 53, 167-171.
    DOI: 10.1002/mrc.4145


    18) Soluble meso-tetrakis(arylethynyl)porphyrins - synthesis and optical properties
    A. Nowak-Król, Ł. G. Łukasiewicz, J. E. Haley, M. Drobizhev, A. Rebane, T. M. Cooper, D. T. Gryko
    J. Porphyrins Phthalocyanines 2014, 18, 998-1013.
    DOI: 10.1142/S1088424614500904

    17) Two-photon absorption in butadiyne-linked porphyrin dimers: torsional and substituent effects
    J. D. Wilkinson, G. Wicks, A. Nowak-Król, Ł. G. Łukasiewicz, C. J. Wilson, M. Drobizhev, A. Rebane, D. T. Gryko, H. L. Anderson
    J. Mat. Chem. C 2014, 2, 6802-6809.
    DOI: 10.1039/C4TC01120A

    16) Insights into the tautomerism in meso-substituted corroles: a variable-temperature 1H, 13C, 15N, and 19F NMR spectroscopy study
    S. Szymański, P. Paluch, D. T. Gryko, A. Nowak-Król, W. Bocian, J. Sitkowski, B. Koszarna, J. Śniechowska, M. J. Potrzebowski, L. Kozerski
    Chem. Eur. J. 2014, 20, 1720-1730.
    DOI: 10.1002/chem.201303406


    15) Oxidative aromatic coupling of meso-arylamino-porphyrins
    A. Nowak-Król, D. T. Gryko
    Org. Lett2013, 15, 5618-5621.
    DOI: 10.1021/ol4022035

    14) Study of intermolecular interactions in the corrole matrix by solid-state NMR under 100 kHz MAS and theoretical calculations
    T. Kobayashi, K. Mao, P. Paluch, A. Nowak-Król, J. Sniechowska, Y. Nishiyama, D. T. Gryko, M. J. Potrzebowski, M. Pruski
    Angew. Chem. Int. Ed. 2013, 52, 14108-14111.
    DOI: 10.1002/anie.201305475
    Angew. Chem. 2013,125, 14358-14361.
    DOI: 10.1002/ange.201305475

    13) All-optical corrole-based oxygen sensor
    N. Czechowski, A. Nowak-Król, D. T. Gryko, S. Maćkowski
    Phys. Scr. 2013, T157, 014009.
    DOI: 10.1088/0031-8949/2013/T157/014009

    12) Strong two-photon absorption enhancement in a unique bis-porphyrin bearing a diketopyrrolopyrrole unit
    A. Nowak-Król, M. Grzybowski, J. Romiszewski, M. Drobizhev, G. Wicks, M. Chotkowski, A. Rebane, E. Górecka, D. T. Gryko
    Chem. Commun. 2013, 49, 8368-8370.

    11) Synthesis and linear and nonlinear optical properties of low-melting π-extended porphyrins
    D. Koszelewski, A. Nowak-Król, M. Drobizhev, C. J. Wilson, J. E. Haley, T. M. Cooper, J. Romiszewski, E. Górecka, H. L. Anderson, A. Rebane, D. T. Gryko
    J. Mater. Chem. C 2013, 1, 2044-2053.
    DOI: 10.1039/C3TC00594A


    10) Fluorescence microscopy of corrole-single silver nanowire hybrid nanostructures
    N. Czechowski, M. Olejnik, A. Nowak-Król, D. Piątkowski, W. Heiss, D.T. Gryko, S. Mackowski
    Acta Phys. Pol. A 2012, 122, 333-336.
    DOI: 10.12693/APhysPolA.122.333

    9) Amplified two-photon absorption in trans-A2B2-porphyrins bearing nitrophenylethynyl substituents
    A. Nowak-Król, C. J. Wilson, M. Drobizhev, D. V. Kondratuk, A. Rebane, H. L. Anderson, D. T. Gryko
    ChemPhysChem 2012, 13, 3966-3972 (Editor’s selection).
    DOI: 10.1002/cphc.201200507

    8) Selective cycloaddition of tetracyanoethene (TCNE) and 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) to afford meso-substituted phenylethynyl porphyrin
    D. Koszelewski, A. Nowak-Król, D. T. Gryko
    Chem. Asian J. 2012, 7, 1887-1894.
    DOI: 10.1002/asia.201200179


    7) Synthesis of trans-A2B2-porphyrins bearing phenylethynyl substituents
    A. Nowak-Król, B. Koszarna, S. Y. Yoo, J. Chromiński, M. K. Węcławski, C.-H. Lee, D. T. Gryko
    J. Org. Chem2011, 76, 2627-2634.
    DOI: 10.1021/jo1025578


    6) Mass spectrometry studies on meso-substituted corroles and their photochemical decomposition products
    P. Świder, A. Nowak-Król, R. Voloshchuk, J. P. Lewtak, D. T. Gryko, W. Danikiewicz
    J. Mass Spectrom. 2010, 45, 1443-1451.
    DOI: 10.1002/jms.1860

    5) meso-Alkylidene (m-benzi)pentaphyrin: a modified pentaphyrin bearing exocyclic double bonds at meso-positions
    S.-D. Jeong, A. Nowak-Król, Y. Kim, S.-J. Kim, D. T. Gryko, C.-H. Lee
    Chem. Commun. 2010, 8737-8739.
    DOI: 10.1039/C0CC03263H

    4) Synthesis and adrenolytic activity of new propanolamines
    G. Groszek, A. Bajek, A. Bis, A. Nowak-Król, M. Bednarski, A. Siwek, B. Filipek
    Molecules 2010, 15, 3887-3904.
    DOI: 10.3390/molecules15063887

    3) Meso-substituted liquid porphyrins
    A. Nowak-Król, D. Gryko, D. T. Gryko
    Chem. Asian J. 2010, 5, 904-909 (cover article).
    DOI: 10.1002/asia.200900693


    2) Synthesis and adrenolytic activity of 1-(1H-indol-4-yloxy)-3-(2-(2-methoxy-phenoxy)ethylamino)propan-2-ol analogs and its enantiomers. Part 2
    G. Groszek, A. Nowak-Król, T. Wdowik, D. Świerczyński, M. Bednarski, M. Otto, M. Walczak, B. Filipek
    Eur. J. Med. Chem. 2009, 44, 5103-5111.
    DOI: 10.1016/j.ejmech.2009.07.012


    1) Straightforward transformation of pentafluorobenzaldehyde into 4-aryloxy-2,3,5,6-tetrafluorobenzaldehydes
    D. T. Gryko, D. Wyrostek, A. Nowak-Król, K. Abramczyk, M. K. Rogacki
    Synthesis­­ 2008, 4028-4032.
    DOI: 10.1055/s-0028-1083246​​​​​​​


    1) Nowe blokery optyczne oparte na bis-porfirynach o rozszerzonym chromoforze (New blockers based on bis-porphyrins with extended chromophores)
    D. T. Gryko, A. Nowak-Król
    Polish granted patent PL 223427 B1, 2016.