Deutsch Intern
Institute for sustainable chemistry & catalysis with boron - ICB

Just Published in Chemistry - A European Journal

12/19/2018

Lanthanide Coordination Polymers and MOFs based on the Dicyanodihydridoborate Anion

Authors: Sven H. Zottnick, Wiebke G. Daul, Christoph Kerpen, Maik Finze, Klaus Müller-Buschbaum*

Abstract: New lanthanide cyanoborates were synthesized from anhydrous lanthanide chlorides and the acid H[BH2(CN)2] in either acetonitrile or pyridine. The obtained compounds show intense photoluminescence based on either 5d–4f transitions or 4f–4f transitions of the respective lanthanide ions.

Link: https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201802627

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